Note: Ingredients listed on restricted chemical lists
EC/CAS
1333-86-4
Name of the chemical
carbon black
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2014-08-08
Product name
XJ-150
Icons in SDS
Company Information
company name
LORD Japan Inc
GHS Information
Signal word
DANGER
Section 2
2.1 Classification of the substance or mixture
Flammable liquids Category 3 Acute toxicity Oral Category 5 Acute toxicity Dermal Category 5 Acute toxicity Inhalation - Dust and Mist Category 2 Acute toxicity Inhalation - Vapours Category 3 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Respiratory sensitization Category 1 Carcinogenicity Category 2 Reproductive toxicity Category 1B Specific target organ systemic toxicity (single exposure) Category 3 Specific target organ systemic toxicity (single exposure) Category 1 Central nervous system, Kidney, Liver, Respiratory system Specific target organ systemic toxicity (repeated exposure) Category 2 Ears, Liver, Kidney Specific target organ systemic toxicity (repeated exposure) Category 1 Respiratory system, Nervous system, Lungs Hazardous to the aquatic environment - acute hazard Category 2 Hazardous to the aquatic environment - chronic hazard Category 2
Signal word
DANGER
Hazard statements
Flammable liquid and vapor. May be harmful if swallowed. May be harmful in contact with skin. Fatal if inhaled. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. May damage fertility or the unborn child. May cause drowsiness or dizziness. May cause respiratory irritation. Causes damage to organs.(Central nervous system, Kidney, Liver, Respiratory system) May cause damage to organs through prolonged or repeated exposure.(Ears, Liver, Kidney) Causes damage to organs through prolonged or repeated exposure.(Respiratory system, Nervous system, Lungs) Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Wear respiratory protection. In case of inadequate ventilation wear respiratory protection. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Response
In case of fire: refer to section 5 of SDS for extinguishing media. Immediately call a POISON CENTER or doctor/physician. Specific treatment is urgent (see supplemental first aid instructions on this label). IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Collect spillage.
Storage
Store in a well-ventilated place. Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal
Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular locality.
2.3 Other hazards
This product contains component(s) which have the following warnings; however based on the GHS classification criteria of your country or locale, the product mixture may be outside the respective category(s). Acute: Vapor harmful; may affect the brain or nervous system causing dizziness, headache or nausea. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. In elevated-temperature applications, product may release vapors that may produce cyanosis in the absence of sufficient ventilation or adequate respiratory protection. Animal tests have indicated that respiratory sensitization can result from skin contact with certain isocyanates. Allergic conditions can occur in certain individuals with high sensitivity to isocyanates; this may result in asthma-like symptoms. Possible irritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause lung damage. May be absorbed through the skin in harmful amounts. Symptoms of inhalation exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Silane monomer 1 in this product may decompose to become ethanol. For ethanol, the OSHA PEL is 1000 ppm, and the ACGIH TLV-TWA is 1000 ppm. Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. Chronic: Prolonged or repeated contact may result in dermatitis. Repeated or prolonged solvent overexposure may result in permanent central nervous system damage. May cause liver or kidney damage. May affect the gastrointestinal system. May affect the blood and blood-forming organs. May cause long-term lung damage. The nitrogen substituted aromatic in this product gave positive results for mutagenicity in an Ames Assay study while two other mutagenicity studies proved negative. IARC has designated carbon black as Group 2B - inadequate evidence for carcinogenicity in humans, but sufficient evidence in experimental animals. Ethylbenzene has been classified by IARC as a possible human carcinogen (Group 2B) and reported by NTP to show clear evidence for carcinogenicity in animals.