NANOCOLOR Crack set

Hazard statements (CLP)

H272, H290, H302, H314, H315, H317, H319, H334, H335

Code

Statements

H272

May intensify fire; oxidiser

SECTION 2: Hazards identification

2.0 Classification of the complete product GHS03 GHS05 GHS07 GHS08

Signal word

DANGER Hazard classes/categories H272 Ox. Sol. 2 H290 Met. Corr. 1 H302 Acute Tox. 4 oral H314 Skin Corr. 1A H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H335 STOT SE 3 DANGER Hazard classes/categories H314 Skin Corr. 1A 17 g Crack Set R2 GHS03 GHS07 GHS08 DANGER Hazard classes/categories H272 Ox. Sol. 2 H302 Acute Tox. 4 oral H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H335 STOT SE 3 100 mL Crack Set R3 GHS05 DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 17 g Crack Set R2 GHS03 GHS07 GHS08 DANGER H317, H334 May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. P261sh, P280sh, P342+311 Avoid breathing dust/vapours. Wear protective gloves/eye protection. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. 100 mL Crack Set R3 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

2.1 Classification of the substance or mixture

100 mL Crack Set R1 GHS05

2.2 Label elements

According CLP directive inner packages must be only labelled with GHS symbol(s) and product identificator(s) (EU 1272/2008 Annex I - 1.5.1.2). Harmful chemicals/mixtures with signal word: WARNING must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2). This labelling exemption is NOT valid for sensibilizing substances. Oxidizing mixtures with signal word: DANGER and H272 must not be labelled with H and P phrases until 125 mL . Metal corrosive solutions do not have to be labelled with GHS symbol, signal word, H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2.1.3). 100 mL Crack Set R1 GHS05

2.3 Other hazards

Possible hazards from physicochemical properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. H290 "May be corrosive to metals." has only relevance for higher concentrations and larger amounts. The labelling GHS05 would be creating an "OVERLABELLING" (see GHS Directive 1272/2008/EC Annex I, chapter 1.5.2.1.3., until 125 mL no labelling necessary). --- Information pertaining to particular risks to human and possible symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapours especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause after oral intake, inhalation of vapours/dust, skin contact, impairments of health when ingested in small quantities. May cause sensitization by skin contact, also in repeated contact of small amounts. May cause allergy or asthma symptoms or breathing difficulties if inhaled. - Information pertaining to particular risks to the environment Avoid contact of substance/mixture to environment.

PBT Substances

not applicable

vPvB Substances

not applicable

Other hazards

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