General Information
Revision date
2015-12-30
Product name
GEL EXt
1.2.1 Relevant identified uses
Drilling fluid additive. Bentonite extender
supplier name
M-1 L.L.C
Icons in SDS
Company Information
company name
M-1 L.L.C
GHS Information
Signal word
WARNING
Section 2
Health hazards
Not classified
Environmental hazards
Not classified
Physical hazards
combustible dust 1-
Signal word
WARNING
Hazard statements
May form combustible dust concentrations in air
Precautionary statements
P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment P243 -Take precautionary measures against static discharge Unknown acute toxicity 93% of the mixture consists of ingredient(s) of unknown toxicity. I ··a: Composition/infQrnuatidrf ' . : ... : ~- ()n 111grl;jdients.·•······. 3.1 Substances Not Applicable 3.2 Mixtures Comments The exact percentage (concentration) of composition has been withheld as a trade secret 4.1 First-Aid Measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs. Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Get medical attention immediately if symptoms occur. Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2 Most important symptoms and effects. both acute and delayed General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible. Main symptoms Inhalation Please see Section 11. Toxicological Information for further information. Ingestion Please see Section 11. Toxicological Information for further information. Skin contact Please see Section 11. Toxicological Information for further information. MiSW~~ Eye contact Please see Section 11. Toxicological Information for further information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician Treat symptomatically •.s .. Fire.:fighting.mea$lires· .·.·· 5.1 Extinguishing media Suitable extinguishing media Water Fog, Alcohol Foam, COz, Dry Chemical. Extinguishing media which shall not be used for safety reasons None known. 5.2 Special hazards arising from the substance or mixture Unusual fire and explosion hazards Suspended dust may present a dust explosion hazard. Hazardous combustion products Carbon oxides (COx). 5.3 Advice for firefighters Special protective equipment for fire-fighters As in any fire, wear self-contained breathing apparatus and full protective gear. Special Fire-Fighting Procedures Containers close to fire should be removed immediately or cooled with water. 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. See also section 8. 6.2 Environmental precautions The product should not be allowed to enter drains, water courses or the soil. Environmental exposure controls Avoid release to the environment. 6.3 Methods and materials for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water. 6.4 Reference to other sections See section 13 for more information. 7. Handling and storage 7.1 Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. 7.2 Conditions for safe storage. including any incompatibilities Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed. Keep airborne concentrations below exposure limits. Storage precautions Keep away from open flames, hot surfaces and sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated place. 8.1 Control parameters Exposure limits Control as an ACGIH particulate not otherwise specified (PNOS): 10 mg/m3 (lnhalable); 3 mg/m3 (Respirable) and an OSHA particulate not otherwise regulated (PNOR): 15 mg/m3 (Total); 5 mg/m3 (Respirable). Com onent ACGIH TLV OSHA PEL Polyacrylate polyacrylamide blend Not Determined 8.2 Exposure controls All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation. Engineering measures to reduce exposure Ensure adequate ventilation. Personal protective equipment Eye protection Tightly fitting safety goggles. Hand protection Wear chemical resistant gloves such as nitrile or neoprene. Respiratory protection All respiratory protection equipment should be used within a comprehensive respiratory protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA Respiratory Protection Standard) or local equivalent. Use NIOSH approved respirator with dust and mist protection (3M 8210). If dust concentration exceeds 5 times the exposure limit, wear an approved HEPA respirator Skin and body protection Wear suitable protective clothing. Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and wash contaminated clothing before re-use. · 9. Physical and chemical prop(;}r1:ies I 9.1 Information on basic physical and chemical properties Physical state Solid powder Appearance Opaque Color White Odor Odorless Odor threshold Not applicable Propertv Values
Remarks
MiSWA~ · pH No information available pH @dilution No information available Melting/freezing point No information available Boiling point/range No information available Flash point Does not flash PMCC Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not Applicable Flammability Limits in Air Upper flammability limit No information available Lower flammability limit No information available Vapor pressure OmmHg Vapor density Not applicable Specific gravity 1.3 Bulk density No information available Water solubility Appreciable Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Log Pow No information available Explosive properties Suspended dust may present a dust explosion hazard Oxidizing properties None known.
Further information
Pour point No information available Molecular weight No information available VOC content(%) None Density No information available 10.1 Reactivity No specific reactivity hazards associated with this product. 10.2 Chemical stability Stable under normal temperature conditions and recommended use. 10.3 Possibility of Hazardous Reactions Hazardous polymerization Hazardous polymerization does not occur. 10.4 Conditions to avoid Heat, flames and sparks. Avoid dust formation. 10.5 Incompatible materials Strong oxidizing agents. Acids. Bases. 10.6 Hazardous decomposition products Carbon oxides (COx). 11. Toxicological h1formatioh 11.1 Information on toxicological effects MiSWAC~ Acute toxicity Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough. Eye contact Dust may cause mechanical irritation. Skin contact Repeated exposure may cause skin dryness or cracking. Ingestion Irritant; may cause pain or discomfort to mouth, throat and stomach. Com onent LD50 Oral LD50 Dermal LC50 Inhalation Polyacrylate polyacrylamide blend No data available Com onent NTP Polyacrylate polyacrylamide blend No data available Sensitization This product does not contain any components suspected to be sensitizing. Mutagenic effects No evidence of mutagenic properties. Carcinogenicity No evidence of carcinogenic properties. Reproductive toxicity No evidence of toxicity to reproduction. Developmental toxicity Not known to cause birth defects or have a deleterious effect on a developing fetus. Routes of exposure Inhalation. Skin contact. Eye contact. Routes of entry Inhalation. Specific target organ toxicity Not classified (single exposure) Specific target organ toxicity Not classified. (repeated exposure) Target organ effects Lungs. Aspiration hazard Not Applicable. ',,-· ~ ~- _j:~ - . 12.1 Toxicity Toxicity to algae See component information below. Toxicity to fish See component information below. Toxicity to daphnia and other aquatic invertebrates See component information below. Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other aquatic invertebrates Polyacrylate polyacrylamide blend No information available ( 60 -100)_ 12.2 Persistence and degradabilitv No product level data available. 12.3 Bioaccumulative potential No data available. 12.4 Mobility in soil No information available. 12.5 Results of PBT and vPvB assessment This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT) This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB) 12.6 Other adverse effects. None known. 13.1 Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state and local regulations. Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal. 14.1 UN Number Not regulated UN No. (DOT) Not regulated UN/ID No. (ADRIRID/ADN/ADG) Not regulated UN No. (IMDG) Not regulated UN No. (ICAO) Not regulated 14.2 Proper shipping name 14.3 Hazard class(es) DOT Hazard class Not regulated ADRIRID/ADN/ADG Hazard class Not regulated IMDG Hazard class Not regulated ICAO Hazard class/division Not regulated 14.4 Packing group DOT Packing group Not regulated ADRIRID/ADN/ADG Packing group Not regulated IMDG Packing group Not regulated ICAO Packing group Not regulated 14.5 Environmental hazard No 14.6 Special precautions Not Applicable 15. Regulatory Information· International inventories USA (TSCA) Complies Canada (DSL) Complies. European Union (EINECS and ELINCS) Does not Comply Philippines (PICCS) Does not Comply Japan (ENCS) Does not Comply China (IECSC) Complies Australia (AICS) Does not Comply Korean (KECL) Does not Comply New Zealand (NZioC) Complies SARA 311/312 Hazard Categories Not a SARA 311/312 hazard. SARA 302 I TPQs SARA 313 CERCLARQ N/A State Comments Proposition 65: This product is not known to contain chemicals considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer and/or reproductive toxicity at levels that are expected to pose a significant risk under anticipated use conditions. This product may not be distributed or used in Canada. . ... ······I ·. ' ~ ' .. Supersedes date 08/Jun/2015 Revision date 30/Dec/2015 The following sections have been 1, 2. Hazards Identification 15, revised: HMIS classification Health 1 Flammability 1 Physical hazard 0 PPE E N/A- Not Applicable, N/D - Not Determined. tA mark of M-1 L.L.C. MiSWA~ Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other