Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
N/A
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2016-12-07
Product name
LaPolla Isocyanate
1.2.1 Relevant identified uses
A component for the production of spray insulation foam
supplier name
Lapolla Industries, Inc
Emergency telephone
CARECHEM (866) 928-0789
Icons in SDS
Company Information
company name
Lapolla Industries, Inc
e-mail address of the competent person responsible for the Safety Data Sheet
sds@lapolla.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
Classification (GHS-US)
Acute toxicity (inhalation) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 2 H315 Causes skin irritation Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation Respiratory sensitization Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin sensitization Category 1 H317 May cause an allergic skin reaction Specific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritation
Hazard statements
see section 16 : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation
2.2 Label elements
GHS-US labeling
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Precautionary statements
P261 - Avoid breathing vapors, spray, mist P264 - Wash hands, forearms and face thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear eye protection, protective clothing, protective gloves, face shield P284 - [In case of inadequate ventilation] wear respiratory protection P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P304+P341 - If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a doctor, a POISON CENTER if you feel unwell P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P342+P311 - If experiencing respiratory symptoms: Call a doctor, a POISON CENTER 07 December 2016 EN (English US) P362+P364 - Take off contaminated clothing and wash it before reuse P363 - Wash contaminated clothing before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
Other hazards which do not result in classification
Inhalation may cause irritation, cough, and shortness of breath. Prolonged exposure to small concentrations may result in pulmonary edema. 2.4.
Ingredient(s) with unknown acute toxicity
Not applicable