Daron B1

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture according to GB 13690-2009 and GB 30000-2013 Classification of the substance or mixture according to GB 13690-2009 and GB 30000-2013 Emergency overview Liquid. Brown Characteristic. Fatal if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure if inhaled. Water reactive. Reacts with water to release toxic gas. May be fatal if inhaled. Get medical attention if you feel unwell. IF exposed or concerned Get medical attention. IF INHALED Call a POISON CENTER or physician if you feel unwell. If experiencing respiratory symptoms: Call a POISON CENTER or physician. If skin irritation or rash occurs Get medical attention. If eye irritation persists Get medical attention Not readily biodegradable. See Section 12 for environmental precautions.

2.1 Classification of the substance or mixture

ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A RESPIRATORY SENSITISATION - Category 1 SKIN SENSITISATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2

Signal word

Danger

Hazard statements

H332 - Harmful if inhaled. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H351 - Suspected of causing cancer. H335 - May cause respiratory irritation. H373 - May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Code

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves > 8 hours (breakthrough time) Butyl rubber (0.70 mm), nitrile rubber (0.4 mm), Chloroprene (0.5 mm). Wear eye or face protection. Wear protective clothing Not recommended polyvinyl chloride (PVC) , polyethylene (PE) P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapour or spray. P264 - Wash hands thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P314 - Get medical attention if you feel unwell. P308 + P313 - IF exposed or concerned: Get medical attention. P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or physician. P302 + P352 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. P333 + P313 - If skin irritation or rash occurs: Get medical attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention.

Storage

P405 - Store locked up. P233 - Keep container tightly closed. P403 - Store in a well-ventilated place.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other physicochemical hazards

No known significant effects or critical hazards.

Health hazards

Water reactive. Reacts with water to release toxic gas. May be fatal if inhaled. Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma Skin contact Adverse symptoms may include the following: irritation redness Ingestion No specific data. Under German legislation the following additional EU classification and labelling applies : Carcinogenic category 3. Physical/chemical hazards : Depending on ambient temperature : A slow or (far) more rapid exothermic reaction with water and / or water vapour forming solid polyureas and carbon dioxide. The formation of carbon dioxide can lead to a dangerous build-up of pressure in closed containers and systems and subsequent rupture of these containers and systems. The heat generated increases the production of isocyanate vapours.

Environmental hazards

No known significant effects or critical hazards.

Other hazards which do not result in classification

Water reactive. Reacts with water to release toxic gas. May be fatal if inhaled.