Note: Ingredients listed on restricted chemical lists
EC/CAS
26471-62-5
Name of the chemical
m-Tolylidendiisocyanat
Concentration
>98% 3-2214
EC/CAS
584-84-9
Name of the chemical
2,4-Diisocyanattoluol
Concentration
3-2214
EC/CAS
91-08-7
Name of the chemical
2,6-Diisocyanattoluol
Concentration
3-2214
General Information
Revision date
2010-12-17
Product name
TDI-80
Icons in SDS
Company Information
company name
Japan Urethane Raw Materials Association
GHS Information
Signal word
:
Hazard Codes
Hazard statements (CLP)
H221, H223, H228, H290, H315, H317, H319, H330, H334, H402
Hazard statements
Code
Statements
H221
Flammable gas
Section 2
SECTION 2: Hazards identification
GHS CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Physical hazards
Explosives Not applicable Flammable gases Not applicable Flammable gases Not applicable Flammable aerosols Not applicable Oxidizing gases Not applicable Gases under pressure Not applicable Flammable liquids Not classified Flammable solids Not applicable Self-reactive substances and mixtures Not applicable Pyrophoric liquids Not classified Pyrophoric solids Not applicable Self-heating substances and mixtures Not applicable Substances and mixture which, in contact with water, emit flammable gases Not classified Oxidizing liquids Not classified Oxidizing solids Not applicable Organic peroxides Not applicable Corrosive to metals : Not classified
Health hazards
Acute toxicity (oral) Not classified Acute toxicity (oral) Not classified Acute toxicity (skin) Not classified Acute toxicity (inhalation: gas) Not applicable Acute toxicity (inhalation: vapour) Category 1 Acute toxicity (inhalation: dust, mist) Not applicable Skin corrosion / irritation Category 2 Serious eye damages / eye irritation Category 2A Respiratory sensitization Category 1 Skin sensitization Category 1 Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity single exposure Category 3 (respiratory tract irritation) Specific target organ toxicity: repeated exposure : Not classified
Aspiration hazard
Not classified
Environmental hazards
Aquatic toxicity (acute) Category 3 Aquatic toxicity (chromic) Not classified
Signal word
: DANGER
Hazard statements
・ Fatal if inhaled. ・ Causes skin irritation. ・ Causes serious eye irritation. ・ May cause allergy or asthma symptoms or breathing difficulties if inhaled. ・ May cause allergic skin reaction. ・ Irritation to the respiratory system. ・ Harmful to aquatic life.
Prevention
・ Do not handle until all safety precautions have been read and understood. ・ Obtain special instructions before use. ・ Do not eat, drink or smoke when using this product. ・ Wear protective gloves/goggles/clothing and respiratory protection. ・ Use only outdoors or in well-ventilated area. ・ Do not breathe dust/fume/gas/mist/vapors/spray. ・ Wash hands thoroughly after handling. ・ Contaminated work clothing should not be allowed out of workplace. ・ Avoid release to the environment. ・ Avoid contact with water and alkali. ・ Do not use near fire.
Response
・ If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. ・ If swallowed: Rinse mouth with water. Do not induce vomiting. ・ If in eyes: Rinse with water for 15 minutes. Remove contact lenses, if present and easy to do. ・ If on skin: Wash with plenty of soap and water. ・ If on skin (or hair): Remove all contaminated clothing. ・ Wash contaminated clothing before re-using. ・ IF exposed or concerned, or if you feel unwell: Get medical advice/attention. ・ Dry chemical powder should be used for small fire. In case of larger fires, large volume of water spray should be used. ・ In case of spill, recover the spilled substance as possible. After neutralizing with NHB3 or alcohols absorb it with sand.
Storage
・ Store in a dry place. Keep container tightly closed in the locked place.
Disposal
・ Dispose of contents / container to waste in accordance with local / regional / national / international regulations (to be specified).
2.1 Classification of the substance or mixture
PHYSICAL HAZARDS ・ Explosives :Not applicable ・ Flammable gases :Not applicable ・ Flammable gases :Not applicable ・ Flammable aerosols :Not applicable ・ Oxidizing gases :Not applicable ・ Gases under pressure :Not applicable ・ Flammable liquids :Not classified ・ Flammable solids :Not applicable ・ Self-reactive substances and mixtures :Not applicable ・ Pyrophoric liquids :Not classified ・ Pyrophoric solids :Not applicable ・ Self-heating substances and mixtures :Not applicable ・ Substances and mixture which, in contact with water, emit flammable gases :Not classified ・ Oxidizing liquids :Not classified ・ Oxidizing solids :Not applicable ・ Organic peroxides :Not applicable ・ Corrosive to metals:Not classified HEALTH HAZARDS ・ Acute toxicity (oral) :Not classified ・ Acute toxicity (oral) :Not classified ・ Acute toxicity (skin) :Not classified ・ Acute toxicity (inhalation: gas) :Not applicable ・ Acute toxicity (inhalation: vapour) :Category 1 ・ Acute toxicity (inhalation: dust, mist) :Not applicable ・ Skin corrosion / irritation :Category 2 ・ Serious eye damages / eye irritation :Category 2A ・ Respiratory sensitization :Category 1 ・ Skin sensitization :Category 1 ・ Germ cell mutagenicity :Not classified ・ Carcinogenicity :Not classified ・ Reproductive toxicity :Not classified ・ Specific target organ toxicity single exposure :Category 3 (respiratory tract irritation) ・ Specific target organ toxicity: repeated exposure :Not classified ・ Aspiration hazard :Not classified ENVIRONMENTAL HAZARDS ・ Aquatic toxicity (acute) :Category 3 ・ Aquatic toxicity (chromic) :Not classified