Hydrochloric acid solutions 1%-50% v/v, 0.01N-6.25N

LabChem, Inc

Revision date : 1996-09-27

SDS Library

Move your SDS library online today

Check Icon
Setup – Easy setup with our database of 16 million+ SDSs
Check Icon
Up-to-date – Your SDS get updated to latest versions.
Check Icon
Employee access – Tablets, Smartphones, or link from Corporate Intranet
Check Icon
Safety – One-click access to first aid information.
Check Icon
Labels – Generate Secondary Container Labels with just one click.
Health risk rating
Safety risk rating
Environmental risk rating

Note: Ingredients listed on restricted chemical lists

EC/CAS

7732-18-5

Name of the chemical

Water, distilled, conductivity or of similar purity H2O

Concentration

balance

EC/CAS

7647-01-0

Name of the chemical

Hydrochloric acid

Concentration

1-50%

General Information

Revision date

1996-09-27

Product name

Hydrochloric acid solutions 1%-50% v/v, 0.01N-6.25N

Emergency telephone

(800) 424-9300

Icons in SDS

M013

Company Information

company name

LabChem, Inc

GHS Information

Signal word

Danger!

Section 2

SECTION 2: Hazards identification

V. REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur Incompatibility (Materials to Avoid): None Hazardous Decomposition or Byproducts: May release CO2 on burning ALCONOX MSDS - ALCONOX MSDS - ALCONOX MSDS - ALCONOX MSDS - ALCONOX MSDS VI. HEALTH HAZARD DATA Inhalation? Yes

Principle Routes of Exposure

Skin? No Ingestion? Yes Inhalation of powder may prove locally irritating to mucous

Health hazards

Acute membranes. Ingestion may cause discomfort and/or diarrhea. Eye and Chronic) contact may prove irritating. NTP? No Carcinogenicity: IARC Monographs? No OSHA Regulated? No Signs and Symptoms of Exposure may irritate mucous membranes. May cause sneezing. Exposure:

Medical Conditions Generally Aggravated by Exposure

Not established. Unnecessary exposure to this product or any industrial chemical should be avoided. Respiratory conditions may be aggravated by powder. Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician. Emergency and First Skin: Flush with plenty of water. Aid Procedures: Ingestion: Drink large quantities of water or milk. Do not induce vomiting. If vomiting occurs administer fluids. See a physician for discomfort. VII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken if Material foams profusely. Recover as much as possible and flush Material is Released or remainder to sewer. Material is biodegradable. Spilled: Small quantities may be disposed of in sewer. Large quantities Waste Disposal Method: should be disposed of in accordance with local ordinances for detergent products. Precautions to be Taken Material should be stored in a dry area to prevent caking. in Storing and Handling: Other Precautions: No special requirements other than the good industrial hygiene and safety practices employed with any industrial chemical. VIII. CONTROL MEASURES Respiratory Protection (Specify Type): Dust mask - Recommended Local Exhaust-Normal Ventilation: Special-Not Required Mechanical-Not Required Other-Not Required Protective Gloves: Impervious gloves are useful but not required. Eye Protection: Goggles are recommended when handling solutions. Other Protective Clothing or Equipment: None Work/Hygienic Practices: No special practices required THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH BUT NO WARRANTY IS EXPRESSED OR IMPLIED. ============ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ============= TRADE NAME: #2 DIESEL FUEL CAS NUMBER: 68476-34-6 SYNONYM(S): PROCESS STREAM; NO. 2 DIESEL FUEL; FUEL OIL; MIDDLE DISTILLATE; AB0/AA9-1; AG7; AG8 MSDS NUMBER: 1354 PRODUCT CODE: NA HIERARCHY: NA MANUFACTURER/SUPPLIER: BP Oil Company ADDRESS: 200 Public Square, Cleveland, OH 44114-2375 TELEPHONE NUMBERS - 24 HOUR EMERGENCY ASSISTANCE: BP America: 800-321-8642 CHEMTREC Assistance (In U.S.): 800-424-9300 CHEMTREC Assistance (Elsewhere): 703-527-3887 TELEPHONE NUMBERS - GENERAL ASSISTANCE: (Normal Office Hours): 8 00-4 30 M-F, EST) Technical: 216-586-6184 MSDS Contact: 216-586-8023 ============== COMPOSITION/INFORMATION ON INGREDIENTS ================ COMPONENT:Diesel Fuel No. 2, A distillate having a minimum viscosity of 32.6 SUS at 100 degrees F to a maximum of 40.1 SUS at 100 degrees F CAS NO.: 68476-34-6 % BY WT.: 99.9 - 100 EXPOSURE LIMITS: None Established ======================== EMERGENCY OVERVIEW: ------------------- Clear Liquid With Hydrocarbon Odor. May Be Dyed For Identification. Danger! Harmful or Fatal If Swallowed. Aspiration Hazard If Swallowed--Can Enter Lungs and Cause Damage. May Be Irritating To the Eyes and Respiratory Tract. Causes Skin Irritation. Vapors May Be Harmful. Possible Cancer Hazard - Contains Material Which May Cause Cancer Based On Animal Data. Combustible Liquid & Vapor.

Potential health effects

SKIN: ----- Repeated or prolonged contact may result in defatting, redness, itching, inflammation, cracking and possible secondary infection. May cause allergic reactions in some individuals. Absorption from prolonged or massive skin contact may cause poisoning. High pressure skin injections are Serious Medical Emergencies. Injury may not appear serious at first; within a few hours, tissue will become swollen, discolored and extremely painful (see Notes to Physician section). EYE: ---- Exposure to vapors, fumes or mists may cause irritation. INHALATION: ----------- May cause respiratory tract irritation. Exposure may cause central nervous system symptoms similar to those listed under "Ingestion" (see Ingestion section). Degenerative changes in the liver, kidneys and bone marrow may occur with prolonged, high concentrations. Repeated or prolonged exposures may cause behavioral changes. INGESTION: ---------- Aspiration into lungs may cause pneumonitis. May cause gastrointestinal disturbances. Symptoms may include irritation, nausea, vomiting and diarrhea. May cause harmful central nervous system effects. Effects may include excitation, euphoria, headache, dizziness, drowsiness, blurred vision, fatigue, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death. SPECIAL TOXIC EFFECTS: ---------------------- Based on animal studies, repeated overexposure may produce skin tumors upon repeated and prolonged skin contact in the absence of good personal hygiene. However, long-term dermal application studies of similar materials, i.e. middle distillates, in animals have shown that skin tumors are produced only when marked and prolonged skin irritation takes place during the study. Therefore, this product should not present a significant hazard of skin tumor formation when the "Skin Protection" recommendations are followed. IARC has determined that diesel engine exhaust is probably carcinogenic to humans. (IARC Class- 2A). Lifetime exposure to whole diesel exhaust has been shown to cause cancer in laboratory animals. NIOSH recommends that whole diesel exhaust be regarded as a potential occupational carcinogen. Warning: The use of any hydrocarbon fuel in an area without adequate ventilation may result in hazardous levels of combustion products and inadequate oxygen levels. IARC has determined that occupational exposures in petroleum refining are probably carcinogenic to humans. ======================== FIRST AID MEASURES ========================== SKIN: ----- Remove contaminated clothing immediately. Wash area of contact thoroughly with soap and water. Get medical attention if irritation persists. High pressure skin injections are serious medical emergencies. Thermal burns require immediate medical attention. Get immediate medical attention. EYE: ---- Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Get medical attention if irritation persists. Thermal burns require immediate medical attention. INHALATION: ----------- Remove affected person from source of exposure. If not breathing, ensure clear airway and institute cardiopulmonary resuscitation (CPR). If breathing is difficult, administer oxygen if available. After administration of oxygen, continue to monitor closely. Get medical attention. INGESTION: ---------- Do not induce vomiting because of danger of aspirating liquid into lungs. Get immediate medical attention. If spontaneous vomiting occurs, monitor for breathing difficulty. NOTES TO PHYSICIAN: ------------------- In case of ingestion, gastric lavage with activated charcoal can be used promptly to prevent absorption. Consideration should be given to the use of an endotracheal tube, to prevent aspiration. Individuals intoxicated by Diesel Fuel No. 2 should be hospitalized immediately, with acute and continuing attention to neurologic and cardiopulmonary function. Positive pressure ventilation may be necessary. After the initial episode, individuals should be followed for changes in blood variables and the delayed appearance of pulmonary edema and chemical pneumonitis. Such patients should be followed for several days or weeks for delayed effects, including bone marrow toxicity, hepatic and renal impairment. Individuals with chronic pulmonary disease will be more seriously impaired, and recovery from inhalation exposure may be complicated. In case of skin injection, prompt debridement of the wound is necessary to minimize necrosis and tissue loss. ======================= FIREFIGHTING MEASURES ======================== FLASH POINT: 51.7 C (125.06 F) AUTOIGNITION TEMPERATURE: ND FLAMMABILITY LIMITS IN AIR (% BY VOL.) LOWER: > 0.7 FLAMMABILITY LIMITS IN AIR (% BY VOL.) UPPER: < 5 HAZARDOUS COMBUSTION PRODUCTS: ------------------------------ Combustion may produce CO, CO2 and reactive hydrocarbons. BASIC FIRE FIGHTING PROCEDURES: ------------------------------- Use water spray, dry chemical, foam or carbon dioxide to extinguish fire. Use water spray to cool fire-exposed containers, structures and to protect personnel. If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to protect personnel attempting to stop leak. Use water to flush spills away from sources of ignition. Do not flush down public sewers or other drainage systems. Exposed firefighters must wear MSHA/NIOSH approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing. UNUSUAL FIRE & EXPLOSION HAZARDS: --------------------------------- Irritating and/or toxic substances may be emitted upon thermal decomposition. Dangerous when exposed to heat or flame. Runoff to sewer may cause fire or explosion hazard. Containers may explode in heat of fire. ==================== ACCIDENTAL RELEASE MEASURES ===================== If your facility or operation has an "Oil or Hazardous Substance Contingency Plan", activate its procedures. Take immediate steps to stop and contain the spill. Caution should be exercised regarding personnel safety and exposure to the spilled material. For technical advice and assistance related to chemicals, contact CHEMTREC (800/424-9300) and your local fire department. Notify the National EYE CONTACT: High concentrations of vapor/mist may cause eye discomfort. SKIN CONTACT: Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis. INHALATION: Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and nausea, and may lead to unconsciousness or death. See "Toxicological Information" section (Section 11.0). INGESTION: Harmful or fatal if liquid is aspirated into lungs. Ingestion causes gastrointestinal irritation and diarrhea. See "Toxicological Information" section (Section 11.0).

Response

Center, if required. Also notify appropriate state and local regulatory agencies, the LEPC and the SERC. Contact the local Coast Guard if the release is into a waterway. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. (Also see Personal Protection Information section.) Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small Spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large Spills: Dike far ahead of liquid spill for later disposal. When reporting a spill to the National Response Center or the Coast Guard, you may need to supply the Coast Guard Chemical Hazard Information System (CHRIS) code Group Number: 33 CHRIS Code: OTD Additional spill related information may be found in the U.S. Coast Guard Chemical Hazard Response Information System (CHRIS) Manual. During an accidental release, personal protection equipment may be required (see Section EXPOSURE CONTROLS/PERSONAL PROTECTION). Additional regulatory requirements may apply (see Section REGULATORY INFORMATION). ======================= HANDLING AND STORAGE ========================= HANDLING: --------- Use non-sparking tools. Ground lines and equipment used during transfer to reduce the possibility of static spark-initiated fire or explosion. Empty containers may contain toxic, flammable/combustible or explosive residue or vapors. Do not cut, grind, drill, weld, reuse or dispose containers unless adequate precautions are taken against these hazards.

Storage

Store in tightly closed containers in cool, dry, isolated, well-ventilated area away from heat, sources of ignition and incompatibles. ============== EXPOSURE CONTROLS / PERSONAL PROTECTION =============== ENGINEERING CONTROLS: --------------------- Ventilation may be used to control or reduce airborne concentrations. PERSONAL PROTECTION EQUIPMENT (PPE): ------------------------------------ EYE PROTECTION: --------------- Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact lenses when working with this substance. Have eye washing facilities readily available where eye contact can occur. SKIN PROTECTION: ---------------- Wear impervious gloves and protective clothing to prevent skin contact. RESPIRATORY PROTECTION: ----------------------- NIOSH/MSHA approved breathing equipment may be required for non-routine and emergency use. See Section COMPOSITION/INFORMATION ON INGREDIENTS For Exposure Guidelines. ================= PHYSICAL AND CHEMICAL PROPERTIES =================== BOILING POINT: 160 C (320 F) SP. GRAVITY (Water=1): 0.84 - 0.88 @ 15.56 C (60.008 F) MELTING POINT: NA % VOLATILE: Negligible VAPOR PRESSURE: 0.4 MM HG @ 20 C (68 F) EVAPORATION RATE: Slower VAPOR DENSITY (Air=1): 4.7 VISCOSITY: 1.2 - 4.6 CST @ 37.8 C (100.04 F) % SOLUBILITY IN WATER: Negligible POUR POINT: -12.22 C (10.004 F) pH: NEUTRAL MOLECULAR WEIGHT: NA MOLECULAR FORMULA: Mixture Store in flammable liquids storage area. Keep container closed. Store away from heat, ignition sources, and open flame in accordance with applicable regulations. SPECIAL PRECAUTIONS: Keep out of sewers and waterways. Avoid strong oxidizers. Report spills to appropriate authorities. USE AS MOTOR FUEL ONLY. 8.0 EXPOSURE CONTROLS / PERSONAL PROTECTION EYE: None required; however, use of eye protection is good industrial practice. SKIN: Avoid prolonged or repeated skin contact. Wear protective clothing and gloves if prolonged or repeated contact is likely. INHALATION: Use with adequate ventilation. Avoid breathing vapor and/or mist. If ventilation is inadequate, use NIOSH certified respirator that will protect against organic vapor and dust/mist. ENGINEERING CONTROLS: Control airborne concentrations below the exposure guidelines. EXPOSURE GUIDELINES: Component CAS# Exposure Limits Gasoline 8006-61-9 OSHA PEL: 300 ppm (1989); Not established. (1971) OSHA STEL: 500 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 300 ppm ACGIH TLV-STEL: 500 ppm Benzene 71-43-2 OSHA PEL: 1 ppm OSHA STEL: 5 ppm ACGIH TLV-TWA: 0.5 ppm (skin) ACGIH TLV-STEL: 2.5 ppm (skin) Mexico TWA: 10 ppm Mexico STEL: 25 ppm Butane 106-97-8 OSHA PEL: 800 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 800 ppm Mexico TWA: 800 ppm Cyclohexane 110-82-7 OSHA PEL: 300 ppm (1989)(1971) ACGIH TLV-TWA: 300 ppm Mexico TWA: 300 ppm Mexico STEL: 375 ppm Ethylbenzene 100-41-4 OSHA PEL: 100 ppm (1989)(1971) OSHA STEL: 125 ppm(1989); Not established. (1971) ACGIH TLV-TWA: 100 ppm ACGIH TLV-STEL: 125 ppm Mexico TWA: 100 ppm Mexico STEL: 125 ppm Heptane 142-82-5 OSHA PEL: 400 ppm (1989); 500 ppm (1971) OSHA STEL: 500 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 400 ppm ACGIH TLV-STEL: 500 ppm Mexico TWA: 400 ppm (skin) Mexico STEL: 500 ppm (skin) Hexane 110-54-3 OSHA PEL: 50 ppm (1989); 500 ppm (1971) ACGIH TLV-TWA: 50 ppm (skin) Mexico TWA: 100 ppm Pentane 109-66-0 OSHA PEL: 600 ppm (1989); 1000 ppm (1971) OSHA STEL: 750 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 600 ppm Mexico TWA: 600 ppm Mexico STEL: 760 ppm Toluene 108-88-3 OSHA PEL: 100 ppm (1989); 200 ppm (1971) OSHA STEL: 150 ppm (1989); Not established. (1971) OSHA Ceiling: 300 ppm (1971) ACGIH TLV-TWA: 50 ppm (skin) Mexico TWA: 100 ppm Mexico STEL: 150 ppm Trimethylbenzene 95-63-6 OSHA PEL: 25 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 25 ppm Mexico TWA: 25 ppm Mexico STEL: 35 ppm Xylene 1330-20-7 OSHA PEL: 100 ppm (1989)(1971) OSHA STEL: 150 ppm (1989); Not established. (1971) ACGIH TLV-TWA: 100 ppm ACGIH TLV-STEL: 150 ppm Mexico TWA: 100 ppm (skin) Mexico STEL: 150 ppm (skin) 9.0 CHEMICAL AND PHYSICAL PROPERTIES

Appearance/Odor

Clear Liquid With Hydrocarbon Odor. May Be Dyed For Identification. ===================== STABILITY AND REACTIVITY ======================= STABILITY/INCOMPATIBILITY: -------------------------- Stable. Avoid contact with strong oxidizers. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS: ------------------------------------------- Thermal decomposition or combustion may produce CO, CO2 and reactive hydrocarbons. Clear. Liquid. Hydrocarbon odor pH: Not determined. VAPOR PRESSURE: 7-15 lb RVP (ASTM D323) VAPOR DENSITY: 3.0-4.0 BOILING POINT: 80.0-430.0°F (range) MELTING POINT: Not determined. SOLUBILITY IN WATER: Negligible, below 0.1%. SPECIFIC GRAVITY (WATER=1): 0.75 10.0 STABILITY AND REACTIVITY STABILITY: Burning can be started easily. CONDITIONS TO AVOID: Keep away from ignition sources (e.g. heat, sparks, and open flames). MATERIALS TO AVOID: Avoid chlorine, fluorine, and other strong oxidizers. HAZARDOUS DECOMPOSITION: None identified. HAZARDOUS POLYMERIZATION: Will not occur. 11.0 TOXICOLOGICAL INFORMATION ACUTE TOXICITY DATA: EYE IRRITATION: This product had a primary eye irritation score (PEIS) of 0/110.0 (rabbit) SKIN IRRITATION: This product had a primary skin irritation score (PDIS) of 1.1/8.0 (rabbit) DERMAL LD50: greater than 5 ml/kg (rabbit). ORAL LD50: 18.8 ml/kg (rat). INHALATION LC50: 20.7 mg/l (rat) OTHER TOXICITY DATA: Excess exposure to vapors may produce headaches, dizziness, nausea, drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea. In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause these kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects. Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard. The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g., phenobarbital). Thus, the significance of the mouse liver tumor response in terms of human health is questionable. Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats. Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death. 12.0 ECOLOGICAL INFORMATION Ecological testing has not been conducted on this material by BP Amoco. 13.0 DISPOSAL INFORMATION Residues and spilled material are hazardous waste due to ignitability. Disposal must be in accordance with applicable federal, state, or local regulations. Enclosed-controlled incineration is recommended unless directed otherwise by applicable ordinances. The container for this product can present explosion or fire hazards, even when emptied! To avoid risk of injury, do not cut, puncture, or weld on or near this container. Since the emptied containers retain product residue, follow label warnings even after container is emptied. 14.0 TRANSPORTATION INFORMATION U.S. DEPT OF TRANSPORTATION Shipping Name Gasoline

TOXICOLOGICAL INFORMATION

OTHER: ------ An extensive profile which characterizes adverse health effects information for this material has been prepared by the Agency for Toxic Substances Disease Registry (ATSDR). Individuals interested in a summary of the toxicology of this material should reference this document. This profile can be obtained from the National Technical Information Services (NTIS). ====================== DISPOSAL CONSIDERATIONS ======================= WASTE DISPOSAL (Resource Conservation & Recovery Act - RCRA): ------------------------------------------------------------- This material, when discarded or disposed of, is a characteristic hazardous waste according to Federal regulations (40 CFR 261). This material exhibits the characteristic of ignitability and is assigned the EPA Hazardous Waste Number of D001. The discarding or disposal of this material must be done at a properly permitted facility in accordance with the regulations of 40 CFR 262, 263, 264, and 268. Additionally, the discarding or disposal of this material may be further regulated by state, regional, or local regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate, or otherwise inappropriate. The transportation, storage, treatment and disposal of this waste material must be conducted in compliance with all applicable Federal, state, and local regulations. There may be specific current regulations at the local, regional, or state level that pertain to this information. Chemical additions, processing, or otherwise altering this material may make the waste management information presented in this MSDS, incomplete, inaccurate, or otherwise inappropriate. ======================= TRANSPORT INFORMATION ======================== U.S. DEPARTMENT OF TRANSPORTATION (D.O.T.): ------------------------------------------- Proper Shipping Name (49 CFR 172.101): Fuel Oil (No. 2) DISPOSAL CONSIDERATIONS TRANSPORT INFORMATION REGULATORY INFORMATION

Hazard categories

49 CFR 172.101) 3 UN/NA Code (49 CFR 172.101): NA 1993 Packing Group (49 CFR 179.101): PG III Bill Of Lading Desc. (49 CFR 172.101): Fuel Oil (No. 2), 3, NA 1993, PG III Labels Required (49 CFR 172.101): Not Regulated Placards Required (49 CFR 172.101): Combustible INTERNATIONAL AND DOMESTIC AIR TRANSPORTATION: ---------------------------------------------- IATA Proper Shipping Name: Diesel Fuel 3 Subsidiary Risk: NA UN Code: UN 1202 Package Specification: 309, 310 Labels Required: Flammable Liquid, Orientation Arrows INTERNATIONAL WATER TRANSPORTATION: ----------------------------------- IMDG Proper Shipping Name: Diesel Fuel 3.3 UN Code: UN 1202 IMDG Page Number: 3375 Labels Required: Flammable Liquid Placards Required: Flammable CANADIAN TRANSPORTATION OF DANGEROUS GOODS (T.D.G.): ---------------------------------------------------- Shipping Name: Fuel Oil, No. 2 PIN (UN/NA): UN 1202 Regulated Class: 3 Division: NA Packaging Group: PG III Labels Required: Flammable Liquid Placards Required: Flammable ====================== REGULATORY INFORMATION ======================== NOTIFICATION: ------------- Any spill or release, or substantial threat of release, of this material to navigable water (virtually any surface water) sufficient to cause a visible sheen upon the water must be reported immediately to the National Response Center (800/424-8802), as required by U.S. Federal Law. Failure to report may result in substantial civil and criminal penalties. Also contact the Coast Guard and appropriate state and local regulatory agencies. US EPA TOXIC SUBSTANCE CONTROL ACT (TSCA): ------------------------------------------ All components of this product are listed on the TSCA inventory. US EPA SUPERFUND AMENDMENTS & REAUTHORIZATION ACT (SARA) TITLE III INFORMATION: Listed below are the hazard catagories for SARA Section 311/312 (40 CFR 370): Immediate Hazard: X Delayed Hazard: X Fire Hazard: X Pressure Hazard: - Reactivity Hazard: - CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): --------------------------------------------- All components of this product are listed on the Canadian DSL or NDSL inventories. CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) CATEGORIES: The following WHMIS categories apply to this product: Compressed Gas: - Other Toxic Effects: X Flammable/Combustible: X Bio Hazardous: - Oxidizer: - Corrosive: - Acutely Toxic: X Dangerously Reactive: - 3 Identification Number UN1203 Packing Group II INTERNATIONAL INFORMATION: Sea (IMO/IMDG) Shipping Name Gasoline Class 3.1 Packing Group II 3

HMIS® ratings

Health: 0 Health: 0 Flammability: 2 Flammability: 2 Reactivity: 0 Reactivity: 0 Special Hazards: - Personal Protective Equipment:H Effective Date 27-sep-1996 REPLACES SHEET DATED: 17-feb-1995 COMPLETED BY: BP OIL HSEQ DEPARTMENT REVISION SUMMARY: The following section(s) have been revised since the previous issue of this MSDS: FIRST AID MEASURES EXPOSURE CONTROLS / PERSONAL PROTECTION STABILITY AND REACTIVITY

Further information

NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, express or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. ND No Data NA Not Applicable *See specific note or section BP UNLEADED GASOLINES MSDS No. 12632000 ANSI/ENGLISH 1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: BP UNLEADED GASOLINES MANUFACTURER/SUPPLIER: EMERGENCY HEALTH INFORMATION: 1 (800) 447-8735 BP Oil Company 200 East Randolph Drive EMERGENCY SPILL INFORMATION: Chicago, Illinois 60601 U.S.A. 1 (800) 424-9300 CHEMTREC (USA) OTHER PRODUCT SAFETY INFORMATION: (630) 836-5441 2.0 COMPOSITION/INFORMATION ON INGREDIENTS Component CAS# Range % by Wt. Gasoline 8006-61-9 99.9-100 Benzene 71-43-2 0-3 Butane 106-97-8 4-6 Cyclohexane 110-82-7 0-1 Ethylbenzene 100-41-4 0-2 Heptane 142-82-5 6-8 Hexane 110-54-3 8-10 Pentane 109-66-0 9-11 Toluene 108-88-3 10-12 Trimethylbenzene 95-63-6 0-3 Xylene 1330-20-7 8-10 (See Section 8.0, "Exposure Controls/Personal Protection", for exposure guidelines) 3.0 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Danger! Extremely flammable. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and nausea, and may lead to unconsciousness or death. Harmful if swallowed and/or aspirated into the lungs. Prolonged or repeated contact may cause irritation and/or dermatitis. Use as motor fuel only. Long- term exposure to vapors has caused cancer in laboratory animals.

HMIS CODES

Health 1) (Flammability 3) (Reactivity 0) CHRONIC HEALTH HAZARD NFPA CODE (Health 1) (Flammability 3) (Instability 0) 4.0 FIRST AID MEASURES EYE: Flush eyes with plenty of water. Get medical attention if irritation persists. SKIN: Wash exposed skin with soap and water. Remove contaminated clothing, including shoes, and thoroughly clean and dry before reuse. Get medical attention if irritation develops. INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get medical attention. INGESTION: If swallowed, do NOT induce vomiting. Get immediate medical attention. 5.0 FIRE FIGHTING MEASURES FLASHPOINT: -45°F UEL: 7.6% LEL: 1.3% AUTOIGNITION TEMPERATURE: 495.0°F FLAMMABILITY CLASSIFICATION: Extremely Flammable Liquid. EXTINGUISHING MEDIA: Agents approved for Class B hazards (e.g., dry chemical, carbon dioxide, foam, steam) or water fog. Water may be ineffective but should be used to cool-fire exposed containers, structures and to protect personnel. UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable vapor/air mixtures form. Extinguishment of fire before source of vapor is shut off can create an explosive mixture in air. Product gives off vapors that are heavier than air which can travel considerable distances to a source of ignition and flashback. Runoff to sewer may cause a fire or explosion hazard. FIRE-FIGHTING EQUIPMENT: Firefighters should wear full bunker gear, including a positive pressure self-contained breathing apparatus.

Precautionary statements

Keep away from sources of ignition (e.g., heat and open flames). Keep container closed. Use with adequate ventilation. HAZARDOUS COMBUSTION PRODUCTS: Combustion of this product in an area without adequate ventilation may result in hazardous levels of combustion products (e.g., carbon monoxide, carbon dioxide) and inadequate oxygen levels. 6.0 ACCIDENTAL RELEASE MEASURES Remove or shut off all sources of ignition. Wear respirator and spray with water to disperse vapors. Increase ventilation if possible. Prevent spreading by diking, ditching, or absorbing on inert materials. Keep out of sewers and waterways. 7.0 HANDLING AND STORAGE HANDLING: Use with adequate ventilation. Keep away from ignition sources (e.g., heat, sparks, or open flames). Ground and bond containers when transferring materials. Wash thoroughly after handling.

UN Number

UN1203 Air (ICAO/IATA) Shipping Name Gasoline , UN1203 Class 3 Packing Group II European Road/Rail (ADR/RID) Shipping Name Not determined. Canadian Transportation of Dangerous Goods Shipping Name Gasoline UN1203 Packing Group II 15.0 REGULATORY INFORMATION CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product is exempt from the CERCLA reporting requirements under 40 CFR Part 302.4. However, if spilled into waters of the United States, it may be reportable under 33 CFR Part 153 if it produces a sheen. SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355): This product is not regulated under Section 302 of SARA and 40 CFR Part 355. SARA TITLE III SECTIONS 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370): This product is defined as hazardous by OSHA under 29 CFR Part 1910.1200(d). Hazardous categories for this product are: Acute = yes; Chronic = yes; Fire = yes; Pressure = no; Reactive = no. SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372: Component/CAS Number Weight Percent Benzene 71-43-2 3 Trimethylbenzene 95-63-6 3 Cyclohexane 110-82-7 1 Ethylbenzene 100-41-4 2 Xylene 1330-20-7 10 Hexane 110-54-3 10 Toluene 108-88-3 12 U.S. INVENTORY (TSCA): Listed on inventory. OSHA HAZARD COMMUNICATION STANDARD: Flammable liquid. Irritant. Contains components listed by ACGIH. Contains components listed by OSHA. Contains a carcinogenic component. WHMIS Controlled Product Classification: B2, D2A, D2B. EC INVENTORY (EINECS/ELINCS): Not determined. JAPAN INVENTORY (MITI): Not determined. AUSTRALIA INVENTORY (AICS): Not determined. KOREA INVENTORY (ECL): Not determined. CANADA INVENTORY (DSL): Not determined. PHILIPPINE INVENTORY (PICCS): Not determined. 16.0 OTHER INFORMATION This material contains an ingredient/ingredients present on the following State Right-To-Know lists: -Florida- -Massachusetts- -New Jersey- -Pennsylvania- -California- -Minnesota- This product contains an ingredient/ingredients known to the state of California to cause cancer and/or reproductive toxicity. Prepared by: Environment, Health and Safety Department Issued: July 16, 1999 This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, express or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. APPENDIX 6 Justification of Action Levels JUSTIFICATION OF ACTION LEVELS Establishment of total volatile hydrocarbons and carbon monoxide monitor action level for level C upgrade and changes in work procedures. Instrument Data Type Model Lamp (ev) Calibration Concentration (PID/FID) PID only Gas (ppm/v) PID RAE 10.6 Isobutylene 100 Notes: AMEC standard 13 ppm Action Limit for petroleum-related site will be utilized for this project. See calculations below, which are based on correction factors from RAE Systems Technical Note TN-106. If additional laboratory analytical results are available, the results should be reviewed by a Certified Industrial Hygienist and new site- specific action levels should be evaluated if necessary. Contaminants Estimated TLV® Correction Factor (CF) Fraction (ppm) for 10.6 ev Lamp Benzene 0.03 0.5 0.53 Ethylbenzene 0.17 100 0.52 Toluene 0.20 50 0.50 o-Xylene 0.30 100 0.59 p-Xylene 0.30 100 0.45 TLV® CF Constituent Fraction/TLV®(benzene) 0.060 Fraction/CF(benzene) 0.06 Fraction/TLV®(ethylbenzene) 0.017 Fraction/CF(ethylbenzene) 0.33 Fraction/TLV®(toluene) 0.004 Fraction/CF(toluene) 0.40 Fraction/TLV®(o-xylene) 0.003 Fraction/CF(o-xylene) 0.51 Fraction/TLV®(p-xylene) 0.003 Fraction/CF(p-xylene) 0.67 TLV® mix total 14 CF mix total 0.51 Action Level = TLV®mix/CFmix = 27.3 ppm CF- Correction Factor ev = electron volts PID = photoionization detector ppm/v = parts per million by volume 50% protection factor: 27.3 ppm/2 = 13.7ppm CF mix = 1/(X1/CF1 ******************* Xn/CFn) TLV® mix = 1/(X1/TLV®1*******************Xn/TLV®n) .________________________________________________ PID = photoionization detector; ppm/v = parts per million by volume TLV= American Conference of Governmental Industrial Hygienist (ACGIH) Threshold Limit Value (TLV), 2006 K:\12000\12900\12987\129870\RAP\App C HASP\Appendices_TRR.doc

SDS Library

Move your SDS library online today

Check Icon
Setup – Easy setup with our database of 16 million+ SDSs
Check Icon
Up-to-date – Your SDS get updated to latest versions.
Check Icon
Employee access – Tablets, Smartphones, or link from Corporate Intranet
Check Icon
Safety – One-click access to first aid information.
Check Icon
Labels – Generate Secondary Container Labels with just one click.