PRIMER BLACK PRB 83661

Hazard statements (CLP)

H225, H317, H319, H332, H334, H336

Code

Statements

H225

Highly Flammable liquid and vapour

CLP CLASSIFICATION

GHS02 flame Flam. Liq. 2 H225 Highly flammable liquid and vapour. GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. GHS07 Acute Tox. 4 H332 Harmful if inhaled. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H336 May cause drowsiness or dizziness.

EU Classification

Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R20: Harmful by inhalation. Xn; Sensitising R42/43: May cause sensitisation by inhalation and skin contact. Xi; Irritant R36: Irritating to eyes. (Contd. of page 1) F; Highly flammable R11: Highly flammable. R66: Repeated exposure may cause skin dryness or cracking. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent. Has a narcotising effect.

Classification system

The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation.

Hazard pictograms

GHS02 GHS07 GHS08 GHS02 GHS07 GHS08

Signal word

Danger Danger

Hazardous Ingredients

butanone 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate diphenylmethane-4-4'-di-isocyanate butanone 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate diphenylmethane-4-4'-di-isocyanate

Hazard statements

H225 Highly flammable liquid and vapour. H332 Harmful if inhaled. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves / eye protection / face protection. P264 Wash thoroughly after handling. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. P284 [In case of inadequate ventilation] wear respiratory protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P272 Contaminated work clothing should not be allowed out of the workplace. (Contd. of page 2) P321 Specific treatment (see on this label). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Additional information

EUH066 Repeated exposure may cause skin dryness or cracking. Contains isocyanates. May produce an allergic reaction. · Labelling of packages where the contents do not exceed 125 ml

PBT Substances

Not applicable

vPvB Substances

Not applicable *