M-1 GELt

Hazard statements (CLP)

H350

Code

Statements

H350

May cause cancer

Health hazards

carcinogenicity !category 1A

Environmental hazards

Not classified

Physical hazards

Not classified

Signal word

DANGER

Hazard statements

H350 - May cause cancer

Precautionary statements

P201 - Obtain special instructions before use P281 -Use personal protective equipment as required P308 + P313 -IF exposed or concerned: Get medical advice/ attention

Supplemental label elements

P202 - Do not handle until all safety precautions have been read and understood P501 - Dispose of contents/ container to an approved waste disposal plant Unknown acute toxicity 17.5% of the mixture consists of ingredient(s) of unknown toxicity. 3.1 Substances Not Applicable 3.2 Mixtures ·, '-' compJ >hEint · ' · ·>• .. ' ·- ··--. CAS;;N() ·,: .. <· .•;' ~->-':!. ·-·· .·c. ' •. dnger;·:·,•'J0<•1· ' ' .'.''·y·· : e·· ;c,. '. " Silica, crystalline, Cristobalite 14464-46-1 10-30 Silica, cry_stalline,_ quartz 14808-60-7 10-30 Silica, crystalline, Tridymite 15468-32-3 1 - 5 Comments The exact percentage (concentration) of composition has been withheld as a trade secret .. ···-····1 4.1 First-Aid Measures Inhalation Move to fresh air. If breathing is difficult, (trained personnel should) give oxygen. Get medical attention immediately if symptoms occur. Ingestion Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. Skin contact Wash skin thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if irritation persists. Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2 Most important symptoms and effects. both acute and delayed Main symptoms Inhalation Please see Section 11. Toxicological Information for further information. Ingestion Please see Section 11. Toxicological Information for further information. Skin contact Please see Section 11. Toxicological Information for further information. Eye contact Please see Section 11. Toxicological Information for further information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician Treat symptomatically I 5.1 Extinguishing media Suitable extinguishing media Water Fog, Alcohol Foam, C02, Dry Chemical. Extinguishing media which shall not be used for safety reasons None known. 5.2 Special hazards arising from the substance or mixture Unusual fire and explosion hazards None known. Hazardous combustion products Silicon oxide. 5.3 Advice for firefighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus and full protective gear. ···.'·I 6.1 Personal precautions, protective equipment and emergency procedures Wear suitable protective equipment. Evacuate personnel to safe areas. Prevent further leakage or spillage if safe to do so. Avoid dust formation. 6.2 Environmental precautions Do not allow material to contaminate ground water system. Environmental exposure controls No information available. 6.3 Methods and materials for containment and cleaning up Methods for containment Cover powder spill with plastic sheet or tarp to minimize spreading. Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 6.4 Reference to other sections No information available. 7~Handling Cirulstoh:~g~ ·. 7.1 Precautions for safe handling Handling Avoid breathing dust; if exposed to high dust concentration, leave area immediately. Avoid contact with skin, eyes and clothing. 7.2 Conditions for safe storage. including any incompatibilities Technical measures/precautions Ensure adequate ventilation. Storage precautions Protect from moisture 8.1 Control parameters Component Information Component ACGIHTLV OSHA PEL Silica, crystalline, Cristobalite 0.025 mgfm3 see Table Z-3 Silica, crystalline, quartz 0.025 mgfm3 see Table Z-3 .. Silica, crystalline, Tridymite 0.025 mgfm3 see Table Z-3 Silica, crystalline, Cnstobalite OSHA- Final PELs- Table Z-3 Mineral Dusts (1/2)(30)/(%Si02 + 2) mg/m3 TWA, total dust; (1/2)(250)/(%Si02 + 5) mppcfTWA, respirable fraction; (1/2)(10)/(%Si02 + 2) mg/llil TWA, respirable fraction Silica, crystalline, quartz OSHA- Final PELs -Table Z-3 Mineral Dusts (30)/(%Si02 + 2) mg/m3 TWA, total dust; (250)/(%Si02 + 5) mppcf TVVA, respirable fraction; (1 O)/(%Si02 + 2) mg/rnJ TVVA, respirable fraction Silica, crystalline, Tridymite OSHA- Final PELs - Table Z-3 Mineral Dusts (1/2)(30)/(%Si02 + 2) mg/m3 TWA, total dust; (1/2)(250)/(%Si02 + 5) mppcfTVVA, respirable fraction; (1/2)(10)/(%Si02 + 2) mg/llil TVVA, respirable fraction 8.2 Exposure controls All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation. Engineering measures to reduce exposure Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye protection Tightly fitting safety goggles. Hand protection Neoprene, Nitrile. Respiratory protection All respiratory protection equipment should be used within a comprehensive respiratory protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA Respiratory Protection Standard) or local equivalent. If exposed to airborne mist/aerosol of this product, use at least a NIOSH-approved N95 half-mask disposable or re-usable particulate respirator. In work environments containing oil mist/aerosol, use at least a NIOSH-approved P95 half-mask disposable or reuseable particulate respirator. If exposed to vapors from this product use a NIOSH/MSHA-approved respirator with an Organic Vapor cartridge. •''·" --::.".;' i. ) ~o~~~ . ;>'·?\t" ;·~~ ... ~~ ~f.~{~' 9.1 Information on basic physical and chemical properties Physical state Solid Appearance Opaque Color Tan- Gray Odor Odorless Odor threshold Not applicable Property Values Remarks pH Not applicable pH@ dilution Melting/freezing point Boiling point/range No information available Flash point No information available PMCC Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not Applicable Flammability Limits in Air Upper flammability limit No information available Lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific gravity 2.3 - 2.6 Bulk density No information available Water solubility slightly soluble Solubility in other solvents Insoluble Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Log Pow No information available Explosive properties No information available Oxidizing properties No information available 9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available Density No information available 1 o. Stability and re~cthrity · · 10.1 Reactivity ASchlumbcrgerCompally ~ No specific reactivity hazards associated with this product. 10.2 Chemical stability Stable. Hazardous polymerization does not occur. 10.3 Possibility of Hazardous Reactions Hazardous polymerization Hazardous polymerization does not occur. Hazardous Reactions None known. 10.4 Conditions to avoid None known. 10.5 Incompatible materials Hydrofluoric acid (HF). 10.6 Hazardous decomposition products Silicon oxide. < ·.:·-~." .- ··, .. -_:·· .· 11.1 Information on toxicological effects Acute toxicity Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system. Repeated or prolonged inhalation of crystalline silica dust can cause delayed lung injury, and other diseases, including silicosis and lung cancer. Eye contact Dust contact with the eyes can lead to mechanical irritation. Skin contact Repeated exposure may cause skin dryness or cracking. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Component LD50 Oral LD50 Dermal LC50 Inhalation Silica, crystalline, Cristobalite No data available Silica, crystalline, quartz = 500 mg/kg ( Rat ) No data available Silica, crystalline, Tridymite No data available Component IARC Group 1 or 2 ACGIH - Carcinogens OSHA listed carcinogens NTP Silica, crystalline, Cristobalite Group 1; Monograph 68 A2 Suspected Human Present No data available [1997] Carcinogen Monograph 68 [1997] (listed under Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources) Silica, crystalline, quartz Group 1; Monograph 1 OOC f:\2. Suspected Human Present Known Human Carcinogen [in preparation] Carcinogen Group 1; Monograph 68 [1997] Monograph 1 OOC [in preparation] (listed under Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources); Monograph 68 [1997] Silica, crystalline, Tridymite Group 1; Monograph 68 No data available Present No data available [1997] Monograph 68 [1997] (listed under Crystalline silica) Sensitization This product does not contain any components suspected to be sensitizing. Mutagenic effects No evidence of mutagenic properties. Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer in humans, if inhaled. Reproductive toxicity No evidence of toxicity to reproduction. Developmental toxicity Not known to cause birth defects or have a deleterious effect on a developing fetus. Routes of exposure Skin contact. Inhalation. Eye contact. Routes of entry Inhalation. Specific target organ toxicity Not classified (single exposure) Specific target organ toxicity Not classified. (repeated exposure) Aspiration hazard Not Applicable. 12.1 Toxicity Toxicity to algae See component information below. Toxicity to fish See component information below. Toxicity to daphnia and other aquatic invertebrates See component information below. Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other aquatic invertebrates Silica, crystalline, Cristobalite No information available 14464-46-1 ( 10- 30) Silica, crystalline, quartz No information available 14808-60-7 ( 10-30) Silica, crystalline, Tridymite No information available 15468-32-3 ( 1 - 5 ) 12.2 Persistence and degradabilitv No product level data available. 12.3 Bioaccumulative potential No product level data available. 12.4 Mobilitv in soil No information available. 12.5 Results of PBT and vPvB assessment This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT) This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB) 12.6 Other adverse effects. None known. 13.1 Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state and local regulations. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. I···· 14.1 UN Number UN No. (DOT) Not regulated UN No. (TOG) Not regulated UN/10 No. (ADR/RID/ADN/ADG) Not regulated UN No. (IMDG) Not regulated UN No. (ICAO) Not regulated 14.2 Proper shipping name Not regulated for transportation by DOT, TOG, IMDG and ICAO/IATA. 14.3 Hazard class{esl DOT Hazard class Not regulated TOG Hazard class Not regulated ADRIRID/ADN/ADG Hazard class Not regulated IMDG Hazard class Not regulated ICAO Hazard class/division Not regulated 14.4 Packing group DOT Packing group Not regulated TOG Packing group Not regulated ADRIRID/ADN/ADG Packing group Not regulated IMDG Packing group Not regulated ICAO Packing group Not regulated 14.5 Environmental hazard No 14.6 Special precautions Not Applicable \_, .. International inventories USA (TSCA) Complies Canada (DSL) Complies European Union (EINECS and ELINCS) Does not Comply Philippines (PICCS) Does not Comply Japan (ENCS) Does not Comply China (IECSC) Does not Comply Australia (AICS) Does not Comply Korean (KECL) Does not Comply New Zealand (NZioC) Complies U.S. Federal and State Regulations SARA 311/312 Hazard Categories Delayed (chronic) health hazard. Component SARA 302 I TPQs SARA 313 CERCLA RQ Silica, crystalline, Cristobalite N/A Silica, crystalline, quartz N/A Silica, crystalline, Tridymite N/A State Comments Proposition 65: This product contains chemical(s) considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 to cause cancer and/or reproductive toxicity. See table under U.S. Federal and State Regulations for the specific chemicals. Silica, crystalline, quartz carcinogen 16. Other informatiqn · Supersedes date 18/May/2012 Revision date 09/0ct/2014 The following sections have been All sections. Updated according to GHS/CLP. revised HMIS classification Health 1* Flammability 0 Physical hazard 0 PPE E N/A- Not Applicable, N/D - Not Determined. Disclaimer The information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier's own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier's warranty obligations and buyer's sole remedies are as stated in separate agreement between the parties. M-1-Xt II (All grades) ..... : 1.1 Product identifier Product name M-1-Xt II (All grades) Product code PID11307 1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended Use Drilling fluid additive. Lost circulation material. Uses advised against Consumer use 1.3 Details of the supplier of the safety data sheet Supplier M-1 L.L.C. P.O.Box 42842 Houston, TX 77242 www.miswaco.slb.com Telephone: 1 281-561-1511 M-1 SWACO, A Schlumberger Company 200- 125, 9th Avenue SE Calgary, Alberta T2G OP6, Canada Telephone: 1-780-962-8221 Prepared by Global Regulatory Compliance- Chemicals (GRC- Chemicals) , Bethicia Prasek 1.4 Emergency Telephone Number Emergency telephone (24 Hour) Australia +61 2801 44558, Asia Pacific +65 31581074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 5611600 2.1 Classification of the substance or mixture GHS - Classification Health hazards !carcinogenicity !category 1A Environmental hazards Not classified Physical Hazards !combustible dust 1- 2.2 Label elements Signal word DANGER Hazard statements H350 - May cause cancer Precautionary statements P201 - Obtain special instructions before use P210- Keep away from heat/sparks/open flames/hot surfaces.- No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P280- Wear protective gloves/ protective clothing/ eye protection/ face protection P308 + P313 -IF exposed or concerned: Get medical advice/ attention P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P403 + P235 - Store in a well-ventilated place. Keep cool Supplementarv precautionary statements P202 - Do not handle until all safety precautions have been read and understood P241 - Use explosion-proof electrical/ ventilating/lighting/ equipment P242 - Use only non-sparking tools P243- Take precautionary measures against static discharge P261 -Avoid breathing dust! fume/ gas/ mist! vapors/ spray P272 - Contaminated work clothing should not be allowed out of the workplace P303 + P361 + P353- IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P333 + P313 - If skin irritation or rash occurs: Get medical advice/ attention P363 - Wash contaminated clothing before reuse P501 - Dispose of contents/ container to an approved waste disposal plant Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity. I