147801 HALFORDS DE-ICER 400ML

Hazard statements (CLP)

H222

Code

Statements

H222

Extremely flammable aerosol

SECTION 2: Hazards identification

Classification (1999/45/EEC) Classification of the substance or mixture Classification (EC 1272/2008)

Other physicochemical hazards

Flam. Aerosol 1 - H222 Human health Not classified.

Environmental hazards

Not classified Classification (1999/45/EEC) F+;R12. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16

Signal word

Danger

Hazard statements

H222 Extremely flammable aerosol.

Precautionary statements

P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261 Avoid breathing vapour/spray. P271 Use only outdoors or in a well-ventilated area. P501 Dispose of contents/container in accordance with local regulations.

Supplemental label elements

P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P410+412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122° F.

2.1 Classification of the substance or mixture

Classification (EC 1272/2008) Physical and Chemical Hazards Flam. Aerosol 1 - H222 Human health Not classified. Environment Not classified. Classification (1999/45/EEC) F+;R12. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. 2.2. Label elements Label In Accordance With (EC) No. 1272/2008 Signal Word Danger Hazard Statements H222 Extremely flammable aerosol. Precautionary Statements P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261 Avoid breathing vapour/spray. P271 Use only outdoors or in a well-ventilated area. P501 Dispose of contents/container in accordance with local regulations. Supplementary Precautionary Statements P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P410+412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122° F. 2.3. Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures AMMONIA ...% CAS-No.: 1336-21-6 EC No.: 215-647-6 Classification (EC 1272/2008) Skin Corr. 1B - H314 STOT SE 3 - H335 Aquatic Acute 1 - H400 BUTANE CAS-No.: 106-97-8 EC No.: 203-448-7 Classification (EC 1272/2008) Flam. Gas 1 - H220 ETHANEDIOL CAS-No.: 107-21-1 EC No.: 203-473-3 Classification (EC 1272/2008) Acute Tox. 4 - H302 ETHANOL CAS-No.: 64-17-5 EC No.: 200-578-6 Classification (EC 1272/2008) Flam. Liq. 2 - H225 ISOBUTANE CAS-No.: 75-28-5 EC No.: 200-857-2 Classification (EC 1272/2008) Flam. Gas 1 - H220 METHANOL CAS-No.: 67-56-1 EC No.: 200-659-6 Classification (EC 1272/2008) Flam. Liq. 2 - H225 Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 STOT SE 1 - H370 < 1% Classification (67/548/EEC) C;R34 N;R50 1-5% Classification (67/548/EEC) F+;R12 5-10% Classification (67/548/EEC) Xn;R22 10-30% Classification (67/548/EEC) F;R11 < 1% Classification (67/548/EEC) F+;R12 < 1% Classification (67/548/EEC) F;R11 T;R23/24/25,R39/23/24/25 PROPAN-2-OL 10-30% CAS-No.: 67-63-0 EC No.: 200-661-7 Classification (EC 1272/2008) Classification (67/548/EEC) Flam. Liq. 2 - H225 F;R11 Eye Irrit. 2 - H319 Xi;R36 STOT SE 3 - H336 R67 PROPANE 1-5% CAS-No.: 74-98-6 EC No.: 200-827-9 Classification (EC 1272/2008) Classification (67/548/EEC) Flam. Gas 1 - H220 F+;R12 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion DO NOT INDUCE VOMITING! Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention if any discomfort continues. Skin contact Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. 5.3. Advice for firefighters Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Let evaporate. Keep out of confined spaces because of explosion risk. If leakage cannot be stopped, evacuate area. 6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. 7.2. Conditions for safe storage, including any incompatibilities Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C. 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes BUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 ETHANEDIOL WEL 10 mg/m3(Sk) 104 mg/m3(Sk) ETHANOL WEL 1000 ppm 1920 mg/m3 ISOBUTANE WEL 800 ppm METHANOL WEL 200 266 250 333 ppm(Sk) mg/m3(Sk) ppm(Sk) mg/m3(Sk) PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 PROPANE Asphyxiating Asphyxiating. Asphyxiating Asphyxiating. WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge. Hand protection Use protective gloves. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Aerosol. Colour Colourless. Odour Characteristic. Solubility Soluble in water. Flammability Limit - Lower(%) 0.8 Flammability Limit - Upper(%) 12.0 9.2. Other information SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Stable under normal temperature conditions. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids. 10.5. Incompatible materials 10.6. Hazardous decomposition products Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system. Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Gastrointestinal symptoms, including upset stomach. Skin contact Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Eye contact Irritating to eyes. May cause chemical eye burns. Route of entry Inhalation. Skin and/or eye contact. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Dangerous for the environment if discharged into watercourses. 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vPvB assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) 1950 14.2. UN proper shipping name Proper Shipping Name AEROSOLS 14.3. Transport hazard class(es) ADR/RID/ADN Class 2 ADR/RID/ADN Class Class 2: Gases