Fragrance No. 3

Hazard statements (CLP)

H226, H227, H303, H320, H336

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS classification Flam. Liq. (Category 4), H227 Acute Tox. (Category 5), H303 Label elements, including precautionary statements

Signal word

Warning Pictogram: N/A Hazards statements H227 - Combustible liquid; H303- May be harmful if swallowed Precautionary statements P210- Keep away from heat, hot surfaces, open flames, sparks, P280- Wear protective gloves, eye protection Hazards not otherwise classified: none Substance: Not applicable Mixture Chemical Name Warning

Product definition

GHS-US classification Peppermint oil CAS# 8006-90-4 100% Flam. Liq. 4, H227; Acute Tox. 5, H303 Chemicals where a trade secret is claimed: none FIRST AID MEASURE Description of the first aid measure INGESTION: Never give anything by mouth to unconscious person. Rinse mouth and get conscious person drink a glass of milk or water. Do NOT induce vomiting unless directed to do so by medical personnel. Get medical attention if necessary INHALATION: Remove to fresh air. Get medical attention if necessary EYE CONTACT: Wash immediately with plenty of water, and continue washing for at least 15min., occasionally lifting upper and lower eyelids. Seek medical attention if necessary SKIN CONTACT: Flush thoroughly with mild soap and water. Remove contaminated clothing. Get medical attention if necessary Most important symptoms and effects, both acute and delayed: Refer to section 11 Indication of any immediate medical attention and special treatment needed: No additional information available FIREFIGHTING MEASURES Extinguishing media: Combustible liquid Suitable extinguishing media: Use TriCiass, dry chemical extinguisher for surrounding fires Special hazard arising from the substance or mixture: Not available Advice for firefighters: Use self-contained breathing apparatus and protective clothing ACCIDENTAL RELEASE MEASURES Personal precautions: Wear laboratory grade gloves, eye protection and a lab coat Emergency procedures: Restrict unprotected personnel from the area Methods and material used for containment and cleanup procedure: Contain the spill with an inert absorbent material and deposit in a sealed con- tainer. For small spills use paper towel. Ventilate and wash spill area with soap and water HANDLING AND STORAGE Precaution for safe handling: Read label on container before using. Keep away from heat, sparks and flame Do not wear contact lenses when working with chemicals. For laboratory use only. Not for drug, food or household use. Use only under adult supervision Avoid breathing vapor. Use hood or with adequate ventilation. Wash hands thoroughly after handling Storage: Flammable cabinet. Keep container tightly closed in cool, well-ventilated area incompatibility: Refer to section 10 Control parameters: ACGIH TWA: lOg/m' (peppermint oil) Exposure controls: Avoid contact with eyes, skin, and clothing: Wear chemical splash goggles, chemical-resistant gloves, and chemical-resistant apron Use ventilation to keep airborne concentrations below exposure li mits Respiratory protection: Non should be needed if normal laboratory handling at room temperature PHYSI~L AND CHEMICAL PROPERTIES Physical state: Liquid Boiling point: Not available Appearance: Colorless to pale yellow Melting point: Not available Odor: peppermint Freezing point: Not available pH: Not available Decomposition temp: Not available Vapor Pressure ( mm Hg): Not available Solubility: Not available Vapor Density: Not available Specific gravity (H,O = 1): Not available Evaporation Rate: Not available Percent volatile(%): 100% Viscosity: N/ A Molecular formula Mixture Flash point: 67'C/153'F Molecular weight: Mixture Autoignition: N/A STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: Incompatible materials, Heat, sparks and open flames Incompatibilities: Strong oxidizers Hazardous decomposition: When heated to decomposition, produces acrid smoke and fumes Hazardous polymerization: Will not occur Acute effects: Eyes: Causes eye irritation. Skin: May cause skin Irritation. Prolonged or repeated skin contact may cause allergic dermatitis. Inhalation: May cause irritation of the respiratory tract. Ingestion: May cause gastrointestinal track irritation. May affect behavior/ central nervous system Toxicological data ORL-RATID50: 2426 mg/kg [Rat] IHL-RAT LD5a: Not available SKN-RABIT LDsa: Not available Carcinogenicity Product Name Fragrance No. 5 Alternative names Amyl Acetate mixture Product Number 3-37EA Relevant identified uses of the substance or mixture and uses advised against Identified uses For laboratory and educational use only Details of the supplier of the safety data sheet Company LAB-AIDS•, Inc, 17 Colt Ct., Ronkonkoma, NY 11779, USA Telephone 1800 3818003 Fax 631 820 8268 Emergency telephone number number CHEMTREC 1 800 424-9300 Classification of the substance or mixture GHS classification Flam. Liq. (Category 3), H226 Eye lrrit. (Category 2B), H320 to&.. <!> Specific Target Organ Toxicity Single Exposure (Category 3), H336 2.2 Label elements, including precautionary statements

Hazard categories

3 Packing group: Ill Exceptions: Ltd Qty. SL

Hazard pictograms

Hazards statements: H226 - Flammable liquid and vapor. H320-Causes eye irritation, H336-May cause drowsiness or dizziness.

Precautionary statements

P210- Keep away from heat, hot surfaces, open flames, sparks, P280- Wear protective gloves, eye protection.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Signal word: Warning