Break Away

Hazard statements (CLP)

H226, H302+H312+H332, H314, H335, H336, H341, H351, H371, H373

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA Emergency Overview Appearance liquid Color clear Odor strong, solvent-like GHS Classification Flammable liquids Category 3 Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 4 Acute toxicity (Dermal) Category 4 Skin corrosion Category 1A Serious eye damage Category 1 Germ cell mutagenicity Category 2 Carcinogenicity Category 2 Specific target organ toxicity - Category 2 single exposure Specific target organ toxicity - Category 3 (Respiratory system, Central nervous system) single exposure Specific target organ toxicity - Category 2 repeated exposure

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H371 May cause damage to organs. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P281 Use personal protective equipment as required.

Response

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/container in accordance with local regulation.

Potential health effects

Carcinogenicity IARC Group 2B Possibly carcinogenic to humans dichloromethane 75-09-2 ACGIH Confirmed animal carcinogen with unknown relevance to humans dichloromethane 75-09-2

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 4 Skin corrosion : Category 1A Serious eye damage : Category 1 Germ cell mutagenicity : Category 2 Carcinogenicity : Category 2 Specific target organ toxicity - : Category 2 single exposure Specific target organ toxicity - : Category 3 (Respiratory system, Central nervous system) single exposure Specific target organ toxicity - : Category 2 repeated exposure