Genfarm Bromo 200 Herbicide

Hazard statements (CLP)

H227, H304, H317, H331, H336, H361, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this MSDS. R22, R23, R43, R63, R65, R66, R67, R50/53. Harmful if swallowed. Toxic by inhalation. May cause sensitisation by skin contact. Possible risk of harm to the unborn child. Harmful: May cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H227: Combustible liquid. AUH066: Repeated exposure may cause skin dryness or cracking. H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H331: Toxic if inhaled. H336: May cause drowsiness or dizziness. H361: Suspected of damaging fertility or the unborn child. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S20, S24, S28, S38, S45, S46, S51, S60, S61, S63, S1/2, S36/37/39. When using, do not eat or drink. Avoid contact with skin. After contact with skin, wash immediately with plenty of . In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately (show this MSDS where possible). If swallowed, contact a doctor or Poisons Information Centre immediately and show this MSDS or label. Use only in well ventilated areas. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest. Keep locked up and out of reach of children. Wear suitable protective clothing, gloves and eye/face protection.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Prevention

P201: Obtain special instructions before use. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P281: Use personal protective equipment as required.

Response

P311: Call a POISON CENTER or doctor. P330: Rinse mouth. P331: Do NOT induce vomiting. P363: Wash contaminated clothing before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P333+P313 If skin irritation or rash occurs Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Amber coloured liquid. Odour: Hydrocarbon odour.

Health hazards

toxic if inhaled, harmful if swallowed, possible skin sensitiser, possible risk of harm to the unborn child, if aspirated, may cause lung damage, repeated exposure may cause skin dryness or cracking, vapours may cause drowsiness and dizziness.

Potential health effects

Persons sensitised to Bromoxynil should avoid contact with this product. Inhalation: Short Term Exposure: High vapour pressures may cause drowsiness and dizziness. In addition product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: Vapours may cause drowsiness and dizziness. Skin Contact: Short Term Exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can be severe. However product is unlikely to cause any discomfort in normal use. Long Term Exposure: Repeated exposure may cause skin dryness or cracking. Eye Contact: Short Term Exposure: This product is believed to be not irritating to eyes. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. This product is unlikely to cause any irritation problems in the short or long term. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.