80-101 Torque-Lok Endura-Tite

Hazard statements (CLP)

H225, H317, H319, H336

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

~ GHS02 Flame l~m. ~iq 2_ ~2_2~ ~ig_hly flan i~a~le _liq_uid ~n~ vap~r._ <!>GHS07 Eye lrrlt. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H336 May cause drowsiness or dizziness . ... ... ... .... ... ... ... ·-· .. -· .......... ··• ..... , --

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS)

Hazard pictograms

~<!> GHS02 GHS07

Signal word

Danger

Hazardous Ingredients

methyl ethyl ketone maleicacid

Hazard statements

H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness.

Precautionary statements

P21 O Keep away from heat/sparks/open flames/hot surfaces. No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P261 Avoid breathing dust/fume/gas/mist/vapors/spray P280 Wear protective gloves / eye protection / face protection. P240 Ground/bond container and receiving equipment. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P264 Wash face, hands and any exposed skin thoroughly after handling. P303+P361+P353 If on skin (or hair): Take off Immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 If In eyes: Rinse cautiously with water for several minutes. Remove contact lenses, If present and easy to do. Continue rinsing. • P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor If you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P405 Store locked up. (Contd. on page 2) (Contd. of page 2) Do not fiush with water or aqueous cleansing agents Dispose of the collected material according to regulations. -Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. -Handling: - Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. No special precautions are necessary if used correctly. - Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. - Conditions for safe storage, including any incompatibilities

Storage

-Requirements to be met by storerooms and receptacles: Store in a cool location. - Information about storage in one common storage facility: Not required. -Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. -Specific end use(s) No further relevant Information available. 11'1& ~i'.~' Cc.ri' ~ 1 · .·~,1 . ~0,l ffillli'~llliJd Additional information about design of technical systems No further data see item 7 - Control parameters - Components with limit values that require monitoring at the workplace: 78-93-3 methyl ethyl ketone --------- _________________ ,,, __ ! ! PEL Long-term value: 590 mgtm•, 200 ppm REL Short-term value: 885 mgtm•, 300 ppm Long-term value: 590 mgtm•, 200 ppm TLV Short-term value: 885 mgtm•, 300 ppm Long-term value: 590 mgtm•, 200 ppm BEi 1 • - Ingredients with biological limit values: I·-.. 78-93-3 methyl ethyl ketone BEi 2 mg/L Medium: urine Time: end of shift 1 Parameter: MEK

Additional information

The lists that were valid during the creation were used as basis - Exposure controls - Personal protective equipment: - General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. • Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. - Breathing equipment: Not required. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. 8 - Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation (Contd. on page 4) i I L .-......... -':'""-~-~----,.: - . ' ..... ~· ·----. •, - .• .. I - , (Contd. of page 4) - Chemical stability - Thermal decomposition I conditions to be avoided: No decomposition if used according to specifications. - Possibility of hazardous reactions No dangerous reactions known. - Conditions to avoid No further relevant information available. • Incompatible materials: No further relevant information available. -Hazardous decomposition products: Aldehyde Hydrocarbons • 11~Tut'iliit~i§I.' - Information on toxicological effects - Acute toxicity: ---------------·----------------------------- - LD!LC50 values that are relevant for classification: 78-93-3 methyl ethyl ketone Oral Loso 1 3300 mg/kg (rat) Dermal i LOSO! sooo mg/kg (rabbit) 110-16-7 malelc acid Oral (LD50I708 mg/kg (rat) ...... _ .. Dermal j LOSO! 1560 mg/kg (rabbit) - Primary irritant effect: - on the skin: No irritant effect. - on the eye: Irritating effect. - Sensitization: Sensitization possible through skin contact. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant , ....... , ______ ;;;_ ____ .....,....-,----=--------,---=----,--------------------~ - Carcinogenic categories 1 "/ARC (International Agency for Research on Cancer) None offhe ingredients is ffsieif ..... , ==c.==========~===~================================- . . .. .~.~ - NTP (National Toxicology Program) I _ .. i,.fri'ne· .. onileTiigredieiiis .. ls"ii'sied'-. ------------------------------------; ! -OSHA-Ca (Occupational Safety & Health Administration) ! None of the.ingredients is listed. -Toxicity - Aquatic toxicity: No further relevant Information available. - Persistence and degradability No further relevant information available. - Behavior in environmental systems: - Bioaccumulative potential No further relevant information available. - Mobility in soil No further relevant Information available. - Additional ecological information: - General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of It to reach ground water, water course or sewage system. - Results of PST and vPvB assessment - PST: Not applicable. - vPvB: Not applicable. - Other adverse effects No further relevant information available. l!il'. ii tliW~~ ·· 1i1~ - Waste treatment methods - Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. - Uncleaned packagings: . - Recommendation: Disposal must be made according to official regulations. (Contd. on page 6) (Contd. of page 6) - Chemicals known to cause reproductive toxicity for females: ,___N_o_n_e_o_f-th-e-in-g-re_d_i_e_n-ts-·iS"listed. - Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. f" - Chemicals known to cause developmental toxicity: None of the ingredients is listed. --------------------------, - Carcinogenic categories -EPA (Environmental Protection Agency) ' '11 -TLV (Threshold Limit Value established by ACGIH) ;-----,-,--=-.,---.,,----,---,-..,,...,--.,----------------------------------------··"'" ... j L None of the ing~e~ie~~! .. (S._ listed. -N/OSH-Ca (National Institute for Occupational Safety and Health) 1----,N"""o_ne_o..,f""th-e""'i,....ngredients is listed. j - Chemical safety assessment: A Chemical Safety Assessment has not been carried out. ... ~J This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. - Contact: Safety, Health and Environmental Affalres -Date of preparation I last revision 10/13/2015 / 16 -Abbreviations and acronyms: ADR: Accord europeen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS:.European List of Notlfled Chemical Substances GAS: Chemical Abstracts Service (dMsion of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials ldenUfication System (USA) voe: VolaUle Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent P8T: Persistent. Bioaccumulatlve and Toxic vPvB: very Persistent and very BioaccumulaUve Flam. Liq. 2: Flammable liquids, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin lrriL 2: Skin corrosion/irritation, Hazard Category 2 Eye lrrit 2A: Serious eye damage/eye Irritation, Hazard Category 2A Eye lrrit. 28: Serious eye damage/eye Irritation, Hazard Category 28 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity .. Single exposure, Hazard Category 3