POLYMER FLOORING ADHESIVE

Kley

Revision date : 2022-05-20

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

General Information

Version

1.1

Revision date

2022-05-20

Product name

POLYMER FLOORING ADHESIVE

Product Synonyms

Not Available

1.2.1 Relevant identified uses

Flooring adhesive

Emergency telephone

+61 3 9338 9511

Icons in SDS

M004 M009 M059

Company Information

company name

Kley

GHS Information

Signal word

Not Applicable

Section 2

SECTION 2: Hazards identification

According to the WHS Regulations and the ADG Code. Classification of the substance or mixture

Signal word

Not Applicable Hazard statement(s) Not Applicable Precautionary statement(s) General P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read carefully and follow all instructions Precautionary statement(s) Prevention Not Applicable Precautionary statement(s) Response Not Applicable Precautionary statement(s) Storage Not Applicable

Disposal

Page 1 continued... Not Applicable

2.1 Classification of the substance or mixture

NON-HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. Poisons Schedule Not Applicable Classification [1] Not Applicable Label elements Hazard pictogram(s) Not Applicable Signal word Not Applicable Hazard statement(s) Not Applicable Precautionary statement(s) General P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read carefully and follow all instructions. Precautionary statement(s) Prevention Not Applicable Precautionary statement(s) Response Not Applicable Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal Page 1 continued... Not Applicable SECTION 3 Composition / information on ingredients Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name Not Available to 100 All substances - non-hazardous Legend: 1. Classification drawn from HCIS; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available SECTION 4 First aid measures Description of first aid measures If this product comes in contact with eyes: Wash out immediately with water. Eye Contact If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Advice for firefighters Use water delivered as a fine spray to control fire and cool adjacent area. Do not approach containers suspected to be hot. Fire Fighting Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. Non combustible. Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn. HAZCHEM Not Applicable SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Minor Spills Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Continued... Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Control personal contact with the substance, by using protective equipment. Major Spills Prevent spillage from entering drains, sewers or water courses. Recover product wherever possible. Put residues in labelled containers for disposal. If contamination of drains or waterways occurs, advise emergency services. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage Precautions for safe handling Product is moisture sensitive; handle under a dry, inert gas. Nitrogen with less than 5 ppm each of moisture and oxygen is recommended Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Safe handling Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Other information Consider storage under inert gas. Conditions for safe storage, including any incompatibilities Polyethylene or polypropylene container. Suitable container Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. Avoid contamination of water, foodstuffs, feed or seed. None known Storage incompatibility NOTE: May develop pressure in containers; open carefully. Vent periodically. Segregate from alcohol, water. SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA Not Available Emergency Limits Ingredient TEEL-1 TEEL-2 TEEL-3 POLYMER FLOORING Not Available ADHESIVE Ingredient Original IDLH Revised IDLH POLYMER FLOORING Not Available ADHESIVE Not Available Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically 'adds' and 'removes' air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. Appropriate engineering General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is controls essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of fresh circulating air required to effectively remove the contaminant. Type of Contaminant: Air Speed: 0.25-0.5 m/s solvent, vapours, degreasing etc., evaporating from tank (in still air) (50-100 f/min) Continued... aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray 0.5-1 m/s (100-200 drift, plating acid fumes, pickling (released at low velocity into zone of active generation) f/min.) direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active 1-2.5 m/s (200-500 generation into zone of rapid air motion) f/min) grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of 2.5-10 m/s very high rapid air motion). (500-2000 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood - local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Personal protection Safety glasses with side shields Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption Eye and face protection and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent] Skin protection See Hand protection below Wear general protective gloves, eg. light weight rubber gloves. The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final choice. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). · When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use. Hands/feet protection · Contaminated gloves should be replaced. As defined in ASTM F-739-96 in any application, gloves are rated as: · Excellent when breakthrough time > 480 min · Good when breakthrough time > 20 min · Fair when breakthrough time < 20 min · Poor when glove material degrades For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended. It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times. Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task. Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example: · Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of. · Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Body protection See Other protection below Continued... No special equipment needed when handling small quantities. OTHERWISE: Other protection Overalls. Barrier cream. Eyewash unit. SECTION 9 Physical and chemical properties Information on basic physical and chemical properties Moisture sensitive. Appearance Brown colour Physical state Liquid Relative density (Water = 1) 1.6-1.7 Partition coefficient n-octanol Odour Not Available / water Odour threshold Not Available Auto-ignition temperature (°C) Not Available pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point Not Available Viscosity (cSt) Not Available (°C) Initial boiling point and boiling Not Available Molecular weight (g/mol) Not Available range (°C) Flash point (°C) Not Available Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Surface Tension (dyn/cm or Upper Explosive Limit (%) Not Available mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available pH as a solution (Not Solubility in water Reacts Not Available Available%) Vapour density (Air = 1) Not Available VOC g/L Not Available SECTION 10 Stability and reactivity Reactivity See section 7 Chemical stability Product is considered stable and hazardous polymerisation will not occur. Possibility of hazardous See section 7 reactions Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition See section 5 products SECTION 11 Toxicological information Information on toxicological effects The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal Inhaled models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. The material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'. This is because of the lack of Ingestion corroborating animal or human evidence. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal Skin Contact models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort Eye characterised by tearing or conjunctival redness (as with windburn). Continued... Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal Chronic models); nevertheless exposure by all routes should be minimised as a matter of course. POLYMER FLOORING TOXICITY IRRITATION ADHESIVE Not Available Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin STOT - Repeated Exposure sensitisation Mutagenicity Aspiration Hazard Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification SECTION 12 Ecological information Toxicity POLYMER FLOORING Endpoint Test Duration (hr) Species Value Source ADHESIVE Not Available Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air No Data available for all ingredients Bioaccumulative potential Ingredient Bioaccumulation No Data available for all ingredients Mobility in soil Ingredient Mobility No Data available for all ingredients SECTION 13 Disposal considerations Waste treatment methods Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate: Reduction Reuse Recycling Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be Product / Packaging disposal appropriate. DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. SECTION 14 Transport information Labels Required Continued... Marine Pollutant NO HAZCHEM Not Applicable Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code Product name Group All substances - non-hazardous Not Available Transport in bulk in accordance with the ICG Code Product name Ship Type All substances - non-hazardous Not Available SECTION 15 Regulatory information Safety, health and environmental regulations / legislation specific for the substance or mixture National Inventory Status National Inventory Status Australia - AIIC / Australia Yes Non-Industrial Use Canada - DSL Yes China - IECSC Yes Europe - EINEC / ELINCS / NLP Yes Japan - ENCS Yes Korea - KECI Yes New Zealand - NZIoC Yes Philippines - PICCS Yes USA - TSCA Yes Taiwan - TCSI Yes Mexico - INSQ Yes Vietnam - NCI Yes Russia - FBEPH Yes Yes = All CAS declared ingredients are on the inventory Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration. SECTION 16 Other information Revision Date 20/05/2022 Initial Date 25/03/2022 Other information Classification of the preparation and its individual components has drawn on official and authoritative sources. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Definitions and abbreviations PC-TWA: Permissible Concentration-Time Weighted Average PC-STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit。 IDLH: Immediately Dangerous to Life or Health Concentrations ES: Exposure Standard OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index AIIC: Australian Inventory of Industrial Chemicals DSL: Domestic Substances List NDSL: Non-Domestic Substances List Continued... IECSC: Inventory of Existing Chemical Substance in China EINECS: European INventory of Existing Commercial chemical Substances ELINCS: European List of Notified Chemical Substances NLP: No-Longer Polymers ENCS: Existing and New Chemical Substances Inventory KECI: Korea Existing Chemicals Inventory NZIoC: New Zealand Inventory of Chemicals PICCS: Philippine Inventory of Chemicals and Chemical Substances TSCA: Toxic Substances Control Act TCSI: Taiwan Chemical Substance Inventory INSQ: Inventario Nacional de Sustancias Químicas NCI: National Chemical Inventory FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances end of SDS

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