Note: Ingredients listed on restricted chemical lists
EC/CAS
137-26-8
Name of the chemical
Thiram
Concentration
N/A
General Information
Revision date
2015-03-20
Product name
THIRAM 24/7
CAS No.
137-26-8
1.2.1 Relevant identified uses
Plant protection agent
Emergency telephone
Agriphar Crop Solutions: +1 800 423 8569(24 hours) 800-424- ber
Icons in SDS
Company Information
company name
MacDermid Agricultural Solutions, Inc
e-mail address of the competent person responsible for the Safety Data Sheet
Regulatory.Affairs@AgripharCropSolutions.com
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H302+H332, H317, H319, H410
Hazard statements
Code
Statements
H302+H332
Harmful if swallowed or if inhaled
Section 2
SECTION 2: Hazards identification
OSHA Emergency Overview WARNING! Appearance liquid Colour white Odour No data available Hazard Summary Harmful if swallowed. Harmful if inhaled. May cause an allergic skin reaction. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects.
2.1 Classification of the substance or mixture
Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Eye irritation : Category 2A Skin sensitisation : Category 1 Acute aquatic toxicity : Category 1 Chronic aquatic toxicity : Category 1
Signal word
Warning
Hazard statements
H302 + H332 Harmful if swallowed or if inhaled H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects.
Prevention
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear eye protection/ face protection. P280 Wear protective gloves.
Response
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. P363 Wash contaminated clothing before reuse. P391 Collect spillage.
Disposal
P501 Dispose of contents/ container to an approved waste dis- posal plant.
Principle Routes of Exposure
Skin contact Eye contact Inhalation : Harmful if inhaled. Skin : May irritate skin. May cause allergic skin reaction. Eyes : Irritating to eyes. Ingestion : Harmful or fatal if swallowed. Chronic Exposure : Harmful: danger of serious damage to health by prolonged exposure if swallowed. May cause sensitisation by skin contact.
Medical Conditions Generally Aggravated by Exposure
None known. Symptoms of Overexposure : Allergic reactions irritant effects Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.