OSHA Yes

Hazardous Ingredients

Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared 3/2000 Product Number: 6000,6001,6002,6003,6004,6005,6006,6065 Section 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Section 2: Identification of Product Chemical Family: Inorganic Product Names: Shell Pink 6000, Alpine Rose 6001, Rose Pink 6002, Crimson 6003, Crimson 6004, Deep Crimson 6005, Deep Crimson 6006, Pink Extender, 6067 Chemical Abstract Number (CAS): 68187-12-2 Chemical Name: Chrome Tin Pink Sphene Chemical Formula CaO,SnO.SiO2 Cr2O3 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1313-13-2 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. Symptoms of overexposure: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: mechanical irritation to the eye may occur such as watering, reddening de to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating , non-toxic if swallowed. Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 ________ SiO2 + 2 Symptoms of overexposure: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) There are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable. Ingestion: Not applicable. 1 Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms Continued ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 Symptoms of overexposure: Inhalation: No information found on acute overexposure. Chronic exposure to tin oxide fumes or dust may result in Stannosis, a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. Section 5: Emergency and First Aid Procedures: Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!! Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. Section 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye stations must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. Section 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: oderless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: Pink Powder Section 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A 2 Section 9: Fire and Explosive Data Flash point: N/A Flammable Limits: None Unusual Fire and Explosion Hazard: None expected Extinguishing Media: Carbon dioxide, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. Section 10: Spill or Leak Procedures: Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X are in reference to the finished product. **************Attention All Retailers of Mason Stains************** ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this Material Safety Data Sheet must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY ! MATERIAL SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. DISCLAMER Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed to be accurate and reliable as of the date of publication or revision but makes no warranty that it is. This information provided should be made available as required by the Federal OSHA Hazard Communication Standard 1910.1200 to ANYONE who handles, uses, stores, transports or will otherwise be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety of any individual who misuses this product by not complying with manufacturer’s instructions contained herein or additional /other measures that may be required under particular conditions. Last issued: 11/97 Updated: 3/2000 3 4 Date Prepared May 2003 Product Number: 6007, 6008, 6090 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Vanadium Oxide (VO3) 0.05 mg/m3 Cas # 1314-62-1 SYMPTOMS OF OVEREXPOSURE: Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing. Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible. Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6009, 6023, 6098 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Vanadium Oxide (VO3) 0.05 mg/m3 Cas # 1314-62-1 SYMPTOMS OF OVEREXPOSURE: Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing. Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible. Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZrO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas #1314-24-4 5 mg/m3 (respirable) 5 mg/m3 (respirable) 15 min. C SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6020 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al2,O3) 10 mg/mg3 (total) 15 mg/m3 (total) N/A Cas # 1344-28-1 5 mg/m3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1 % crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin contact: May cause abrasions. Ingestion: May cause irritation. ACGIH-TLVs OSHA PELs NOISHA RELs Manganese Compound (Mn) 0.2 mg/mg3 5 mg/mg3 1.0 mg/mg3 Cas # 7349-96-5 3.0 mg/mg3 SYMPTOMS OF OVEREXPOSURE: Inhalation: Elemental Manganese fume and dust, when in high concentrations, may adversely affect the central nervous system with symptoms including langour, sleepiness, weakness, emotional disturbances, spastic gait, mash-like facial expressions and paralysis. Eye Contact: May cause irritation, if persists call doctor. Skin Contact: May cause abrasions. Ingestion: May cause irritation. Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6024, 6025, 6026, 6027, 6022, 6033, 6421, 6021, 6028,5987,5988 Updated: December 2009 k5997 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Cadmium/Selenium Compound (CdSeS) 0.01 mg/mg3 .005 mg/m3 (total) 0.1 mg/m3 Cas # 7440-43-9 .002 mg/mg3 (respirable) ACGIH, OSHA, IARC, NTP: consider various forms of cadmium are to be carcinogenic. SYMPTOMS OF OVEREXPOSURE: Inhalation: Overexposure to Cd can result in metallic taste in mouth, headache, shortness of breath, chest pains, weakness, leg pains and fluid in the lung. These symptoms may be delayed, sometimes occuring 4-8 hrs. after exposure. Long term overexposure to cadmium fumes and dust have been associated with emphysema, bronchitis and kidney damage. Chronic over- exposure to metal and cadmium compounds, such as cadmium oxide, cadmium sulfide, cadmium sulfate and cadmium chloride, may result in lung cancer, although a definite cause-effect relationship has not been fully established. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: Swallowing may result in severe nausea, vomiting, diarrhea, stomach cramps, salivation, headache, muscle cramps and dizziness. ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZrO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas # 1314-24-4 5 mg/m3 (Respirable) 5 mg/m3 (respirable) 15 min. C SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6103, 6107, 6109, 6121, 6122, 6123, 6125, 6126, 6129, 6163, 6166, 6181,k7046,k7047 SECTION 1: Manufacturer Identification Updated: January 2009 Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. ACGIH-TLVs OSHA PELs NOISHA RELs Iron Oxide (Fe2O3) 5 mg/m3 10 mg/m3 5 mg/m3 Cas # 1309-37-1 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of its carcinogencity in humans/animals. The value is for a particulate matter containing no asbestos and 1% crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called Sideordsis. Eye Contact: May cause irritation. Skin Contact: May cause mechanical skin irritation. Ingestion: Expected to be non-toxic. Zinc Oxide (ZnO) 10 mg/m3 10 mg/m3(total) 5 mg/m3 Cas # 1314-13-2 5 mg/m3 (respirable) SYMPTOMS OF OVEREXPOSURE: Inhalation: High levels of dust may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat. Chronic exposure may produce symptoms known as metal fume fever or "zinc shakes", an acute, self-limiting condition without recognized coomplications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and vomiting. May aggravate respiratory conditions. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: May cause irritation to the gastro-intestinal tract. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6204, 6206, 6263, 6264 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZrO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas # 1314-24-4 5 mg/m3 (Respirable) 5 mg/m3 (respirable) 15 min. C SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6211, 6236 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Vanadium Oxide (VO3) 0.05 mg/m3 Cas # 1314-62-1 SYMPTOMS OF OVEREXPOSURE: Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZrO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas # 1314-24-4 5 mg/m3 (Respirable) 5 mg/m3 (respirable) 15 min. C SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6302, 6317, 6318, 6331, 6332, 6333, 6336, 6360 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al2,O3) 10 mg/mg3 (total) 15 mg/m3 (total) N/A Cas # 1344-28-1 5 mg/m3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1 % crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin contact: May cause abrasions. Ingestion: May cause irritation. ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. ACGIH-TLVs OSHA PELs NOISHA RELs Cobalt Oxide (Co3O4) 0.02 mg/m3 0.5 mg/m3 N/A Cas # 1308-06-1 ACGIH Animal carcinogen Agent is carcinogenic in experimental animals at dose levels, by route(s) of administration at site, or histologic type, or by mechanism considered relevant to workers exposure. Available epidemiologis studies do not confirm an increased risk of cancer in humans except under common levels of exposure. SYMPTOMS OF OVEREXPOSURE: Inhalation: Prolonged inhalation of dust or metal dust, and fume or mist containing cobalt may cause serious respiratory illness. May cause an irritation of respiratory organs of sensitive persons resulting in obstruction of airways with shortness of breath. Eye Contact: May cause serious eye irritation. Skin Contact: Prolonged exposure may produce irritation Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Zinc Oxide (ZnO) 10 mg/m3 10 mg/m3(total) 5 mg/m3 Cas # 1314-13-2 5 mg/m3 (respirable) SYMPTOMS OF OVEREXPOSURE: Inhalation: High levels of dust may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat. Chronic exposure may produce symptoms known as metal fume fever or "zinc shakes", an acute, self-limiting condition without recognized coomplications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and vomiting. May aggravate respiratory conditions. Eye Contact: May cause irritation. Skin Contact: May cause irritation. Ingestion: May cause irritation to the gastro-intestinal tract. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6310, 6363 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al2,O3) 10 mg/mg3 (total) 15 mg/m3 (total) N/A Cas # 1344-28-1 5 mg/m3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1 % crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin contact: May cause abrasions. Ingestion: May cause irritation. ACGIH-TLVs OSHA PELs NOISHA RELs Cobalt Oxide (Co3O4) 0.02 mg/m3 0.5 mg/m3 N/A Cas # 1308-06-1 ACGIH Animal carcinogen Agent is carcinogenic in experimental animals at dose levels, by route(s) of administration at site, or histologic type, or by mechanism considered relevant to workers exposure. Available epidemiologis studies do not confirm an increased risk of cancer in humans except under common levels of exposure. SYMPTOMS OF OVEREXPOSURE: Inhalation: Prolonged inhalation of dust or metal dust, and fume or mist containing cobalt may cause serious respiratory illness. May cause an irritation of respiratory organs of sensitive persons resulting in obstruction of airways with shortness of breath. Eye Contact: May cause serious eye irritation. Skin Contact: Prolonged exposure may produce irritation Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6315, 6364, 6374, 6376, 6378, 6391 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable ACGIH-TLVs OSHA PELs NOISHA RELs Vanadium Oxide (VO3) 0.05 mg/m3 Cas # 1314-62-1 SYMPTOMS OF OVEREXPOSURE: Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZrO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas # 1314-24-4 5 mg/m3 (Respirable) 5 mg/m3 (respirable) 15 min. C SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute inhalation to respirable dust which contains radioactive uranium, tohium and radium may cause lung cancer. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6404 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Alumina Oxide (Al2,O3) 10 mg/mg3 (total) 15 mg/m3 (total) N/A Cas # 1344-28-1 5 mg/m3 (respirable) ACGIH: The value for particulate matter containing no asbestos and 1 % crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Acute may cause coughing and shortness of breath. Chronic may adversely effect breathing capacity. Eye Contact: Direct contact may cause irritation. Skin contact: May cause abrasions. Ingestion: May cause irritation. ACGIH-TLVs OSHA PELs NOISHA RELs Tin Oxide (SnO) 2.0 mg/m3 Cas # 21651-19-4 SYMPTOMS OF OVEREXPOSURE: Inhalation: No information found on acute overexposure. Chronic exposure to tin oside fumes or dust may result in Stannosis a form of Phenumoconiosis. Eye Contact: Abrasive, mild irritant Skin Contact: Possible irritant. Ingestion: Considered non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Vanadium Oxide (VO3) 0.05 mg/m3 Cas # 1314-62-1 SYMPTOMS OF OVEREXPOSURE: Inhalation: Irritation of the respiratory tract, chest tightness, wheezing, coughing Eye Contact: Irritation possible with corneal injury. Skin Contact: Irritation with reddening and itching. Absorption of harmful amounts possible Ingestion: Abdominal discomfort, nausea, vomiting, cramping. Harmless greenish tongue discoloration. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6433, 6450, 6410 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Zirconium Oxide (ZnO) 10 mg/m3 (total) 15 mg/m3 (total) 5 mg/m3 Cas # 1314-13-2 5 mg/m3 (Respirable) 5 mg/m3 (respirable) 15 min. C Praseodymium Oxide (P6O11) Cas # 12037-29-5 SYMPTOMS OF OVEREXPOSURE: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Eye Contact: May cause irritation with discomfort, tearing or blurring of vision. Skin Contact: Not applicable. ACGIH-TLVs OSHA PELs NOISHA RELs Silica, Crystalline (SiO2) 0.1 mg/m3 10 mg/m3 0.05 mg/m3 Cas # 14808-60-7 SiO2 + 2 SYMPTOMS OF OVEREXPOSURE: Inhalation: a) Prolonged exposure to respirable crystalline silica (quartz) can cause Silicosis, a fibrosis (scarring) of the lungs. Silicosis may be progressive; it may lead to disability and death. Silicosis increases risk of Tuberculosis. b) Inhaled from occupational sources is classified as carcinogenic to humans. (cancer) c) There is evidence that exposure to respirable crystalline silica or that the disease Silicosis is associated with increased incidence of Sceroderma, an auto-immune disorder manifested by fibrosis (scarring) of the skin and internal organs. d) Thjere are several studies suggesting that exposure to respirable silica or that the disease Silicosis is associated with the increased incidence of kidney disorders. (Nephrotoxicity) Eye Contact: May cause abrasions of the cornea. Skin Contact: Not applicable Ingestion: Not applicable SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST. disclaimer Date Prepared May 2003 Product Number: 6600 Updated: January 2009 SECTION 1: Manufacturer Identification Mason Color Works, Inc. Phone: (330) 385-4400 250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488 East Liverpool, OH 43920-5076 Identity/Information and Overexposure Symptoms ACGIH-TLVs OSHA PELs NOISHA RELs Chrome Oxide (Cr2O3) 0.5 mg/m3 Cas # 1308-38-9 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of carcinogencity in humans/animals. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated prolonged exposure to trivalent compounds may cause delayed effects involving the respiratory system. Eye Contact: Mechanical irritation to the eye may occur such as watering, reddening do to exposure to fines. Skin Contact: Expected to be non irritating. Ingestion: Considered to be non-irritating, non-toxic if swallowed. ACGIH-TLVs OSHA PELs NOISHA RELs Cobalt Oxide (Co3O4) 0.02 mg/m3 0.5 mg/m3 N/A Cas # 1308-06-1 ACGIH Animal carcinogen Agent is carcinogenic in experimental animals at dose levels, by route(s) of administration at site, or histologic type, or by mechanism considered relevant to workers exposure. Available epidemiologis studies do not confirm an increased risk of cancer in humans except under common levels of exposure. SYMPTOMS OF OVEREXPOSURE: Inhalation: Prolonged inhalation of dust or metal dust, and fume or mist containing cobalt may cause serious respiratory illness. May cause an irritation of respiratory organs of sensitive persons resulting in obstruction of airways with shortness of breath. Eye Contact: May cause serious eye irritation. Skin Contact: Prolonged exposure may produce irritation Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. ACGIH-TLVs OSHA PELs NOISHA RELs Iron Oxide (Fe2O3) 5 mg/m3 10 mg/m3 5 mg/m3 Cas # 1309-37-1 ACGIH Not classifiable as a human carcinogen Inadequate data on which to classify the agent in terms of its carcinogencity in humans/animals. The value is for a particulate matter containing no asbestos and 1% crystalline silica. SYMPTOMS OF OVEREXPOSURE: Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called Sideordsis. Eye Contact: May cause irritation. Skin Contact: May cause mechanical skin irritation. Ingestion: Expected to be non-toxic. ACGIH-TLVs OSHA PELs NOISHA RELs Nickel Oxide (NiO) 0.2 mg/m3 1 mg/m3 0.015 mg/m3 Cas # 7440-02-0 ACGIH: Inhalable fraction, the concentration of inhalable particulate for application of this TLV is to be determined from the fraction passing a size-selector with characteristics defined in (A1). (A1) - Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemologic studies of, or convincing clinical evidence, in exposed humans. (Ca) Carcinogen. SYMPTOMS OF OVEREXPOSURE: Inhalation: Primary enters through inhalation of dust. Eye Contact: May cause irritation in eyes and mucous membranes. Skin contact: may irritate skin, can cause "Nickel Itch" in sensitive persons. Ingestion: Low order of acute toxicity. May cause gastro-intestinal disorders. SECTION 5: Emergency and First Aid Procedures Eye: flush thoroughly with water for 15 minutes. Skin: remove contaminated clothing, wash thoroughly with soap and water. Inhalation: remove to fresh air, may give oxygen if needed. Ingestion: give large amounts of water to induce vomiting, only in conscious persons. IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN Principal Routes of Entry: Inhalation: Dust from this product may cause irritation of the respiratory system. Overexposure may cause lung damage. Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation. SECTION 6: Special Protection Information Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit. Wash thoroughly after handling. No food or beverage should be consumed in work area. Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety showers and eye statioins must be present in work stations. Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels below Occupational Exposure Limits. SECTION 7: Physical and Chemical Characteristics Boiling Point: N/A Odor: Odorless Solubility in water: trace Specific Gravity (water=1): N/A Vapor Pressure (mmHg): N/A Evaporation rate: None Vapor Density (air=1): N/A % Volatile by volume: None Appearance: SECTION 8: Reactivity Data Stability: Stable Hazardous Polymerization: will not occur Incompatibility: None Hazard Decomposition of product: N/A SECTION 9: Fire and Explosive Data Flash point: N/A Flammable Limits: Unusual Fire and Explosion Hazard: None expected. Extinguishing Media: Carbon Dioside, dry chemical or water Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved. SECTION 10: Spill or Leak Procedures Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container for disposal. Waste disposal method in accordance with Federal, State and Local Laws. This product is a blend of various metal oxides, salts and some compounds which are interfused by high calcinations to form the finished product. Section 3, Hazardous ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to individual components. Section 5 through Section 10 are in reference to the finished product. * * * * * * * Attention all Retailers of Mason Stains * * * * * * * ALL retailers of this product are REQUIRED by law to supply their customers with a copy of material safety data sheet with initial purchase. ***SARA 313 This product contains certain oxides and compounds which are subject to reporting requirements of Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning and Community Right to Know Act and of 40 CRF, Part 372. The information contained in this MSDS must be provided to every employee who is exposed to this product in any way. We recommend the user reads and understands the contents herein before using this material. PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST.

HMIS® ratings

Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic C.I PIGMENT RED 233/YELLOW 160 Product Names: Peach 6007, Peach 6008, Coral 6090 Chemical Abstract Number(CAS): 68187-12-2, 68186-93-6 Chemical Name: Chrome Tin Vanadium Coral Chemical Formula CaO, SnO.SiO2 Cr2O3 + (Sn, V)2 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic C.I PIGMENT RED 233/YELLOW 160 Product Names: Coral 6009, Clover Pink 6023, Flesh 6098 Chemical Abstract Number(CAS): 68186-93-6,68186-93-6,10101-52-7 Chemical Name: Chrome Tin Vanadium Coral Chemical Formula CaO, SnO.SiO2 Cr2O3 + (Zr,V)2 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic C.I PIGMENT RED 231 Product Names: Manganese Alumina Pink 6020 Chemical Abstract Number(CAS): 68186-99-2 Chemical Name: Manganese Alumina Pink - Corundum Chemical Formula: (Al,Mn)2O3 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Orange 6024, Coral Red 6025, Lobster 6026, Tangerine 6027, Shrimp 6022, Sunset 6033, Bright Yellow 6421, Dark Red 6021, Orange 6028, Red k-5987, Red k-5988,Red k-5997 Chemical Abstract Number(CAS):72828-62-7 Chemical Name: Encapsulated Zircon/Cadmium Pigment Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Golden 6103, Dark Golden 6107, Deep Brown 6109, Saturn Orange 6121, Cedar 6122 Saddle 6123, Leather 6125, Hazelnut 6126, Golden Ambrosia 6129, Terra Cotta 6163, Camel Beige 6166, Sandstone 6181 Chemical Abstract Number(CAS):68186-88-9 Chemical Name: Zinc Iron Chromite Brown - Spinel Chemical Formula: (Zn,Fe)(Fe,Cr)2O4 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Victoria Green 6204, Grass Green 6206, Victoria Green 6263, 6264 Chemical Abstract Number(CAS) 68553-01-5 Chemical Name: Victoria Green - Garnet Chemical Formula: 3CaO.Cr2O33SiO2 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Pea Green 6211, Chartreuse 6236 Chemical Abstract Number(CAS) 68186-95-8, 68186-93-6 Chemical Name: Zirconium Tin Vanadium Green Chemical Formula: (Zr,V)SiO4 (Sn,V)O2 + Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Cadet Blue 6302, Lavender 6317, Amethyst 6318, Orchid 6331, 6332, Lavendar 6333, Peacock 6336, Willow Blue 6360 Chemical Abstract Number(CAS) 68187-49-5, 18282-10-5 Chemical Name: Cobalt Chromite - Spinel Chemical Formula: CoCr2O4 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Wedgewood Blue 6310, Sky Blue 6363 Chemical Abstract Number(CAS) 68186-86-7 Chemical Name: Cobalt Aluminate Blue - Spinel Chemical Formula: CoAl2O4 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Zirconium Vanadium Blue 6315, Turquoise Blue 6364, Dark Turquoise 6374, Robin's Egg Blue 6376, Zirconium Vanadium Blue 6378, Zirconium Vanadium Blue 6391 Chemical Abstract Number(CAS) 68186-95-8 Chemical Name: Zirconium Vanadium Blue - Zircon Chemical Formula: (Zr,V) SiO4 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Vanadium Yellow 6404 Chemical Abstract Number(CAS) 68186-93-6 Chemical Name: Tin Vanadium Yellow - Cassierite Chemical Formula: (Sn,V)O2 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Praseodymium Yellow 6433, Praseodymium Yellow 6450, Canary yellow 6410 Chemical Abstract Number(CAS) 68187-15-5, Chemical Name: Zirconium Praseodymium Yellow - Zircon Chemical Formula: (Zr,Pr)SiO4 Health 2* Flammability 0 Reactivity 0 Personal Protection See Section 6 *Indicates possible chronic health effects. SECTION 2: Identification of Product Chemical Family: Inorganic Product Names: Black 6600 Chemical Abstract Number(CAS) 67186-97-0 Chemical Name: Cobalt Chromite Black - Spinel Chemical Formula: (Co,Fe)(Fe,Cr)2 O4