Scented Surfactant Solution

Health hazards

Category 5 cute toxicity - Oral \Category 2 iSkin corrosion/irritation Category Serious eye damage/eye irritation 1 Category iSkin sensitization 1 \Category 2 Acute aquatic toxicity Category 3 [Chronic aquatic toxicity a Skin contact + Repeated or prolonged skin contact may cause allergic reactions with susceptible persons + Symptoms may be delayed + Irritating to skin Eye contact + Avoid contact with eyes + Risk of serious damage to eyes Inhalation + None Ingestion + May be harmful if swallowed

Hazard pictograms

q

Signal word

DANGER 4

Hazard statements

a H303 - May be harmful if swallowed A H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H401 - Toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects

Precautionary statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do, Continue rinsing P310 - Immediately call a POISON CENTER or doctor from a reasonable distance Dike fire-control water for later disposal. Fight fire with Fire Fighting Notes and Protective Measures — inhale toxic smoke and gas. If possible, Firefighters must wear appropriate protective equipment. Fight fire from upwind side. Ss Lec Evacuate non-essential ; S remove containers exposed to heat or cool with water. Use water fog to cool the ambie! eee Move the personnel to a safe ea, Use suitable extinguishing medium (Manufacturer/supplier or the comple the containers and package. Use applicable conditions) to put out the fire. Isolate the site and prohibit the unnecessary person te container to a safe area. If the containers can't be removed, use suitable extinguishing medium te le medium. Recycle the fire ‘ water fog to cool. Fire: Cut off the ignition resource and put out the fire from upwind with extinguishing services run-off and dispose it. Personal precautions - Wear protective gloves/protective clothing and eye/face protection Advice for emergency responders In the case of vapor formation use a respirator with an approved filter. Environmental precautions Should not be released into the environment. Spills and Leaks ¥ P ; Water spills: Notify the relevant authorities immediately if the product flows into rivers accidentally, lakes or oceans and take necessary measures in accordance with applicable regulations. Methods for containment Contain spill. The product should not be allowed to enter drains, water courses or the soil. Methods for cleaning up i Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and ‘ place in container for disposal according to local / national regulations (see section 13). Prevention of secondary hazards No information available. Handling Advice on safe handling Manufacturing Sites: . Clean up spill immediately. Do not allow to enter into surface water or drains. Empty containers should be taken for local recycling, recovery or waste disposal. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Hygiene Measures Manufacturing Sites: Do not eat, drink or smoke when using this product Wash hands thoroughly after handling

Other physicochemical hazards

_* None

Prevention

Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves Wash hands thoroughly after handling Wear eye/face protection

Response

If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN: Wash with plenty of water and soap Take off contaminated clothing and wash it before reuse IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician

Disposal

Dispose of contents/containers in accordance with local regulations

Storage

None Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Technical measures/Storage conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Packaging material No information available Exposure Guidelines .5 mg/m? Benzoate| inhalable particulate matter} Sk* lsopropyl Alcohol 67-63-0 TWA: 350 mg/m? TWA: 200 ppm 40 mg/L - urine (Acetone) - STEL: 700 mg/m? STEL: 400 ppm end of shift at end of workweek Recommended monitoring procedures No information available ACGIH No data available Engineering Measures Manufacturing Sites: . Prevent splashing and leaking of product. Use with local exhaust ventilation. Personal protective equipment Eye Protection Manufacturing Sites: . Tight sealing safety goggles. If splashes are likely to occur, wear:. Wear suitable face shield. Household: \Requires Eye Protection. \ Hand Protection Manufacturing Sites: . Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Household: . Gloves. \ Skin and B Protection Manufacturing Sites: | Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Wear protective gloves and protective clothing. Household: . No special protective equipment required. Respira Protection Manufacturing Sites: . Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Household: . No special protective equipment required. Hygiene Measures Manufacturing Sites: . Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Household: . No special handling advice required. 7 Section 9: PHYSICAL AND CHEMICAL PROPERTI Physical state Liquid

Environmental hazards

Toxic to aquatic life Harmful to aquatic life with long lasting effects

2.3 Other hazards

No Data Available Sodium Lauryl Sulfate 151-21-3 10 - 30 Geraniol 106-24-1 1-5 Sodium Benzoate 532-32-1 1-5 lsopropyl Alcohol 67-63-0 dS. Potassium Sorbate 24634-61-5 0-1 Inhalation IF INHALED Remove to fre sh air and keep at rest in a position comfortable for breathing. IF exposed or concerned Get medical advice/attention. Skin contact IF ON SKIN Wash with plenty of water and soap. If skin irritation or rash occurs Get medical advice/attention. Take off contaminated clothing and wash before reuse. Wash hands thoroughly after handling. Eye contact IF IN EYES: Rinse Cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Most important symptoms and effects, both acute and delayed May cause allergic skin reaction. MAY CAUSE SKIN IRRITATION. Causes serious eye damage. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Protection of first-aiders No information available. Notes to Physician Treat symptomatically. Treatment may vary with the conditions of victim and specifics of incident. In all of the potential poisoning conditions, site first-aid is important. Suitable extinguishing media Dry chemical, Water, Alcohol resistant foam, Carbon dioxide (CO 2) Extinguishing Media Which Must Not Be Used For Safety Reasons No information available . Special Hazard spray. water Cniishen may explode when heated. Keep containers and surroundings cool with Special protective equipment for fire-fighters normal

Appearance/Odor

clear Mint-like Property. Values pH 6.2 Melting point / freezing point No information available Initial boiling point and boiling range 99 °C Flash point No Flash to Boiling (NFTB) Evaporation rate No information available Flammability No information available Flammability Limit in Air Upper flammability or explosive No information available limits Lower flammability or explosive No information available limits Vapor pressure No information available Relative vapor density No information available Specific gravity No information available Solubility Soluble in water Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity No information available Explosive properties No information available Oxidizing properties No information available Sodium Lauryl Sulfate 16 Geraniol 26 Sodium Benzoate -2.13 Isopropyl Alcohol 0.05 Reactivity None under normal use conditions Stability Stable under normal conditions. Hazardous Reactions Hazardous polymerization does not occur Conditions to Avoid No information available. Incompatible Materials No information available Hazardous decomposition Products No information available COLOGICALINFORMATION Product Information

Principle Routes of Exposure

Skin contact. Ingestion. Acute toxicity May be harmful if swallowed Skin corrosionj/irritation Irritating to skin Serious eye damage/eye irritation _ Risk of serious damage to eyes Skin sensitization May cause sensitization by skin contact Respiratory sensitization Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified STOT - single exposure Not classified STOT - repeated exposure Not classified

Aspiration hazard

Not classified Component Information Sodium Lauryl Sulfate 978 mg/kg (RAT) 5001 mg/kg (RAT) > 3900 mg/m? _( Rat) 1h Geraniol 3600 mg/kg (RAT) 5001 mg/kg (RABBIT) cd ‘Sodium Benzoate 3450 mg/kg (RAT) 5001 mg/kg (RABBIT) 21 mg/L (RAT) Isopropyl Alcohol 5840 mg/kg (RAT) 13900 mg/kg (RABBIT) 25 mg/L (RAT) _Potassium Sorbate 10500 mi RAT, 5001 RAT = Sodium Lauryl Sulfate Y (OECD 405), Rabbit Geraniol 'Y (OECD 405) Sodium Benzoate OECD 405 Isopropyl Alcohol Y (OECD 405) Potassium Sorbate Y (OECD 405) Rabbit Sodium Lauryl Sulfate Y (OECD 404) Rabbit Geraniol Y (OECD 404) Geraniol \ Y (OECD 429) Isopropyl Alcohol, (Y) ecotoxicity \ Ecotoxicity effects Toxic to aquatic life. Harmful to aquatic life with long lasting effects. ~ Acute toxicii Sodium Lauryl Sulfate 29 mg/L (OECD 203, 120 mg/L 135 mg/L (activated Pimephales promelas,|_ (Desmodesmus sludge ofa 96 h) subspicatus; 72 h) predominantly domestic sewage; 3 h) Geraniol 22 mg/L (OECD 203; }13.1 mg/L (OECD 201;| 70 mg/L (OECD 209; |10.8 mg/L (OECD 202; - Danio rerio, 96 h) Desmodesmus activated sludge, |Daphnia magna; 48 h) subspicatus, 72 h) domestic; 0.5 h) Sodium Benzoate 484 mg/L (EPA OPP |30.5 mg/L (OECD 201, - 101 mg/L (OECD 202, « 72-1, Pimephales Raphidocelis Daphnia magna; 48 h) promelas, 96 h) subcapitata; 72 h) Isopropyl Alcohol 70001 mg/L (OECD | EC50: >1000mg/L - 10001 mg/L (OECD [3.2 % (Guideline nol| 203, Pimephales (96h, Desmodesmus 202; Daphnia magna; |indicated; Drosophilal promelas; 96 h) subspicatus) EC50: >1000mg/L 24h e ) melanogaster; 1 d) (72h, Desmodesmus subspicatus) Potassium Sorbate 500 mg/L (OECD 203, 100 mg/L (OECD 209; | 982 mg/L (OECD 202;| 675 mg/kg soil dw (Read across data Danio rerio; 96 h) activated sludge of a Daphnia magna, 48 h) predominantly on Hexa-2,4-dienoic} domestic sewage; 3 h) lacid; OECD 207 andj EU Method C.8; Eisenia fetida; short-term toxicity; artificial soil; 14 d) 1.357 mg/L (Pimephales Sodium Lauryl Sulfate 0.88 mg/L (Ceriodaphnia 30 mg/L (Desmodesmus dubia; 7 d) subspicatus; 3d) promelas; 42 d) Geraniol T mg/L (OECD 201, 10 mg/L (OECD 203; Danio} (13 mg/L rst 209; 0.5 Desmodesmus rerio; 4 d) subspicatus; 3 d) - Sodium Benzoate 65 mg/L ((OECD 201, | 10 mg/L (Guideline not (> 100 mg/L 5.81 mg/L (OECD a Pseudokirchneriella indicated; Danio rerio; 6 d)| (Achromobacter sp.; 7 d))| Daphnia magna; 2 subcapitata; 3 d) - Isopropyl Alcohol 7800 mg/L (Scenedesmus |1001 mg/L (Danio rerio, 28] (1050 mg/L (DIN 38412-81001 mg/L (Daphnia magna; 21 d) quadricauda; 7 d) d) Pseudomonas putida; 16 h)) Potassium Sorbate 500 mg/L (OECD 203, | (> 100 mg/L (OECD 209, | 50 mg/L (OECD 211; Danio rerio; 4d) activated sludge of a Daphnia magna; 21 d) predominantly domestic sewage, 3 h)) Persistence and degradability Sodium Lauryl Sulfate 95 % (; CO2; OECD 3¢1 B, 28 d; 81.5) Geraniol 95 % (OECD 301 A; COC removal, 3 d) Sodium Benzoate 101_(Achromobacter sp., 7 d) 94 % (CC2, 28 d) lsopropyl Alcohol 53 % (; EU Method ©.6; aerobic sewage, domestic; 02 consumption; 5 d) Potassium Sorbate 455 mg/kg soil dw (Read across data on 74.9 % (02; OECD 301 D; 28 d) Hexa-2,4-dienoic acid, OECD 207 and EU Method C 8, Eisenia fetida, short-term toxicity, artificial soil; 14 d) i SORT Sulfate 87.3 % (Simi 314D; aerobic; natural water / sediment, CO2 oe evolution; 35 d) me Geraniol 94 (OECD 301 F; 02 Eee consumption; 28 d) Sodium Benzoate 111 % (EEC-Directive 79/831, Annex V, Part C; PEE aerobic; digested sludge; ORE 02 consumption; normal medium, nitrification (> 0.1 OS Img N-NO2-/NO3- per liter), fails 10-d window criterion) Potassium Sorbate >95% (OECD 302B; 8 d) EP Bioaccumulation SOS Sodium Lauryl Sulfate Geraniol SPRUCE-X3_RANDD_CH it Scented Surfactant Solution Revision date 17-May-2024 Sodium Benzoate sepropyl Alcohol 128 ‘otassium Sorb: 0.964 0.05 (0.05) Mobility - 26 (26) =1.72 (OECD 117) auryl Sulfate 316 - 446 Geraniol 70.79 (70.79) Sodium Benzoate 7.033 sepropyl Alcohol 3.478 ‘otassit Other adverse effects sm Sopale = G No information available — Waste from R esidues/Unused Products Disposal should be in accordance with applicable regional, national and local laws and regulations Waste Disposal Method Don't dump the product into soil, sewers, drains, underground water or any body of water. Avoid release to the environment. It is suggest to contract an agency for industrial waste disposal licensed by the prefectural governor or local public authorities to dispose of the substance. Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Empty the container completely because there will be residual and disposed of in accordance with the related instructions. Personal protective measures for disposing persons see section 8. Note of Disposal: When contracting an agency for industrial waste disposal licensed by the prefectural governor or local public authorities to dispose of the substance, sign a contract and fully notify the agency of possible danger and harmfulness of the Substance. If the waste has been confirm to hazardous waste, which generated by the product or during its production and use, It's Needed to disposal in accordance with the relevant national waste regulations. Not regulated ATA \ Not regulated International Inventories lECSC Complies China Inventory Legend China Inventory of Existing Chemical Substances (IECSC) Isopropyl Alcohol Present ({0111]) Section 16: OTHER INFORMATIO Issuing Date: 17-May-2024 Revision date 17-May-2024 is No information available. EINECS: European Inv of Existing Commercial Chemical Substances