D082 4Fleas Household Spray 600ml

Hazard statements (CLP)

H400, H410

Code

Statements

H400

Very toxic to aquatic life

Further information

4] Substance is listed in Annex I of the Prior Informed Consent Regulation (PIC, Regulation (EU) 649/2012). [19] UVCB = Unknown or variable composition, complex reaction products or of biological materials 4.1. Description of first aid measures General information: In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet. Contact a doctor if in doubt about the injured person’s condition or if the symptoms persist. Never give an unconscious person water or other drink. Inhalation: Upon breathing difficulties or irritation of the respiratory tract: Bring the person into fresh air and stay with him/her. Skin contact: IF ON SKIN: Wash with plenty of water and soap. Remove contaminated clothing and shoes. Ensure to wash exposed skin thoroughly with water and soap. DO NOT use solvents or thinners. If skin irritation occurs: Get medical advice/attention. Eye contact If in eyes Flush eyes immediately with plenty of water or isotonic water (20-30 °C) for at least 5 minutes and continue until irritation stops. Remove contact lenses. Make sure to flush under upper and lower eyelids. If irritation continues, contact a doctor. Continue flushing during transport. Ingestion: If the person is conscious, rinse the mouth with water and stay with the person. Never give the person anything to drink. In case of malaise, seek medical advice immediately and bring the safety data sheet or label from the product. Do not induce vomiting, unless recommended by the doctor. Have the person lean forward with head down to avoid inhalation of or choking on vomited material. Burns: Rinse with water until pain stops then continue to rinse for 30 minutes. 4.2. Most important symptoms and effects, both acute and delayed Sensitisation: This product contains substances, which may trigger allergic reaction upon dermal contact. Manifestation of allergic reactions typically takes place within 12-72 hours after exposure. 4.3. Indication of any immediate medical attention and special treatment needed If eye irritation persists: Get medical advice/attention. Information to medics Bring this safety data sheet or the label from this product. 5.1. Extinguishing media Suitable extinguishing media: Alcohol-resistant foam, carbon dioxide, powder, water mist. Unsuitable extinguishing media: Waterjets should not be used, since they can spread the fire. 5.2. Special hazards arising from the substance or mixture Extremely flammable aerosol. Pressurised container. In a fire or if heated, a pressure increase will occur and the container may burst. In use may form flammable/explosive vapour-air mixture. Fire will result in dense smoke. Exposure to combustion products may harm your health. Closed containers, which are exposed to fire, should be cooled with water. Do not allow fire- extinguishing water to enter the sewage system and nearby surface waters. If the product is exposed to high temperatures, e.g. in the event of fire, dangerous decomposition compounds are produced. These are: Carbon oxides (CO / CO2) 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective clothing to prevent contact. Upon direct exposure contact The National Poisons Information Service (dial 111, 24 h service) in order to obtain further advice. Hazchem Code: None 6.1. Personal precautions, protective equipment and emergency procedures Accidental releases always pose a serious risk of fire or explosion. Storages not yet ignited must be cooled by water mist. Remove flammable materials if conditions allow it. Ensure sufficient ventilation. Ensure adequate ventilation, especially in confined areas. 6.2. Environmental precautions Avoid discharge to lakes, streams, sewers, etc. In the event of leakage to the surroundings, contact local environmental authorities. 6.3. Methods and material for containment and cleaning up Limit spillage and collect using granular absorbent or similar materials, and dispose of it in accordance with the regulations on dangerous waste. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Wherever possible cleaning should be performed with normal cleaning agents. Avoid use of solvents. 6.4. Reference to other sections See section 13 “Disposal considerations” on handling of waste. See section 8 "Exposure controls/personal protection" for protective measures. 7.1. Precautions for safe handling Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. The product should be tested for peroxides before distillation or evaporation and tested for peroxide formation or discarded after 1 year. Peroxide formation may be present anywhere in the container, including the sides, bottom, exterior and threaded cap. Peroxide formation in ppm concentrations may not be visually observable and must be identified through the use of appropriate testing procedures. If any of the following conditions exist, the material may be explosively unstable and will require stabilization prior to use: 1. Material appears to be degraded and or contaminated. 2. Material appears to be discolored. 3. Deterioration or distortion of storage container. 4. Thermal shock (sunlight). 5. Age of material exceeds recommended storage time. Avoid contact during pregnancy and while nursing. Smoking, drinking and consumption of food is not allowed in the work area. See section 8 "Exposure controls/personal protection" for information on personal protection. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed containers and store protected from moisture and light. Containers should be dated when opened and tested periodically for the presence of peroxides. Do not exceed storage time limits. Must be stored in a cool and well-ventilated area, away from possible sources of ignition. Pressurized gas packs (spray cans, aerosol cans) must be stored behind a wire mesh, which allows gases to escape and holds back packs flying around. Recommended storage material: Keep only in original packaging. Storage temperature: Dry, cool and well ventilated Incompatible materials: Strong acids, strong bases, strong oxidizing agents, and strong reducing agents. 7.3. Specific end use(s) This product should only be used for applications quoted in section 1.2. 8.1. Control parameters Petroleum gases, liquefied Long term exposure limit (8 hours) (ppm): 1000 Long term exposure limit (8 hours) (mg/m³): 1750 Short term exposure limit (15 minutes) (ppm): 1250 Short term exposure limit (15 minutes) (mg/m³): 2180 Annotations: Carc1 = Capable of causing cancer and/or heritable genetic damage if it contains more than 0.1% of buta-1,3-diene. propan-2-ol Long term exposure limit (8 hours) (ppm): 400 Long term exposure limit (8 hours) (mg/m³): 999 Short term exposure limit (15 minutes) (ppm): 500 Short term exposure limit (15 minutes) (mg/m³): 1250 Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Long term exposure limit (8 hours) (ppm): 220 The Control of Substances Hazardous to Health Regulations 2002. SI 2002/2677 The Stationery Office 2002. EH40/2005 Workplace exposure limits (Fourth Edition 2020). DNEL Petroleum gases, liquefied Duration: Oxidizing properties: Testing not relevant or not possible due to the nature of the product. Other physical and chemical parameters: No data available. 10.1. Reactivity No data available. 10.2. Chemical stability The product is stable under the conditions, noted in section 7 “Handling and storage”. 10.3. Possibility of hazardous reactions None known. 10.4. Conditions to avoid Do not expose to any forms of heat (e.g. solar radiation). May lead to excess pressure. Mechanical influences (e.g. Shock, pressure, impact, friction). Fire, sparks or other ignition sources. Sunlight 10.5. Incompatible materials Strong acids, strong bases, strong oxidizing agents, and strong reducing agents. 10.6. Hazardous decomposition products The product is not degraded when used as specified in section 1. 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 as retained and amended in UK law Acute toxicity Product/substance Petroleum gases, liquefied Species: Rat Route of exposure: Inhalation Test: LC50 (4 hours) Result: >20 mg/L Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 401 Species: Rat Test: LD50 Result: 5000 mg/kg Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 402 Species: Rabbit Route of exposure: Dermal Test: LC50 Result: 5000 mg/kg Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 403 Species: Rat Route of exposure: Inhalation Test: LC50 Result: 5000 mg/kg Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Causes serious eye irritation. Respiratory sensitisation Based on available data, the classification criteria are not met. Skin sensitisation This product contains substances that may trigger an allergic reaction in already sensitized persons. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. 11.2. Information on other hazards Long term effects Irritation effects: This product contains substances, which may cause irritation upon exposure to skin, eyes or lungs. Exposure may result in an increased absorption potential of other hazardous substances at the area of exposure. Endocrine disrupting properties This mixture/product does not contain any substances known to have hormone-disrupting properties in relation to health. Other information propan-2-ol has been classified by IARC as a group 3 carcinogen. permethrin (ISO);m-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate has been classified by IARC as a group 3 carcinogen. 12.1. Toxicity Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 203 Species: Fish, Oncorhynchus mykiss Duration: 96 hours Test: LC50 Result: 1000 mg/L Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 202 Species: Daphnia magna Duration: 48 hours Test: EC50 Result: 1000 mg/L Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Test method: OECD 201 Species: Algae, Scenedesmus subspicatus Duration: 72 hours Test: EC50 Result: 1000 mg/L Toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Product/substance Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Result: 69% Conclusion: - Test: OECD 301 F 12.3. Bioaccumulative potential Based on available data, the classification criteria are not met. 12.4. Mobility in soil No data available. 12.5. Results of PBT and vPvB assessment This mixture/product does not contain any substances known to fulfil the criteria for PBT and vPvB classification. 12.6. Endocrine disrupting properties This mixture/product does not contain any substances considered to have endocrine- disrupting properties in relation to the environment. 12.7. Other adverse effects This product contains substances that are toxic to the environment. May result in adverse effects to aquatic organisms. This product contains substances, which may cause adverse long-term effects to the aquatic environment. Waste treatment methods Product is covered by the regulations on hazardous waste. To the extent the material has not been subject to regular tests of peroxide formation the waste shall be treated as explosive waste. HP 3 - Flammable HP 14 – Ecotoxic Dispose of contents/container to an approved waste disposal plant. Regulation (EU) No 1357/2014 of 18 December 2014 on waste as retained and amended in UK law. EWC code Not applicable. Specific labelling Contaminated packing Packaging containing residues of the product must be disposed of similarly to the product. 14.1 14.2 14.3 14.4 14.5 Other UN / ID UN proper shipping name Hazard class(es) PG* Env** information: ADR UN1950 AEROSOLS Transport hazard class: 2 - Yes Limited Label: 2.1 quantities: 1 Classification code: 5F L Tunnel restriction code: (D) See below for

Principle Routes of Exposure

DNEL: Long term – Systemic effects - Workers Dermal 23.4 mg/kg bw/day Long term – Systemic effects - General population Inhalation 66.4 µg/m³ Long term – Systemic effects - Workers Inhalation 2.21 mg/m³ PNEC No data available. 8.2. Exposure controls Compliance with the given occupational exposure limits values should be controlled on a regular basis. General recommendations: Smoking, drinking and consumption of food is not allowed in the work area. Exposure scenarios: There are no exposure scenarios implemented for this product. Exposure limits: Professional users are subjected to the legally set maximum concentrations for occupational exposure. See occupational hygiene limit values above. Appropriate technical measures: Apply standard precautions during use of the product. Avoid inhalation of gas or dust. Hygiene measures: In between use of the product and at the end of the working day all exposed areas of the body must be washed thoroughly. Pay special attention to hands, forearms and face. Measures to avoid environmental exposure: Provide adequate general and local exhaust ventilation. Individual protection measures, such as personal protective equipment Generally: Use only UKCA marked protective equipment. Respiratory Equipment: No specific requirements Skin protection: No specific requirements. Hand protection: No specific requirements. Eye protection: Work situation Type Standards When there is Safety glasses with side shields. EN166 risk of splash- / intermittent exposure 9.1. Information on basic physical and chemical properties Physical state: Aerosol Colour: Testing not relevant or not possible due to the nature of the product. Odour / Odour threshold: Testing not relevant or not possible due to the nature of the product. pH: Testing not relevant or not possible due to the nature of the product. Density (g/cm³): Testing not relevant or not possible due to the nature of the product. Kinematic viscosity: Testing not relevant or not possible due to the nature of the product. Particle characteristics: Testing not relevant or not possible due to the nature of the product. Phase changes Melting point/Freezing point (°C): Testing not relevant or not possible due to the nature of the product. Softening point/range (°C): Does not apply to aerosols. Boiling point (°C): Testing not relevant or not possible due to the nature of the product. Vapour pressure: Testing not relevant or not possible due to the nature of the product. Relative vapour density: Testing not relevant or not possible due to the nature of the product. Decomposition temperature (°C): Testing not relevant or not possible due to the nature of the product. Data on fire and explosion hazards Flash point (°C): Does not apply to aerosols. Flammability (°C): The material is ignitable. Auto-ignition temperature (°C): Testing not relevant or not possible due to the nature of the product. Lower and upper explosion limit (% v/v): Testing not relevant or not possible due to the nature of the product. Solubility Solubility in water: Testing not relevant or not possible due to the nature of the product. n-octanol/water coefficient (LogKow): Testing not relevant or not possible due to the nature of the product. Solubility in fat (g/L): Testing not relevant or not possible due to the nature of the product.