Borane dimethyl sulfide complex, 2M solution in Toluene

Hazard statements (CLP)

H225, H260, H302+H312, H304, H315, H318, H336, H360, H361, H373, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Physical hazards

Flammable liquids Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 1 3 2 N/A W

Health hazards

Aspiration Toxicity Category 1 Acute Oral Toxicity Category 4 Acute Dermal Toxicity Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 1 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 2

Environmental hazards

Chronic aquatic toxicity Category 3

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H361 - Suspected of damaging fertility or the unborn child H336 - May cause drowsiness or dizziness H373 - May cause damage to organs through prolonged or repeated exposure H318 - Causes serious eye damage H360 - May damage fertility or the unborn child H412 - Harmful to aquatic life with long lasting effects H302 + H312 - Harmful if swallowed or in contact with skin

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P280 - Wear protective gloves/protective clothing/eye protection/face protection P223 - Do not allow contact with water P231 + P232 - Handle and store contents under inert gas. Protect from moisture P264 - Wash hands and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P273 - Avoid release to the environment

Response

P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P302 + P335 + P334 - IF ON SKIN: Brush off loose particles from skin. Immerse in cool water or wrap in wet bandages P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P330 - Rinse mouth P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P331 - Do NOT induce vomiting P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P312 - Call a POISON CENTER or doctor if you feel unwell P321 - Specific treatment (see supplemental first aid instructions on this label) P362 + P364 - Take off contaminated clothing and wash it before reuse P332 + P313 - If skin irritation occurs: Get medical advice/attention P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P308 + P313 - IF exposed or concerned: Get medical advice/attention P314 - Get medical advice/attention if you feel unwell

Storage

P403 + P235 - Store in a well-ventilated place. Keep cool P402 + P404 - Store in a dry place. Store in a closed container P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.3 Other hazards

Reacts violently with water Stench Toxic to terrestrial vertebrates This product does not contain any known or suspected endocrine disruptors NFPA Health Flammability Instability