D-8000

Hazard statements (CLP)

H302, H303, H315, H319, H335

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Appearance Off-white powder Physical State Powder Odor Mild Classification Skin irritation Category 2 Eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed

Signal word

Warning Hazard Statements Causes serious eye irritation Causes skin irritation Harmful if swallowed May cause respiratory irritation Precautionary Statements - Prevention Wear protective gloves, protective clothing, eye and face protection Do not get in eyes, on skin, or on clothing Do not breathe dust Wash skin and contaminated clothing thoroughly after handling Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF SWALLOWED: Rinse mouth. DO NOT induce vomiting IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Precautionary Statements - Storage Store in a secure manner. Keep container closed. Store in a well-ventilated place. Keep cool

Precautionary statements

Disposal Dispose of contents/container in accordance with local, regional, national, and/or international regulations.

2.1 Classification of the substance or mixture

Classification Skin irritation Category 2 Eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Warning Hazard Statements Causes serious eye irritation. Causes skin irritation. Harmful if swallowed. May cause respiratory irritation. Precautionary Statements - Prevention Wear protective gloves, protective clothing, eye and face protection. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Wash skin and contaminated clothing thoroughly after handling. Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Wash contaminated clothing before reuse. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Precautionary Statements - Storage Store in a secure manner. Keep container closed. Store in a well-ventilated place. Keep cool. Precautionary Statements - Disposal Dispose of contents/container in accordance with local, regional, national, and/or international regulations. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Sodium Carbonate 497-19-8 <40 Trisodium Phosphate-Dodecahydrate 10101-89-0 <15 Sodium Metasilicate 6834-92-0 <50 Ethylene Glycol Mono Butyl Ether 111-76-2 2 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact IF IN EYES: Immediately flush eyes with plenty of water occasionally lifting the upper and lower eyelids. After 15 minutes, check for and remove any contact lenses. Continue to rinse for at least 15 minutes and get medical attention. Skin Contact IF ON SKIN (or hair): Wash with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse. If irritation or burn occurs get medical attention. Inhalation Remove from exposure and move to fresh air immediately and keep in a position comfortable for breathing. Give artificial respiration if necessary. Ingestion If victim is conscious and alert, wash out mouth with water. Never give anything by mouth to an unconscious. Consult a physician or medical facility with regard to inducing vomiting. Most important symptoms and effects Symptoms Causes severe skin burns and eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use agent suitable for type of surrounding fire. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined Hazardous Combustion Products None known. Protective equipment and precautions for firefighters Wear self-contained breathing apparatus with full face piece operated in positive pressure demand mode when fighting fire. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with skin, eyes, and clothing. Environmental Precautions Prevent entry into sewers, water courses, basements or confined areas. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Sweep up and shovel material into suitable container. Dispose of properly. Flush spill area with water if appropriate, and clean this up with floor absorbent. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Avoid contact with skin, eyes, and clothing. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Keep in original container. Do not reuse container. Use appropriate personal protective equipment (see section 8). Conditions for safe storage, including any incompatibilities Storage Conditions Store in accordance with local regulations. Store in segregated and approved area. Keep container closed and store at moderate temperature in a well ventilated area, away from incompatible materials. Incompatible Materials Acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium Carbonate N/A - 497-19-8 Trisodium Phophate- Dodecahydrate TWA: 5 mg/m3 - 10101-89-0 Sodium Metasilicate TWA: 2 mg/m3 - 6834-92-0 Ethylene Glycol Mono Butyl Ether TWA: 20 ppm - 111-76-2 Appropriate engineering controls Engineering Controls Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local ventilation to keep airborne levels of vapor or mist to acceptable levels. Individual protection measures, such as personal protective equipment Eye/Face Protection Wear approved safety glasses or chemical splash goggles. Use a face shield when appropriate. Skin and Body Protection Wear chemical resistant protective gloves. Wear appropriate protective clothing to prevent skin exposure. Respiratory Protection NIOSH approved respirator for dust. General Hygiene Considerations Avoid contact with skin, eyes, and clothing. Do not breathe vapor or mist. Do not ingest. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Powder Appearance Off-white powder Odor Mild Color Off-white Odor Threshold Not determined Property Values Remarks • Method pH N/A Melting Point/Freezing Point N/A Boiling Point/Boiling Range N/A Flash Point N/A Evaporation Rate N/A (Water = 1) Flammability (Solid, Gas) N/A Upper Flammability Limits N/A Lower Flammability Limit N/A Vapor Pressure N/A Vapor Density N/A Specific Gravity N/A Water Solubility Complete Solubility in other solvents N/A Partition Coefficient N/A Auto-ignition Temperature N/A Decomposition Temperature N/A Kinematic Viscosity N/A Dynamic Viscosity N/A