General Information
Version
1.0
Revision date
2013-01-16
Product name
Phosphine
Chemical name
Phosphine
CAS No.
7803-51-2
REACH No
01-2119462840-39
1.2.1 Relevant identified uses
Industrial and professional. Perform risk assessment prior to use Use as an Intermediate (transported, on-site isolated). Use for electronic component manufacture. Using gas alone or in mixtures for the calibration of analysis equipment. Using gas as feedstock in chemical processes Formulation of mixtures with gas in pressure receptacles
1.2.2. Uses advised against
Consumer use
supplier name
Linde Gas Benelux B.V
Emergency telephone
+31 (0) 30 2748888
Icons in SDS
Company Information
company name
Linde Gas Benelux B.V
e-mail address of the competent person responsible for the Safety Data Sheet
sheq.lg.nl@linde.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H220, H280, H314, H318, H330, H335, H400
Hazard statements
Code
Statements
H220
Extremely flammable gas
Section 2
SECTION 2: Hazards identification
Classification according to Regulation (EC) No 1272/2008 as amended Classification of the substance or mixture
Contains
Phosphine
Signal word
Danger
Hazard statements
H220: Extremely flammable gas. H280: Contains gas under pressure; may explode if heated. H314: Causes severe skin burns and eye damage. H330: Fatal if inhaled. H400: Very toxic to aquatic life.
Prevention
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260: Do not breathe gas/vapors. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P303+P361+P353+P315 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/ shower. Get immediate medical advice/attention. P304+P340+P315 IF INHALED Remove person to fresh air and keep comfortable for breathing. Get immediate medical advice/attention. P305+P351+P338+P315 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. P377 Leaking gas fire Do not extinguish, unless leak can be stopped safely P381: Eliminate all ignition sources if safe to do so.
Storage
P403: Store in a well-ventilated place. P405: Store locked up.
Disposal
None.
Supplemental label elements
EUH071 Corrosive to the respiratory tract
2.3 Other hazards
Contact with evaporating liquid may cause frostbite or freezing of skin. Spontaneously flammable in air. Spontaneously flammable in air.
2.1 Classification of the substance or mixture
Classification according to Directive 67/548/EEC or 1999/45/EC as amended. F+; R12 R17 T+; R26 C; R34 N; R50 The full text for all R-phrases is displayed in section 16. Classification according to Regulation (EC) No 1272/2008 as amended. Physical Hazards Flammable gas Category 1 H220: Extremely flammable gas. Gases under pressure Liquefied gas H280: Contains gas under pressure; may explode if heated. Health Hazards Acute toxicity (Inhalation - gas) Category 1 H330: Fatal if inhaled. Skin corrosion Category 1B H314: Causes severe skin burns and eye damage. Serious eye damage Category 1 H318: Causes serious eye damage. Specific Target Organ Toxicity - Category 3 H335: May cause respiratory irritation. Single Exposure Environmental Hazards Acute hazards to the aquatic Category 1 H400: Very toxic to aquatic life. environment
