Acetone

Hazard statements (CLP)

H223, H229, H280, H302, H304, H315, H319, H335, H336

Code

Statements

H223

Flammable aerosol

SECTION 2: Hazards identification

GHS / HAZCOM 2012 Classification Health Physical Skin Irritation Category 2 Flammable Aerosol Category 2 Eye Irritation Category 2A Gas Under Pressure: Compressed Gas Specific Target Organ Toxicity – Single Exposure Category 3 (Respiratory Irritation, CNS) Aspiration Hazard Category 1

2.2 Label elements

Danger! Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container. Do not pierce or burn, even after use. Avoid breathing mist, vapors or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection and face protection. IF SWALLOWED: Immediately call a POISON CENTER. Do NOT induce vomiting. IF ON SKIN Wash with plenty of soap and water. If skin irritation occurs Get medical attention Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. 20 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER if you feel unwell. In case of fire: Use carbon dioxide, dry chemical or foam to extinguish. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with local and national regulations. Chemical Name CAS# % Severely Hydrotreated Petroleum Distillates 64742-52-5 30-50 Light Petroleum Distillates 64742-95-6 30-50 64742-88-7 64742-47-8 64742-96-7 Proprietary Ingredients Proprietary 1-10 Dipropylene Glycol Monopropyl Ether 29911-27-1 1-5 Diisobutyl Ketone 108-83-8 0-15 Dipropylene Glycol Methyl Ether 88917-22-0 0-5 Aliphatic Alcohol #1 123-42-2 <3 Aliphatic Alcohol #2 78-83-1 <3 Carbon Dioxide Propellant 124-38-9 1-15 The specific identity and/or exact percentage has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES Eye: Rinse thoroughly with water for several holding the eye lids open to be sure the material is washed out. Get medical attention if irritation develops or persists. Skin: Remove contaminated clothing. Wash contact area thoroughly with soap and water. Get medical attention if irritation or symptoms of exposure develop. Launder clothing before re-use. Inhalation: Remove victim to fresh air. Give artificial respiration if needed. If breathing is difficult, oxygen should be administered by qualified personnel. Get medical attention if symptoms develop. Ingestion: DO NOT induce vomiting. Keep the victim calm and warm. Never give anything by mouth to an unconscious or drowsy person. Get immediate medical attention. Most important symptoms and effects, acute and delayed: May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects such as headache, dizziness, nausea and vomiting. Harmful or fatal if swallowed. Aspiration into the lungs during ingestion or vomiting may cause lung damage. Indication of immediate medical attention and special treatment, if needed: If swallowed, get immediate medical attention.

2.1 Classification of the substance or mixture

Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Keep away from heat, sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container. Do not pierce or burn, even after use. Avoid breathing mist, vapors or spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection and face protection. IF SWALLOWED: Immediately call a POISON CENTER. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. 20 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER if you feel unwell. In case of fire: Use carbon dioxide, dry chemical or foam to extinguish. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with local and national regulations. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# % Severely Hydrotreated Petroleum Distillates 64742-52-5 30-50 Light Petroleum Distillates 64742-95-6 30-50 64742-88-7 64742-47-8 64742-96-7 Proprietary Ingredients Proprietary 1-10 Dipropylene Glycol Monopropyl Ether 29911-27-1 1-5 Diisobutyl Ketone 108-83-8 0-15 Dipropylene Glycol Methyl Ether 88917-22-0 0-5 Aliphatic Alcohol #1 123-42-2 <3 Aliphatic Alcohol #2 78-83-1 <3 Carbon Dioxide Propellant 124-38-9 1-15 The specific identity and/or exact percentage has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES Eye: Rinse thoroughly with water for several holding the eye lids open to be sure the material is washed out. Get medical attention if irritation develops or persists. Skin: Remove contaminated clothing. Wash contact area thoroughly with soap and water. Get medical attention if irritation or symptoms of exposure develop. Launder clothing before re-use. Inhalation: Remove victim to fresh air. Give artificial respiration if needed. If breathing is difficult, oxygen should be administered by qualified personnel. Get medical attention if symptoms develop. Ingestion: DO NOT induce vomiting. Keep the victim calm and warm. Never give anything by mouth to an unconscious or drowsy person. Get immediate medical attention. Most important symptoms and effects, acute and delayed: May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects such as headache, dizziness, nausea and vomiting. Harmful or fatal if swallowed. Aspiration into the lungs during ingestion or vomiting may cause lung damage. Indication of immediate medical attention and special treatment, if needed: If swallowed, get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use carbon dioxide, dry chemical or foam. Water may be ineffective but can be used to cool containers and structures. Specific Hazards Arising from the Chemical: Contents under pressure. Keep away from heat and open flames. Container may rupture or explode in the heat of a fire. Prolonged exposure to temperatures above 120ºF may cause cans to burst. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 21 Never use welding or cutting torch on or near containers (even empty) because product can ignite explosively. Combustion products may be hazardous: Oxides of carbon, organic compounds, smoke and fumes. Special Protective Equipment and Precautions for Fire-fighters: Wear NIOSH approved positive pressure, self-contained breathing apparatus and full protective clothing. Cool fire exposed containers with water. Protect against bursting cans. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, Protective equipment, and Emergency procedures: Wear appropriate protective clothing to prevent eye and skin contact including impervious gloves, safety goggles and respirator if needed. Environmental precautions: Avoid release to the environment. Report spills and releases as required to appropriate authorities. Methods and Materials for Containment and Cleaning up: Remove all ignition sources such as open flames, spark producing equipment, pilot lights, etc. Ventilate area. Cover with an inert absorbent material and collect into an appropriate container for disposal. SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling: Avoid breathing vapors, aerosols and mists. Use with adequate ventilation. Avoid contact with the eyes, skin and clothing. Wash exposed skin thoroughly with soap and water after use. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Do not cut, braze, solder, grind or weld on or near containers. Contents under pressure. Do not puncture or incinerate container. Conditions for Safe Storage, Including any Incompatibilities: Store in a cool, well ventilated area at temperatures below 120ºF. Do not store in direct sunlight. Store as a Level 3 aerosol. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name Exposure Limits Severely Hydrotreated Petroleum Distillates 5 mg/m3 TWA OSHA PEL 5 mg/m3 TWA ACGIH TLV(inhalable fraction) Light Petroleum Distillates 500 ppm TWA OSHA PEL (As stoddard solvent) 200 ppm TWA ACGIH TLV (as kerosene) Dipropylene Glycol Monopropyl Ether None Established Proprietary Ingredients None Established Diisobutyl Ketone 25 ppm TWA OSHA PEL 50 ppm TWA ACGIH TLV Dipropylene Glycol Methyl Ether None Established Aliphatic Alcohol #1 50 ppm OSHA TWA PEL- 50 ppm TWA ACGIH TLV Aliphatic Alcohol #2 100 ppm TWA OSHA PEL 50 ppm TWA ACGIH TLV Carbon Dioxide Propellant 5000 ppm OSHA PEL-TWA 5000 ppm ACGIH TLV-TWA 30000 ppm ACGIH TLV-STEL Appropriate Engineering Controls: Use with adequate general or local exhaust ventilation to maintain concentrations below the occupational exposure limits. Use explosion proof electrical equipment and wiring where required. Personal Protective Equipment: 22 Respiratory Protection: If the exposure limits listed above are exceeded, a NIOSH approved respirator with organic vapor cartridges may be used. For higher exposures, a supplied air respirator may be required. Respirator selection and use should be based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Hand protection: Impervious gloves are recommended when needed to avoid skin contact. Eye Protection: Chemical safety goggles recommended. Skin Protection: Impervious clothing as required to prevent skin contact and contamination of personal clothing. Hygiene measures: Suitable eye wash and washing facilities should be available in the work area. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Slightly reddish liquid Odor: Solvent packaged as an aerosol Odor Threshold: Not available pH: Not available Melting/Freezing Point: Not available Boiling Point/Range: Not available Flash Point: 132°F (55.5°C) TOC Evaporation Rate: Not available Flammability: (Solid, Gas) Not applicable Flammability Limits: 10.9% (aliphatic alcohol #2) LEL: 0.7% (light petroleum distillates) Vapor Pressure: Not available Vapor Density: Not available Relative Density: 0.8596 Solubilities: Negligible in Water Partition Coefficient: Not available Autoignition Not available (N-Octanol/Water) Temperature: Decomposition Not available Viscosity: Not available Temperature: SECTION 10: STABILITY AND REACTIVITY Reactivity: None known. Chemical Stability: Stable under normal conditions of storage or use. Possibility of Hazardous Reactions: None known. Conditions to avoid: Avoid heat, sparks, flames and all other sources of ignition. Incompatible Materials: Avoid strong oxidizing agents, reducing agents, acids and bases. Hazardous decomposition products: Combustion will produce oxides of carbon, acetone, acrid fumes and smoke. SECTION 11: TOXICOLOGICAL INFORMATION Potential Health Effects: Eye: May cause eye irritation with redness, tearing and stinging. Skin: May cause irritation with redness, rash, swelling. Prolonged or repeated contact may result in defatting and dermatitis. Inhalation: Inhalation of vapors or mists may cause mucous membrane and upper respiratory tract irritation and central nervous system depression. Symptoms may include coughing, wheezing, shortness of breath, headache, dizziness, drowsiness, nausea, fatigue and unconsciousness. Ingestion: Ingestion is an unlikely route of exposure for aerosol products. Swallowing may cause gastrointestinal irritation with abdominal pain, nausea, vomiting and diarrhea and central nervous system depression with symptoms 23 including headache, dizziness, intoxication, weakness, nausea, and vomiting. Aspiration into the lungs during ingestion or vomiting may cause lung damage. Chronic Hazards: Prolonged or repeated exposure may cause effects on the central nervous system, kidney and liver. Carcinogen Status: None of the components of this product at greater than 0.1% are listed as carcinogens by OSHA, IARC or NTP. Acute toxicity: Toxicological testing has not been performed on this product as a mixture. Severely Hydrotreated Petroleum Distillates: Oral rat LD50 > 5000 mg/kg; Dermal rat LD50 > 5000 mg/kg Inhalation rat LC50 > 2.18 mg/L/4 hr. Light Petroleum Distillates: Oral rat LD50 >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg Proprietary Ingredients: Oral rat LD50 2760 mg/kg; Dermal rabbit LD50 >2000 mg/kg Dipropylene Glycol Monopropyl Ether: Oral rat LD50 >2000 mg/kg Dermal rabbit LD50 >2000 mg/kg. Diisobutyl Ketone: Oral rat LD50 5233 mg/kg; Dermal rat LD50 > 2000 mg/kg; Inhalation rat LC50 14.5 mg/L/4 hr. Dipropylene Glycol Methyl Ether: Oral rat LD50 >5000 mg/kg, Dermal rat LD50 >2000 mg/kg, Inhalation rat LD50 >5.7 mg/L/4 hr Aliphatic Alcohol #1: Oral rat LD50 3002 mg/kg; Dermal rat LD50 > 1875 mg/kg; Inhalation rat LC50> 7.6 mg/L/4 hr. Aliphatic Alcohol #2: Oral rat LD50 > 2830 mg/kg; Inhalation rat LC50 24.6 mg/L/4 hr.; Dermal rabbit LD50 > 2000 mg/kg Carbon Dioxide: Inhalation rat LC50 167857 ppm/4 hr SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: No toxicity data available for the product. Severely Hydrotreated Petroleum Distillates: 96 hr. LC50 Pimephales promelas > 100 mg/L; 48 hr. EC50 daphnia magna>1000 mg/L; 72 hr. EC50 Pseudokirchnerella subcapitata > 100 mg/L Light Petroleum Distillates: 96 hr LL50 Oncorhynchus mykiss 2.5 mg/kg, 48 hr EL50 daphnia magna 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L Proprietary Ingredients: 96 hr. LC50 Oncorhynchus mykiss 18350 ug/L Dipropylene Glycol Monopropyl Ether: 96 hr LC50 Oncorhynchus mykiss >100 mg/L, 48 hr EC50 daphnia magna >100 mg/L, 96 hr EC50 Pseudokirchneriella subcapitata >1000 mg/L Diisobutyl Ketone: 96 hr. LC50 Oncorhynchus mykiss 30 mg/L; 48 hr. EC50 daphnia magna 37.2 mg/L, 72 hr. EC50 Pseudokirchnerella subcapitata 46.9 mg/L Dipropylene Glycol Methyl Ether: 96 hr LC50 Oncorhynchus mykiss 110.2 mg/L, 48 hr LC50 daphnia magna 2701 mg/L, 72 hr EC50 Pseudokirchneriella subcapitata >1000 mg/L Aliphatic Alcohol #1: 96 hr. LC50 Oryzias latipes >100 mg/L; 48 hr. EC50 daphnia magna >1000 mg/L; 72 hr. EC50 Pseudokirchnerella subcapitata>1000 mg/L 96 hr LC50 Pimephales promelas 1430 mg/L; 48 hr EC50 daphnia pulex 1100 mg/L; 72 hr EC50 Pseudokirchnerella subcapitata 1799 mg/L Carbon Dioxide: 96 hr LC50 Oncorhynchus mykiss 35 mg/L Persistence and Degradability: Aliphatic alcohol #1 and aliphatic alcohol #2 are readily biodegradable. . Light petroleum distillates is not readily biodegradable. Severely hydrotreated petroleum distillates is inherently biodegradable based on structurally similar chemicals. Bioaccumulative Potential: Aliphatic alcohol #1 has a calculated BCF of 0.5. Diisobutyl Ketone has a calculated BCF of 7. Aliphatic alcohol #2 has a calculated BCF of 3. Mobility in Soil: Aliphatic alcohol #1, aliphatic alcohol #2 and diisobutyl ketone have a high to very high mobility in soil. Other Adverse Effects: None known 24 SECTION 13: DISPOSAL INFORMATION Disposal instructions: Dispose of product in accordance with all local, state/provincial and federal regulations. Contaminated packaging: Offer empty packaging material to local recycling facilities. SECTION 14: TRANSPORT INFORMATION UN Proper shipping name Hazard Packing Group Environmental Number Class Hazard DOT Ground Consumer Commodity ORM-D or Limited Quantity DOT / 49 CFR UN1950 Aerosols, Flammable, Limited 2.1 None Quantity IMDG UN1950 Aerosols, Limited Quantity 2.1 None IATA UN1950 Aerosols, Flammable, Limited 2.1 None Quantity Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable – product is transported only in packaged form. Special precautions: None known. SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category for Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure