and of the

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Regulation (EC) No 1272/2008 [CLP Remove person from danger area. Supply person with fresh air and consult doctor according to symptoms. If the person is unconscious, place in a stable side position and consult a doctor. Respiratory arrest - Artificial respiration apparatus necessary.

2.1 Classification of the substance or mixture

Skin contact

CLP CLASSIFICATION

Wipe off residual product carefully with a soft, dry cloth.

Hazard statements

Remove polluted, soaked clothing immediately, wash thoroughly with plenty of water and soap, in case of Eye Irrit. 2 irritation of the skin (flare), consult a doctor. H319-Causes serious eye irritation. Dab away with polyethylene glycol 400 STOT SE 3 H335-May cause respiratory irritation. Eye contact Skin Irrit. 2 H315-Causes skin irritation. Remove contact lenses. Resp. Sens. 1 H334-May cause allergy or asthma Wash thoroughly for several minutes using copious water - call doctor immediately, have Data Sheet available. symptoms or breathing difficulties if inhaled. Ingestion Skin Sens. 1 H317-May cause an allergic skin reaction. Rinse the mouth thoroughly with water. Carc. 2 Do not induce vomiting - give copious water to drink. Consult doctor immediately. H351-Suspected of causing cancer. Never pour anything into the mouth of an unconscious person! STOT RE 2 H373-May cause damage to organs through 4.2 Most important symptoms and effects, both acute and delayed prolonged or repeated exposure by If applicable delayed symptoms and effects can be found in section 11 and the absorption route in section 4.1. inhalation (respiratory tract). The following may occur: Dermatitis (skin inflammation)

2.2 Label elements

Drying of the skin. Allergic contact eczema Labeling according to Regulation (EC) 1272/2008 (CLP) Discoloration of the skin Irritant to mucosa of the nose and throat Coughing Headaches Effect on the central nervous system Asthmatic symptoms In case of sensitivity, concentrations below the limit value may already result in asthmatic symptoms. Respiratory distress In certain cases, the symptoms of poisoning may only appear after an extended period / after several hours. 4.3 Indication of any immediate medical attention and special treatment needed In case of irritation of the lungs, perform first-aid with controlled-dosage aerosol dexamethasone. Danger Pulmonary oedema prophylaxis Medical supervision necessary due to possibility of delayed reaction. SECTION 5: Firefighting measures H319-Causes serious eye irritation. H335-May cause respiratory irritation. H315-Causes skin irritation. H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317- May cause an allergic skin reaction. H351-Suspected of causing cancer. H373-May cause 5.1 Extinguishing media damage to organs through prolonged or repeated exposure by inhalation (respiratory tract). Suitable extinguishing media P201-Obtain special instructions before use. P260-Do not breathe vapours or spray. P280-Wear CO2 protective gloves / protective clothing and eye protection / face protection. P284-Wear respiratory Extinction powder protection. Water jet spray P302+P352-IF ON SKIN Wash with plenty of water and soap. P304+P340-IF INHALED Remove Foam person to fresh air and keep comfortable for breathing. P305+P351+P338-IF IN EYES: Rinse Unsuitable extinguishing media cautiously with water for several minutes. Remove contact lenses, if present and easy to do. High volume water jet Continue rinsing. P308+P313-IF exposed or concerned: Get medical advice / attention. 5.2 Special hazards arising from the substance or mixture In case of fire the following can develop: EUH204-Contains isocyanates. May produce an allergic reaction. Oxides of carbon Oxides of nitrogen Isocyanates Methylenediphenyl diisocyanate, modified Hydrocyanic acid (hydrogen cyanide)

2.3 Other hazards

Toxic gases Danger of bursting (explosion) when heated The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not included under XIII of the regulation (EC) 1907/2006 (< 0,1 %). 5.3 Advice for firefighters The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included In case of fire and/or explosion do not breathe fumes. under XIII of the regulation (EC) 1907/2006 (< 0,1 %). Protective respirator with independent air supply. According to size of fire Full protection, if necessary. Cool container at risk with water.