Temp-Alarm 13C

Hazard statements (CLP)

H225, H315, H318, H332, H336, H361, H373, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA 241, Classification of the substance or mixture Classification in accordance with the Globally Harmonized Standard Flam. Liq. 2 H225 Acute Tox. 4 (Inhalation:dust mist) H332 Skin Irrit. 2 H315 Eye Dam. 1 H318 Repr. 2 H361 STOT SE 3 H336 STOT RE 2 H373 Aquatic Chronic 3 H412 Full text of classification categories and H statements see section 16 22

2.2 Label elements

SO GHS-US labelling

Hazard pictograms

GHS02 GHS05 GHSO7 GHS08

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H318 - Causes serious eye damage H332 - Harmful if inhaled H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H412 - Harmful to aquatic life with long lasting effects see section 16 41, Description of first aid measures First-aid measures general Never give anything by mouth to an unconscious person. First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell First-aid measures after skin contact Rinse skin with water/shower. Remove/Take off inmediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Inmediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell 42 Most important symptoms and effects, both acute and delayed Symptoms/injuries . Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause drowsiness or dizziness. Symptoms/injuries after skin contact © Causes skin irritation. Symptoms/injuries after eye contact - Causes serious eye damage. Symptoms/injuries after ingestion Nausea. Drowsiness. Headache. 21/09/2015 EN (English) SDS Ref.: LACO1509011 28 43. Indication of any immediate medical attention and special treatment needed Treat symptomatically. [ SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide. Dry chemical. Foam. Unsuitable extinguishing media None known. 5.2. Special hazards arising from the substance or mixture Fire hazard Highly flammable liquid and vapour. Explosion hazard May form flammable/explosive vapour-air mixture Reactivity No dangerous reactions known 5.3. Advice for firefighters Firefighting instructions Do not allow run-off from fire fighting to enter drains or water courses. Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection Wear a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. Avoid all eye and skin contact and do not breathe vapour and mist 6.1.1. For non-emergency personnel Protective equipment Chemical goggles or safety glasses. Wear suitable gloves. Emergency procedures Evacuate unnecessary personnel 6.1.2. For emergency responders Protective equipment Chemical goggles or safety glasses. Wear suitable gloves. Emergency procedures Stop leak if safe to do so. Ventilate area. 6.2 Environmental precautions Avoid release to the environment. Do not discharge into drains or the environment. 6.3. Methods and material for containment and cleaning up For containment Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams Methods for cleaning up Absorb and/or contain spill with inert material, then place in suitable container. 6.4. Reference to other sections disposal information. Section 7 safe handling. Section 8 personal protective equipment SECTION 7: Handling and storage 71. Precautions for safe handling Additional hazards when processed Handle empty containers with care because residual vapours are flammable. Precautions for safe handling No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well- ventilated area. Avoid all eye and skin contact and do not breathe vapour and mist. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work 72. Conditions for safe storage, including any incompatibilities Technical measures Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment Storage conditions Keep in fireproof place. Keep container tightly closed. Incompatible materials Heat sources. Heat and ignition sources Keep away from heat, sparks and flame. Storage area Store in dry, cool, well-ventilated area 21/09/2015 EN (English) SDS Ref.: LACO1509011 £ 73. Specific end use(s) Temperature indicator. 8.1. Control parameters Temp-Alarm® 13C ACGIH Not applicable

Precautionary statements

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, open flames, sparks. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P260 - Do not breathe mist, spray, vapours P264 - Wash hands thoroughly after handling 21/09/2015 EN (English) SDS Ref.: LACO1509011 8 P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear eye protection, protective gloves P302+P352 - If on skin: Wash with plenty of water P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P310 - Immediately call a doctor P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P370+P378 - In case of fire: Use dry extinguishing powder, foam, carbon dioxide (CO2) to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to an authorised waste collection point 23.

2.3 Other hazards

24

Ingredient(s) with unknown acute toxicity

1.47 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) 1.47 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist)) 3.1 Substance Not applicable 3.2 Mixture Name

Product definition

% (wiw)

Classification (GHS-US)

Toluene (CAS No) 108-83-3 59.52 - 65.97 Flam. Liq. 2, H225 Skin Iit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox 1, H304 Aquatic Chronic 3, H412 copper dinydroxide (CAS No) 20427-59-2 2379 Acute Tox. 4 (Oral), H302 Acute Tox. 2 (Inhalation:dust. mist), H330 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 2, H411

Further information

Do not eat, drink or smoke when using this product. 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Opaque liquid Colour Blue. Odour Hydrocarbons. Odour threshold No data available pH No data available Relative evaporation rate (butyl acetate=1) © 45 Melting point © No data available Freezing point © No data available Boiling point 11°C Flash point 6°C Auto-ignition temperature © No data available Decomposition temperature © No data available Flammability (solid, gas) © No data available Vapour pressure 53 mm Hg Relative vapour density at 20 °C No data available Relative density 11 Solubility insoluble in water. Log Pow No data available Log Kow No data available Viscosity, kinematic No data available 21/09/2015 EN (English) SDS Ref.: LACO1509011 a8 Viscosity, dynamic No data available Explosive properties No data available Oxidising properties No data available Explosive limits © No data available VOC content 7029/l 10.1. Reactivity No dangerous reactions known. 10.2. Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Open flame. Direct sunlight. 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products May release flammable gases. Burning produces irritating, toxic and noxious fumes. Carbon oxides (CO, CO2). 1.1, Information on toxicological effects Acute toxicity Inhalation dust,mist Harmful if inhaled Temp-Alarm® 13C ATE CLP (dust mist) | 1.896 mg/iah Toluene ( 108-88-3) LD50 oral rat 5580 mg/kg EU Method B.1 (Acute Toxicity (Oral)) LC50 inhalation rat (mg/l) > 20 mg/l/4h OECD Guideline 403 (Acute Inhalation Toxicity) ATE CLP (oral) 5580.000 mg/kg bodyweight copper dihydroxide ( 20427-59-2) LD50 oral rat 552 mg/kg LD50 dermal rat > 2000 mg/kg LC50 inhalation rat (mg/l) 0451 mg/liah ATE CLP (oral) 552 000 mg/kg bodyweight ATE CLP (vapours) 0451 mg/l/ah ATE CLP (dust,mist) 0.451 mg/l/4h Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes serious eye damage. Respiratory or skin sensitisation Not classified ‘Germ cell mutagenicity Not classified Carcinogenicity Not classified. Toluene ( 108-88-3) IARC group | 3- Not classifiable Reproductive toxicity Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single May cause drowsiness or dizziness. exposure) Specific target organ toxicity (repeated May cause damage to organs through prolonged or repeated exposure. exposure) Toluene ( 108-88-3) LOAEL (inhalation, rat, gas, 90 days) 1250 ppmv/6h/day NOAEL (oral, rat, 90 days) 625 mg/kg bodyweight/day EU Method B.26. Increased relative weights of liver and kidney are interpreted as toxicologically insignificant differences in the absence of histological findings. NOAEL (inhalation, rat, gas, 90 days) 300 ppmv/6hiday OECD Guideline 453 Aspiration hazard Not classified 2110912015 EN (English) SDS Ref.: LACO1509011 Potential adverse human health effects and symptoms Symptoms/injuries after inhalation Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause drowsiness or dizziness. Symptoms/injuries after skin contact © Causes skin irritation. Symptoms/injuries after eye contact - Causes serious eye damage. Symptoms/injuries after ingestion © Nausea. Drowsiness. Headache. Likely routes of exposure - Inhalation;Skin and eye contact 121 Toxicity Ecology - water Harmful to aquatic life with long lasting effects Toluene ( 108-88-3) LC50 fish 1 5.5mg/l EC50 Daphnia 2 3.78 mg/l ErC50 (algae) 134 mg/l LOEC (chronic) 277 mg/l NOEC chronic fish 1.39 mg/l NOEC chronic crustacea 0.74 mg/I copper dihydroxide ( 20427-59-2) LC50 fish 1 [ 810 pgii 96 h 12.2. Persistence and degradability Temp-Alarm® 13C Persistence and degradability | May cause long-term adverse effects in the environment. Toluene ( 108-88-3) Persistence and degradability | Readily biodegradable. 123. Bioaccumulative potential Toluene ( 108-88-3) Bioconcentration factor (BCF REACH) 90 Log Kow 273 124, Mobility in soil No additional information available 125, Other adverse effects No additional information available 131 Waste treatment methods Sewage disposal recommendations - Do not dispose of waste into sewer. Waste disposal recommendations - Dispose in a safe manner in accordance with local/national regulations. Additional information Handle empty containers with care because residual vapours are flammable. Ecology - waste materials © Avoid release to the environment In accordance with DOT and TDG Transport document description - UN1263 Paint (including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base), 3, Il UN-No.(DOT) UN1263 Proper Shipping Name (DOT) * Paintincluding paint, lacquer, enamel, stain, shellac solutions, vamnish, polish, liquid filler, and liquid lacquer base Transport hazard class(es) (DOT) 3 - Flammable liquid Packing group (DOT) 11 - Medium Danger ADR Transport document description UN 1263 PAINT, 3, I, (D/E) Proper Shipping Name (ADR) o PAINT Packing group (ADR) o Class (ADR) . 3 - Flammable liquid Transport by sea UN-No. (IMDG) UN 1263 2110912015 EN (English) SDS Ref.: LACO1509011 68 Proper Shipping Name (IMDG) PAINT Class (IMDG) 3 - Flammable liquids Packing group (IMDG) n Air transport UN-No. (IATA) UN 1263 Proper Shipping Name (IATA) Paint Class (IATA) 3- Flammable Liquids Packing group (IATA) it 15.1. US Federal regulations Toluene (108-88-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's 1000 Ib List of Lists) copper dihydroxide (20427-59-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA Toluene (108-88-3) Listed on the Canadian DSL (Domestic Substances List) inventory. copper dihydroxide (20427-59-2) Listed on the Canadian DSL (Domestic Substances List) inventory. EU-Regulations Toluene (108-88-3) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) copper dihydroxide (20427-59-2) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Temp-Alarm® 13C Allingredients are listed in the Toxic Substances Control Act (TSCA). Allingredients are listed on the Canadian Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL). All components are listed on the EEC inventory European Inventory of Existing Commercial Chemical Substances (EINECS). 15.3. US State regulations Toluene (108-88-3) U.S. - California - Non-significant risk level Proposition 65 - (NSRL) Carcinogens List Developmental Toxicity Reproductive Toxicity - Female Male No Yes 7000 Toluene (108-88-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Indication of changes - Original Document. 21/09/2015 EN (Engiish) SDS Ref.: LACO1509011 78 Data sources ACGIH (American Conference of Governement Industrial Hygienists). European Chemicals Agency (ECHA) C&L Inventory database. Accessed at hitp//s /web/c formatic Ii! icals/cl-i Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing”, Fifth Edition National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th edition. OSHA 29CFR 1910.1200 Hazard Communication Standard. TSCA Chemical Substance Inventory. Accessed at http//www.epa.gov/oppt/existingchemicals/pubs/tscainventory/howto_html. Abbreviations and acronyms ATE: Acute Toxicity Estimate. CAS (Chemical Abstracts Service) number. CLP: Classification, Labelling, Packaging. EC50: Environmental Concentration associated with a response by 50% of the test population. GHS: Globally Harmonized System (of Classification and Labeling of Chemicals). LD50: Lethal Dose for 50% of the test population. OSHA: Occupational Safety & Health Administration. PBT: Persistent, Bioaccumulative, Toxic. TWA: Time Weight Average. TSCA: Toxic Substances Control Act.

2.1 Classification of the substance or mixture

Classification in accordance with the Globally Harmonized Standard Flam. Liq. 2 H225 Acute Tox. 4 (Inhalation:dust mist) H332 Skin Irrit. 2 H315 Eye Dam. 1 H318 Repr. 2 H361 STOT SE 3 H336 STOT RE 2 H373 Aquatic Chronic 3 H412 Full text of classification categories and H statements : see section 16 22