+ Nitric acld, 70% wiw

Hazard statements (CLP)

H260, H272, H280, H314, H318

Code

Statements

H260

In contact with water releases flammable gases which may ignite spontaneously

SECTION 2: Hazards identification

OSHA 24, Classification of the substance or mixture GHS-US classification Ox.liqd H272 Met. Cor. 1 H280 Skin Corr. 1A H314 EyeDam.1 H318 22

2.2 Label elements

GHS-US labelling

Hazard pictograms

6 aHs0s GHsos

Signal word

Danger

Hazard statements

H272 - May intensify fire; oxidiser H260 - May be corrosive (o metals H314 - Causes severs skin burns and eye damage see section 16 32 Mixture Not applicable First aid measures 44 Description of first aid measures First-aid measures ganeral - Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiatory arest artiicial respiration or oxygen. Cardiac arrest perform resuscitation, Vietim conscious with laboured breathing half-seated. Victim in shock on his back with legs slightly raised. Vomiting prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avaid physical strain. Depending on the victim's condition: doctorhospital. First-aid measures after inhalation + Remove the victim into fresh air. Respiratory problems: consult a doctarimedical service. First-aid measures after skin contact Wash immediately with fots of water (15 minutes)shower. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds wilh sterile bandage. Corsuft a dostorimedical servic. If burned surface > 10%: take victim to hospitai. First-aid measures after eye contact Rinse immediately with plenty of water for 16 minutes. Do not apaly neutralizing agents. Cover eyes asepticaily. Take victim to an ophthaimologist. First-aid measures after ingestion Rinse moulh with water. Immediately after ingestion: give lots of water to drink. Give milk to drink. Do not induce vomiting. Do not give activated charcoal. Do not give chemicai antidote. Immediately consult a doctorimedical service. Call Poison Information Centre (www.big be/antigit.htm). Take the containerivomit to the doctor/ospltal. Ingestion of lasge quantities: immediately (o hospital. 42 Most important symptoms and effects, both acute and delayed ‘Symptoms/injuries after inhalation Initation of the respiratory tract. Dry/scre throat. Corrosion of the upper respiratory tract. Coughing. FOLLOWING SYMPTOMS MAY APPEAR LATER: Respiratory difficulties. Possible inflammation of the respiratory tract. Risk of lung oedema. Blue/grey discolouration of the skin. Symptoms/injuries after skin contact Yellow skin. May stain the skin. Caustic bumsfcorrosion of the skin. Slow-healing wounds. Symptoms/injuries after eye contact Corrosion of the eye tissue. Permanent eye damage. Symptomsfinjuries aftet Ingestion Nausea. Vomiting. Abdorminal pain. Bums to the gastric/intestinal mucosa. Posslble esophageat perforation. Shock. Chronic symptoms ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Affection/discalouration of the teeth. Risk of preumonia. 4.3, Indication of any immediate medical attention and spacial treatment needed Obtain medical assistance. 5.1. Suitable extinguishing media - EXTINGUISHING MEDIA FOR SURROUNDING FIRES: All extinguishing media allowad. Unsuitable extinguishing media No unsuitable extinguishing media known. 52 Special hazards arising from the substance or mixture Fire hazard DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Promotes combustion. Reactions involving a fire hazard: see "Reactivity Hazard". Expiosion hazard INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard". 07ERT3 EN (English) B 205

Precautionary statements

P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P220 - Keep/Store away from clothing, combustible materials P221 - Take any precaution to avoid mixing with combustibles P234 - Keep only in original container P260 - Do not breathe mist, spray, vapours P264 - Wash exposed skin thoroughly after handling P280 - Wear eye protection, face protection, protective clothing, protective gloves P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALE: Remove person to fresh ir and keep comortable for breathing P305+P351+P338 - Ifin eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediatsly call a POISON CENTER/doctor P363 - Wash contaminated clothing before reuse P370+P378 - In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction P390 - Absorb spillage to prevent material damage P405 - Store locked up P406 - Store In corrosive resistant container with a resistant inner liner 0710342013 EN (English} o Page 1

Other hazards which do not result in classification

Nore. 24.

Ingredient(s) with unknown acute toxicity

No data available 31, Substances Substance type + Multi-constituent Nameo

Product definition

[ %

Classification (GHS-US)

Nitric acid, 70% wiw (CAS No) 7697-37-2 1 100 { Ox.Lig. 3, H272 {Main constituert) 1 Met. Corr. 1, H290 | { Skin Con. 1A, H314 | Eye Dam. 1, H318 | L

Further information

Saturation concentration 10g/m® VOC content Not applicable Other properties Gas/vapour heavier than air at 20°C. Hygroscopic. Producing fumes/mist, Physical praperies depending on the concentration. Substance has acid reaction. SECTION 10: Stability and reactivit 101, Reactivity Cancentrated solution reacts exothermically with water (moisture). Decomposes on exposure to temperature rise: release of toxic and corrosive gasesivapours (nitrous vapours). Violent to explosive reaction with many compounds e.g.: with (sirong) reducers, with (some) bases, with organic material and with combustible materials with risk of spontaneous ignition. Reacts violently with (some) mells, Decomposes skowly on exposure 1o fight release of loxic and corrosive gases/ivapours (nitrous vapours). Violent to explosive reaction with (some) metal powders release of highly flammable gases/vapours (hydrogen). 102 Chemical stabllity Unstable on exposure to light. Hygroscopic. 103. Possibility of hazardous reactions May react violently with reducing agents. 104. Conditions to avoid Direct sunlight. Incompatible materiats. 105, Incompatible materials Strong bases. Strang reducing agents. Organic compaunds. cyanides. combustible materials. Aldehydes. Ammonia. metals. alcohols. 106 Hazardous decomposition products Nitrogen oxides. oxygen. SECTION 11: Toxicological information [RAE Informatior: un texicological effects Acute toxicity Not classified Skin corrosion/iritation Causes severe skin bums and eye damage. pH: 1 (6 %) Serlous eye damageliritation Causes serious eye damage. PH: 1(6 %) Respiratory or skin sensitisation Not classified Gem cell mutagenicity Not classifled Carcinogenicity Not classified (Based on available data, the classification critsria are not met) Reproductive toxicity Mot classified Specific target organ toxicity (single exposure) Nat classified Specific target organ toxicity (repeated Not classified exposure) Aspiration hazard Nol classified Symptomsfinjuries after inhalation Initation of the respiratory (ract. Dry/sore throat. Corrosion of the upper respiralory tract. Coughing. FOLLOWING SYMPTOMS MAY APPEAR LATER: Respiratory difficulties. Possible inflammation of the respiratory tract. Risk of lung oedema. Blue/grey discolouration of the skin. Symptoms/injuries after skin contact Yeliow skin. May stain the skin. Caustic bums/corrosion of the skin. Slow-healing wounds. Symptoms/injuries after eye contact Corrosion of the eye tissue. Permanent eye damage. Symptoms/injuries after ingestion Nausea. Vomiting. Abdominal pain. Bums to the gastric/intestinal mucosa. Possible esophageal perforation. Shock. Chranic symptorns ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Affection/discolouration of the testh. RIsk of preumonia. Ecological 124, Toxicity Ecology - general Classification conceming the environment: not applicable. Ecology - water Mild water pollutant (surface water). Harmful to fishes. Slightly hammful to inverlebrates (Daphnia). May cause eutrophication. pH shift 07/0272013 EN (English) 59 Nitric acid, 70% wihw (7687-37-2) T RQ {Reportable quantily, section 304 of EPA's | 1000 la List of Lists) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations. CANADA Nitric acld, 70% wiw ( 7697-37-2) Listed on the Canadian DSL {Domestic Sustances List) inventory. WHMIS Classification Class E - Carrosive Material Class C - Oxidizing Materia E£U-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Ox.Lig.3 H272 Skin Corr. 1A H314 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC O;R8 CiR35 Full text of R-phrases: see seclion 16 1522, National regulations Nitric acid, 70% wiw ( 7697-37-2) Listed on the Canadian Ingredient Disclosure List 15.3. US State regulations Nitric acld, 70% wiw( 7697-37-2) State or local regufations U'S - Pennsylvania - RTK (Right o Know) List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Massachusetts - Right To Know List SECTION 16:Other informati Full text of H-phrases: see section 16: [ Eye Dam_1 Serious eye damageleye irritation, Category 1 | { Met_Corr 1 Corrosive to metals, Category 1 Ox. Liq. 3. Oxidising Liquids, Category 3 “ - Skin Corr. 1A Skin corrosionritation, Category 1A H H272 May intensify fire; oxidiser 1 H290 May be corrosive (o metals 1 Hatd I Causes severe skin bums and eye damage | [ Hat8 B (" Causes serlous eye damage —1 NFPA health ha + 4-Very short exposure could cause death or serious residual injury even though prompt medical attention was given. NFPA fire hazard 0 - Materials that will not bumn. NFPA reactivity 0 - Normatly stable, even under fire exposure conditions, and are not reactive with water. NFPA specific hazard OX - This denotes an oxidizer, a chemical which can greatly increase the raté of combustion/fire. EN(Engish) (g ‘according to Federal Register / Val. 77, No. 58 / Monday, March 26, 2012/ Rules and Regulations HMIS Il Rating Health 4 Severe Hazard - Life-threatening, major or permanent damage may result from single or repeated overexposures Flammability 0 Minimal Hazard Physical 0 Minimal Hazard Personal Protection H SDS US (GHS HazCom 2012) indormation i iris SDS s ffom available published sources a1 is belisved to b accurals. No warranly, expross of implo, is mace ard LabCher In: assumes no iiabilly resuiling o the use of s SDS. The user must deformine suitabilly of this informaton for s applicalion. 071032013 N (English)

2.1 Classification of the substance or mixture

GHS-US classification Ox.liqd H272 Met. Cor. 1 H280 Skin Corr. 1A H314 EyeDam.1 H318 22