ALLIGATOR-FG

Hazard statements (CLP)

H303, H314

Code

Statements

H303

May be harmful if swallowed

SECTION 2: Hazards identification

Appearance Clear liquid Physical State Liquid Odor Detergent odor Classification Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed

Signal word

Danger Hazard Statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.1 Classification of the substance or mixture

Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Danger Hazard Statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Sodium metasilicate 6834-92-0 5-15 Dipropylene glycol monomethyl ether 34590-94-8 5-10 Sodium Tripolyphosphate 7758-29-4 <5 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret. ** 4. FIRST-AID MEASURES First Aid Measures Eye Contact IF IN EYES: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If skin irritation persists, call a physician. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion IF SWALLOWED: call a poison control center or physician immediately. Rinse mouth. Do not induce vomiting. Most important symptoms and effects Symptoms Causes severe skin burns and eye damage. May cause pain, conjunctivitis of the eyes or burns. Ingestion may cause severe burns to mouth, throat or stomach. Inhalation may cause burns to upper respiratory tract and lung tissue depending on length of exposure. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Product is not flammable. Hazardous Combustion Products None known. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions Prevent from entering soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Confine and absorb into approved absorbent. Place material into approved containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Do not breathe vapors. Wash face, hands and any exposed skin thoroughly after handling. Product should only be handled by trained personnel. For institutional and industrial use only. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep away from children and untrained personnel. Store locked up. Incompatible Materials Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium metasilicate 2 mg/m3 - 6834-92-0 Dipropylene glycol monomethyl ether 100 ppm / 606 mg/m3 (skin) 100 ppm / 600 mg/m3 (skin) IDLH: 700 ppm 34590-94-8 TWA: 5 ppm TWA: 24 mg/m3 Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Safety glasses as a minimum for protection. Skin and Body Protection Wear suitable protective clothing. Wear waterproof gloves. Respiratory Protection Ensure adequate ventilation, especially in confined areas. In case of inadequate ventilation wear respiratory protection. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear liquid Odor Detergent odor Color Clear Odor Threshold Not determined Property Values Remarks • Method pH 12.5 Melting Point/Freezing Point Not determined Boiling Point/Boiling Range > 100 °C / >212 °F Flash Point