CLP

Hazard statements (CLP)

H225, H226, H304, H312, H315, H317, H319, H332, H334, H335, H336, H351, H361d, H373, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

can is relieved 50 interfere laboratorio@azichem.com and labeling from with any the of liability 723 chemicals metabolism arising of from xylenes. 150 improper uses. 6.3. medical ISOBUTYL Solubility ADR / RID, IMDG, IATA: Methods advice/attention. in and ACETATE water material for containment and cleaning 100 UN 1263 up - 1000 mg/l - Provide INHALATION: Rapidly Substances IATA Type VLEP DGR: Risk degradable Results: Species: appointed of explosion International subject Remove Causes rabbit staff Country to on exportation FRA (New with victim contact to with: serious Air adequate Transport Zealand eye TWA/8h fresh 241 damage reporting strong White) training air, away Association pursuant oxidising on how 50 from the Dangerous to use chemical to agents.May Regulation accident scene. Goods STEL/15min react (EU) violently 723 Regulation products. 649/2012: In the event with: of alkaline 150 respiratory hydroxides,potassium

Remarks

/ Observations symptoms (coughing, tert-butoxide.Forms wheezing, 1.4. - IC50: 9.1. breathing Collect None Emergency Information TLV Immobilization explosive the difficulty, TOLUENE Routes telephone leaked mixtures on basic of exposure: product asthma) GRC Concentration with: physical number into air. keep a suitable oral mg/m3 the and victim 950 50% chemical container. in a comfortable properties ppm 200 Evaluate position the compatibility mg/m3 950 for breathing. of the If container ppm 200 necessary to administer be used, by oxygen. checking If the section subject 10. stops Absorb the 14.2. UN proper shipping name As RESPIRATORY - CALCULATION IMDG: from NDS/NDSCh AK Certain Results: 24 International August drugs METHODS OR negative. 2023 SKIN POL HUN Maritime and adequate SENSITISATION other NOAEL FOR Code industrial CLASSIFICATION 0,03 241 training maternal) for dangerous products is required 125 50 can mg/kg goods before interfere body industrial weight/day; with 0,09 723 the or metabolism professional NOAEL (malformations) 150 of use the toluene. 350 mg/kg body weight/day; NOAEL breathing, remainder ISOBUTYL Conditions administer with ACETATE inert to avoid absorbent artificial respiration material. Get medical advice/attention For Chemical IMO TLV VLEP urgent International development) and inquiries physical Maritime refer ROU ITA hazards 250 to mg/kg Organization Product 241 body weight/day classification 50 Osp derives Pediatrico from 0,15 criteria 723 Bambino established Gesù 150 ROMA by the CLP 06 68593726 Regulation, Annex I, Part 2. The data for Make Properties Solubility Substances ADR / RID sure in the water subject leakage to the PAINT or PAINT RELATED MATERIAL site Rotterdam is well aired Convention Contaminated Value material 1000 - should 10000 be mg/l disposed of in compliance Information with the provisions set forth in point 13 ACUTE Sensitising evaluation Rescuer Appearance Avoid Rapidly None overheating INDEX VLE TOXICITY degradable protection Avoid bunching of electrostatic charges Identifier of for chemical-physical the skin in PRT Annex VI of properties CLP 241 are reported 50 Az. in Osp liquid Avoid all sources of ignition section Univ 723 Foggia FOGGIA: 150 800183459 Sensitising IMDG STOT Health LC50 Other NDS/NDSCh hazards SINGLE Lethal hazards for the Concentration EXPOSURE Product respiratory POL classification PAINT or PAINT RELATED MATERIAL 50% system 240 is based on calculation Az. Osp. methods Cardarelli" 720 as per Annex NAPOLI I of 081-5453333 CLP, Part 3, unless determined otherwise in Section Colour IATA Reference to other sections PAINT or PAINT RELATED MATERIAL grey ATE LD50 It Odour ISOBUTYL SALICYLIC Substances is good practice TLV Inhalation Lethal dose ACETATE ACID subject for to rescuers vapours) 50% ROU of the mixture the Stockholm lending Convention 241 support to a person 50 Policlinico characteristic who has been exposed to a chemical substance or to a mixture to wear personal 20 "Umberto mg/l TOLUENE 723 I" ROMA: 150 06-49978000 On Threshold ATE Skin Does Environmental protective Any Melting Rapidly None Avoid OEL: WEL the (Oral) information sensitization not Occupational basis point degradable meet exposure equipment of Limit of the the freezing hazards available on personal mixture Value classification to: The GBR Exposure sources point nature Product data, Level protection of heat,naked the criteria classification of such and protection 724 product for this does disposal flames. is depends is hazard based not 150 Policlinico contain not given class on calculation available 90% in on sections any Not "A PBT the in 14 hazard classified 903 Gemelli" or methods giorni and level vPvB no ROMA EU Method in significant as percentage of the substance per 187 Annex 06-3054343 C.9) component) I of than CLP, 0,1% or mixture, on the type of exposure and on , unless determined otherwise in ATE the Section Initial PBT Transport Incompatible Type OEL extent Dermal) boiling Persistent, 12 of the point contamination hazard of the bioaccumulative materials mixture Country EU class(es) TWA/8h In the absence of other 115 more specific °C indications, use of disposable gloves in the event of possible contact 241 and toxic 50 Az. Osp. >2000 Careggi" STEL/15min 723 mg/kg U.O. Tossicologia 150 Medica Remarks FIRENZE Observations 055-7947819 with The PEC Flammability Healthcare Bioaccumulative ACGIH product body fluids Predicted SALICYLIC controls contains is recommended environmental ACID potential substances Concentration mg/m3 with endocrine disrupting For the type of PPE not suitable ppm 50 Centro properties available Nazionale for the characteristics of the substance or mixture, see section 8 mg/m3 in di concentration Informazione ppm 150 ≥ 0,1% Tossicologica PAVIA: 0382-24444 SECTION ADR / RID SALICYLIC Changes PEL TLV Predicted Method Based to 7 previous ACID on Handling OECD exposure available BGR review Class: 3 429 level data, and the 192 storage substance does 50 Osp Label: 3 not present Niguarda specific 384 Ca' Granda target organ MILANO 100 toxicity 02-66101029 effects SKIN for single exposure and is not classified Lower ISOBUTYL Workers explosive exposed ACETATE limit to this chemical agent must not undergo not available health checks, provided that available risk-assessment data prove that the risks Upper The PMT: AGW related Most Incompatible following explosive Persistent, important to the workers' XYLENE Reliability under sections the (Klimisch with limit symptoms relevant mobile DEU strong were and CLP health oxidants,nitrates,strong score) modified and and safety toxic hazard 190 2 effects, class are both modest acute 50 Azienda Ospedaliera acids,strong and not and available that delayed the 98/24/EC bases 760 directive is respected Papa Giovanni 200 XXII SKIN BERGAMO: 800883300 Precautions for safe handling 04 PNEC MAK 09 / LD50 Species Predicted / 12 (Dermal) mouse no / DEU 14 effect CBA) concentration 190 50 Azienda 4350 Ospedaliera SALICYLIC mg/kg 760 Rabbit Integrata ACID 200 VERONA: SKIN 800011858 Flash Composition/information on ingredients XYLENE Hazardous point decomposition products 33 Predicted STOT REACH Specific Auto-ignition Partition VLA - ATE Routes REPEATED coefficient Regulation no-effect Dermal) temperature of exposure EXPOSURE on n-octanol/water ESP concentration

2.2 Label elements

ACETATE of soils pursuant and sediments to EC Regulation (HSDB, 2019).

Hazard pictograms

Classified carbon) България (EU) on in other 2017/776 Group hazards 3 (not (X Atp. Cargo: classifiable CLP) НАРЕДБА as a human № 13 carcinogen) 11,92 % CLP - Regulation: ОТ Maximum 30 ДЕКЕМВРИ 190,67 by the quantity: International C g/litre 2003 220 Г. L ЗА Agency ЗАЩИТА for Research НА Packaging РАБОТЕЩИТЕ on Cancer instructions: ОТ (IARC). РИСКОВЕ, 366 8.2. 14. Exposure Aquatic Regulation In infants Based The US Chronic controls on (EU) Environmental and 3 children, it Hazardous the 2018/669 weight of (XI Protection evidence is rapidly absorbed Atp. Passengers: CLP) of Agency СВЪРЗАНИ С ЕКСПОЗИЦИЯ НА ХИМИЧНИ АГЕНТИ ПРИ РАБОТА (изм. ДВ. бр.28 от 2 to the aquatic available (EPA) through environment, data affirms determined the skin with chronic that Maximum "the by data expert a greater quantity: is judgment, toxicity, inadequate risk of category 60 L toxic effects. the for substance an assessment 3 Packaging is not classified of the instructions: carcinogenic for the 355 acute potential". 12.5. EC Results of PBT 203-745-1 and vPvB assessment Based 15. Regulation H225 CAUSED BY EXPOSURE on inhalation the available (EU) toxicity 2019/521 data, (XII class. Highly IN flammable product Special Atp. CLP) THE EVENT

Contains

provision: Април 2024г.) liquid OF and FIRE vapour. the following endocrine A3, A72, A192 disruptors in concentrations of 0.1% or greater by weight that may CAS Excess Information H226 pressure on likely may routes 110-19-0 form in of containers exposure Flammable exposed liquid to and fire vapour. at a risk of explosion. Do not breathe combustion products. DEU As have 16. the On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. Delegated endocrine use of adequate Regulation disrupting Deutschland technical (UE) effects 2018/1480 equipment on humans (XIII WirkungDosisNOAELMAK-und must and Atp. cause always CLP) adverse take priority effects over on BAT-Werte-Liste personal the exposed protective individual 2024 equipment, Ständige or his or make Senatskommission her progeny: sure that the workplace zur Prüfung is SALICYLIC H351 Regulation aired Method: through ACID (EU) OECD effective 2019/1148 Suspected of causing cancer. 14.7. well 17. Maritime transport in 402 bulk local according aspiration. to gesundheitsschädlicher IMO instruments Arbeitsstoffe ESP When 18. Delegated H361d choosing Reliability Regulation personal (Klimisch España protective (UE) score): 2020/217 Suspected of damaging the unborn child. 1 equipment, (XIV Límites Atp. ask CLP) de your exposición chemical profesional substance para supplier agentes for advice. químicos en España 2024 ... / >> XYLENE Methylene diphenyl diisocyanate Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 2,4-diisocyanato-1-methylbenzene TOLUENE As from 24 August 2023 adequate training is required before industrial or professional use. Identification x = Conc. %

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. EUH204 Contains isocyanates. May produce an allergic reaction.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P331 Do NOT induce vomiting. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER / doctor / . . . P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER / doctor / . . .

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product contains substances with endocrine disrupting properties in concentration ≥ 0,1%: SALICYLIC ACID 3.2. Mixtures

2.1 Classification of the substance or mixture

training (maternal): for dangerous products is required 125 50 can mg/kg goods before interfere body industrial weight/day; with 0,09 723 the or metabolism professional NOAEL (malformations): 150 of use. the toluene. 350 mg/kg body weight/day; NOAEL 10.4. breathing, remainder ISOBUTYL Conditions administer with ACETATE inert to avoid absorbent artificial respiration. material. Get medical advice/attention. For - Chemical IMO: TLV VLEP urgent International (development): and inquiries physical Maritime refer ROU ITA hazards: 250 to mg/kg Organization Product 241 body weight/day. classification 50 Osp. derives Pediatrico from 0,15 criteria 723 Bambino established Gesù 150 ROMA: by the CLP 06 68593726 Regulation, Annex I, Part 2. The data for Make Properties Solubility Substances ADR / RID: sure in the water subject leakage to the PAINT or PAINT RELATED MATERIAL site Rotterdam is well aired. Convention: Contaminated Value material 1000 - should 10000 be mg/l disposed of in compliance Information with the provisions set forth in point 13. ACUTE Sensitising - evaluation Rescuer Appearance Avoid Rapidly None overheating. INDEX: VLE TOXICITY degradable protection Avoid bunching of electrostatic charges. Identifier of for chemical-physical the skin in PRT Annex VI of properties CLP 241 are reported 50 Az. in Osp. liquid Avoid all sources of ignition. section Univ. 9. 723 Foggia FOGGIA: 150 800183459 2.3. Sensitising IMDG: STOT - Health LC50: Other NDS/NDSCh - hazards: SINGLE Lethal hazards for the Concentration EXPOSURE Product respiratory POL classification PAINT or PAINT RELATED MATERIAL 50% system 240 is based on calculation Az. Osp. methods "A. Cardarelli" 720 as per Annex NAPOLI: I of 081-5453333 CLP, Part 3, unless determined otherwise in Section 6.4. Colour IATA: Reference to other sections PAINT or PAINT RELATED MATERIAL grey ATE - 11. LD50: It Odour ISOBUTYL SALICYLIC Substances is good practice TLV (Inhalation Lethal dose ACETATE ACID subject for to rescuers - vapours) 50% ROU of the mixture: the Stockholm lending Convention: 241 support to a person 50 Policlinico characteristic who has been exposed to a chemical substance or to a mixture to wear personal > 20 "Umberto mg/l TOLUENE 723 I" ROMA: 150 06-49978000 On Threshold ATE Skin Does - Environmental protective Any Melting Rapidly None Avoid OEL: WEL the (Oral) information sensitization not Occupational basis point degradable meet exposure equipment. of Limit of the the / freezing hazards: available on personal mixture: Value classification to: The GBR Exposure sources point nature Product data, Level protection of heat,naked the criteria classification of such and protection 724 product for this does disposal flames. is depends is hazard based not 150 Policlinico contain not given class on calculation available > 90% in on sections any Not "A. PBT the in 14 hazard classified 903 Gemelli" or methods giorni 8 and level vPvB (no ROMA: (EU 13. Method in significant as percentage of the substance per 187 Annex 06-3054343 C.9) component) ≥ I of than CLP, 0,1%. or mixture, on the type of exposure and on Part 4, unless determined otherwise in 14.3. ATE 10.5. the - Section Initial PBT: Transport Incompatible Type OEL extent (Dermal) boiling Persistent, 12. of the point contamination. hazard of the bioaccumulative materials mixture: Country EU class(es) TWA/8h In the absence of other 115 more specific °C indications, use of disposable gloves in the event of possible contact 241 and toxic 50 Az. Osp. >2000 "Careggi" STEL/15min 723 mg/kg U.O. Tossicologia 150 Medica Remarks FIRENZE: / Observations 055-7947819 12.3. with The - PEC: Flammability Healthcare Bioaccumulative ACGIH product body fluids Predicted SALICYLIC controls contains is recommended. environmental ACID potential substances Concentration mg/m3 with endocrine disrupting For the type of PPE not suitable ppm 50 Centro properties available Nazionale for the characteristics of the substance or mixture, see section 8. mg/m3 in di concentration Informazione ppm 150 ≥ 0,1%: Tossicologica PAVIA: 0382-24444 SECTION ADR / RID: SALICYLIC - Changes PEL: TLV Predicted Method: Based to 7. previous ACID on Handling OECD exposure available BGR review: Class: 3 429 level data, and the 192 storage substance does 50 Osp. Label: 3 not present