WCS 188 (winter)

Hazard statements (CLP)

H226, H302, H315, H317, H318, H336, H370

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS- Category 3 ACUTE TOXICITY (oral)- Category 4 SKIN IRRITATION- Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION- Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (optic nerve)- Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic Date of issue/Date of revision 101812018 People + Products - Performance~ Version : I effects)- Category 3 UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 Ill

Signal word

Danger

Hazard statements

H226 - Flammable liquid and vapor. H302 - Harmful if swallowed. H318- Causes serious eye damage. H315- Causes skin irritation. H317 - May cause an allergic skin reaction. H370- Causes damage to organs. (optic nerve) H336 - May cause drowsiness or dizziness.

Precautionary statements

General P1 03- Read label before use. P102- Keep out of reach of children. P1 01 - If medical advice is needed, have product container or label at hand.

Prevention

P280 -Wear protective gloves. Wear eye or face protection. P21 0 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240- Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, ventilating, lighting and all material- handling equipment. P242 - Use only non-sparking tools. P243 -Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - P270 - Do not eat, drink or smoke when using this product. P264- Wash hands thoroughly after handling. P272 (OSHA) - Contaminated work clothing must not be allowed out of the workplace.

Response

P307 + P311 -IF exposed: Call a POISON CENTER or physician. P304 + P340 + P312- IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 -IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353- IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P363 -IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. P333 + P313 -If skin irritation or rash occurs: Obtain medical attention. P305 + P351 + P338 + P310 -IF IN EYES: Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. P370 + P378 In Case of Fire: Use dry chemical, C02 , water spray (fog) or foam to extinguish.

Storage

P405 - Store locked up. P403 - Store in a well-ventilated place. P235 - Keep cool. Date of issue/Date of revision 10/8/2018 People + Products .- Performance~ Version

Disposal

P501 -Dispose of contents and container in accordance with all local, regional, national and international regulations.

2.3 Other hazards

None known.

Principle Routes of Exposure

Dermal contact. Eye contact. Inhalation. Ingestion. INGESTION: Although not a normal route of entry, ingestion is expected to be harmful. DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY. Target organs Contains material which may cause damage to the following organs: the nervous system, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. ~ection 3. Composition/information on ingredients Substance/mixture Mixture Other means of : Not available. identification CAS number/other identifiers CAS number Not applicable. Ingredient name % CAS number Methanol 30-60 67-56-1 Proprietary 1 - 5 Proprietary (2-hyd roxyethyl)am mon iu m mercaptoacetate 1 - 5 126-97-6 Proprietary 1 - 5 Proprietary 1 - 5 Proprietary Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. ~ection 4. First aid measures Description of necessa[y first aid measures Eye contact If irritation persists, obtain medical attention. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Inhalation If irritation persists, obtain medical attention. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition Date of issue/Date of revision 101812018 People + Products o¢o Performance~ Versio11 : I ~ection 4. First aid measures products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact If irritation persists, obtain medical attention. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion If irritation persists, obtain medical attention. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects. acute and delayed Target organs Methanol Category 1 Oral optic nerve Category 3 Not applicable. Narcotic effects Date of issue/Date ofrevisioll 101812018 People + Products ., Performance~ Versio11 ~ection 4. First aid measures Specific target organ toxicity (repeated exposure) Not available. ~piration hazard Not available. Indication of immediate medical attention and special treatment needed. if necessary Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments No specific treatment. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) I Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing Use dry chemical, C0 2 , water spray (fog) or foam. media Unsuitable extinguishing Do not use water jet. media Specific hazards arising Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur from the chemical and the container may burst, with the risk of a subsequent explosion. The vapor/ gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Additional Vapor Statement Not available. Hazardous thermal Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide nitrogen oxides sulfur oxides phosphorus oxides halogenated compounds Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident for fire-fighters if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Date of issue/Date of revision 1018/2018 People + Products ...., PerformanceN Versiou \section 6. Accidental release measures Personal precautions. protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. I Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Date of issue/Date of revision 10/812018 People + Products - Performance~ Version I Section 7. Handling and storage Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved including any area. Store in original container protected from direct sunlight in a dry, cool and incompatibilities well-ventilated area, away from incompatible materials (see Section 1 0) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. I section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name I Exposure limits Methanol ACGIH TLV (United States, 4/2014). Absorbed through skin. TWA: 200 ppm 8 hours. TWA: 262 mg/m3 8 hours. STEL: 250 ppm 15 minutes. STEL: 328 mg/m3 15 minutes. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hours. TWA: 260 mg/m3 8 hours. STEL: 250 ppm 15 minutes. STEL: 325 mg/m3 15 minutes. NIOSH REL (United States, 10/2013). Absorbed through skin. TWA: 200 ppm 10 hours. TWA: 260 mg/m3 10 hours. STEL: 250 ppm 15 minutes. STEL: 325 mg/m3 15 minutes. OSHA PEL (United States, 2/2013). TWA: 200 ppm 8 hours. TWA: 260 mg/m3 8 hours. Proprietary ACGIH TLV (United States, 4/2014). TWA 10 mg/m3 8 hours. Form Fume STEL 20 mg/m3 15 minutes. Form Fume NIOSH REL (United States, 10/2013). TWA 10 mg/m3 10 hours. Form Fume STEL 20 mg/m3 15 minutes. Form Fume OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m3 8 hours. STEL: 20 mg/m3 15 minutes. Appropriate engineering Use only with adequate ventilation. Use process enclosures, local exhaust controls ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Date of issue/Date ofrevisioll 101812018 People + Products - Performance~ Versio11 : 1 I Section 8. Exposure controls/personal protection Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Personal protective equipment (Pictograms) I Section 9. Physical and chemical properties Appearance Physical state Liquid. Color Clear. Light Straw Odor Mild. Odor threshold Not available. pH 6 to 8 Melting point <-40°C ( <-40°F) Boiling point Not available. Flash point Closed cup: 31 .111 oc (88°F) [Pensky-Martens.] Evaporation rate Not available. Date of issue/Date of revision 101812018 People + Products - Performance~ Version I Section 9. Physical and chemical properties Flammability (solid, gas) Not available. Lower and upper explosive Not available. (flammable) limits Vapor pressure Not available. Vapor density >1 [Air= 1] Relative density 0.92 to 0.99 Density 7.67 to 8.27 (lbs/gal) Solubility Easily soluble in the following materials: cold water and hot water. Target organs Methanol Category 1 Oral optic nerve Category 3 Not applicable. Narcotic effects Date of issue/Date of revision 1018/2018 People + Products - PerformanceN I Version : I ~ection 11. Toxicological information Sgecific target organ toxi~itll (rege~ted exgosure) Not available.

Potential Acute Health Effects

Eye contact Causes serious eye damage. Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Skin contact Causes skin irritation. May cause an allergic skin reaction. Ingestion Harmful if swallowed. Can cause central nervous system (CNS) depression. Over-exposure signs/symptoms Eye contact Adverse symptoms may include the following : pain watering redness Inhalation Adverse symptoms may include the following : nausea or vomiting headache d rowsi ness/fatigue dizziness/vertigo unconsciousness Skin contact Adverse symptoms may include the following : pain or irritation redness blistering may occur Ingestion Adverse symptoms may include the following : stomach pains blindness Specific target organ toxicity (single exposure\ Name Category Eye contact Causes serious eye damage. Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Skin contact Causes skin irritation. May cause an allergic skin reaction. Ingestion Harmful if swallowed. Can cause central nervous system (CNS) depression. Sl£mgtoms related to the ghnical. chemical and toxicological characteristics Eye contact Adverse symptoms may include the following: pain watering redness Inhalation Adverse symptoms may include the following : nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Skin contact Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion Adverse symptoms may include the following: stomach pains blindness Delal£ed and immediate effects and also chronic effects from short and long term exgosure Short term exgosure Potential immediate Not available. effects Potential delayed effects Not available. Long term exgosure Potential immediate Not available. effects Potential delayed effects Not available.

Teratogenic Effects

Product/ingredient name Result Species Dose Exposure Not available. S~ecific target organ tQxi~ity {singl~ ex~osyre) Name Category No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route ATE value Oral 775.5 mg/kg Dermal 2834.1 mg/kg Inhalation (vapors) 28.34 mg/1 ~ection 12. Ecological information Toxicity Product/ingredient name Result Species Exposure rvJethanol Acute EC50 16.912 mg/1 Marine water Algae - Ulva pertusa 96 hours Acute LC50 2500000 1-Jg/1 Marine water Crustaceans - Crangon crangon 48 hours - Adult Acute LC50 3289 mg/1 Fresh water Daphnia - Daphnia magna - 48 hours Neonate Acute LC50 100 mg/1 Fresh water Fish - Pimephales promelas - 96 hours Juvenile (Fledgling, Hatchling, Weanling) Chronic NOEC 9.96 mg/1 Marine water Algae - Ulva pertusa 96 hours Proprietary Acute EC50 0.07 mg/1 Marine water Algae - Hormosira banksii - 72 hours Gamete Acute LC50 20 1-Jg/1 Fresh water Crustaceans - Macrobrachium 48 hours rosenbergii - Post-larvae Acute LC50 390 1-Jg/1 Fresh water Daphnia - Daphnia magna - 48 hours Young Acute LC50 80 1-Jgll Fresh water Fish - Oncorhynchus mykiss 96 hours Chronic NOEC 0.6 mg/1 Marine water Algae - Entomoneis punctulata - 72 hours Exponential growth phase Chronic NOEC 330 1-Jg/1 Fresh water Crustaceans - Crangonyx sp. - 21 days Juvenile (Fledgling, Hatchling, Weanling) Chronic NOEC 19.66 mg/1 Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 0.006 mg/1 Fresh water Fish - lctalurus punctatus - Fry 30 days Conclusion/Summary Not available. Persistence and degradability Not available. Date of issue/Date of revision 101812018 People + Products - Performance• Version ~ection 12. Ecological information Product/ingredient name Not available. Product/ingredient name Not available. Bioaccumulative ootential Product/ingredient name Log Pow BCF Potential Methanol -0.77 <10 low Proprietary -3.2 low Mobility in soil Soil/water partition Not available. coefficient (Koc)

Aspiration hazard

Name Result Not available. Information on the likely Routes of entry anticipated: Oral, Dermal, Inhalation. ToxKinetics- routes of exposure

Potential chronic health

effects Not available. Date of issue/Date ojrevisio11 101812018 People Products ...,. Performance~ + Versio11 ~ection 11. Toxicological information General Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards.

Other hazards

No known significant effects or critical hazards. \Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. RCRA classification Not applicable. United States- RCRA Toxic hazardous waste "U" List Ingredient CAS# Status Reference number Methanol (I); Methyl alcohol (I) 67-56-1 Listed U154 !section 14. Transport information Regulatory UN/NA Proper shipping name PG* information Number Class(es) DOT Classification PG* : Packing group Date of issue/Date ofrevisioll 101812018 People + Products """' Performanceft Versio11 J Section 14. Transport information UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) RQ (methanol) 3 Ill

Additional information

Emergency Response Guide (ERG): 128 Reportable quantity 14170.3 lbs I 6433.3 kg [1779.6 gal I 6736.5 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Label TOG Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 18-2.19 (Class 3). Label IMDG Class UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 Ill Marine pollutant notes: Not available. Label IATA-DGR Class Date of issue/Date of revision 101812018 People + Products ..,.,. PerformanceN Version I Section 14. Transport information UN1993 FLAMMABLE LIQUID, N.O.S. (methanol) 3 Ill Label ~ection 15. Regulatory information U.S. Federal regulations :TSCA 4(a) proposed test rules: Quaternary ammonium compounds, (oxydi-2, 1-ethaned bis[coco alkyldimethyl, dichlorides TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. Clean Water Act (CWA) 311 : Proprietary Clean Air Act Section 112 Listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Not listed Class I Substances Clean Air Act Section 602 Not listed Class II Substances DEA List I Chemicals Not listed (Precursor Chemicals) DEA List II Chemicals Not listed (Essential Chemicals) SARA 302/304