Rustlick Kleenzol DY

Hazard statements (CLP)

H301, H302, H332

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

OSHA Hazards Emergency overview: May flash if vapors are ignited, but product will not burn.

HMIS® ratings

Health: 1 Flammability: 2 Reactivity: 0 Personal protection: B

Principle Routes of Exposure

Skin, eyes, respiratory tract, digestive system.

Potential Acute Health Effects

Skin: May cause mild irritation. Eyes: May cause mild irritation. Inhalation: May cause irritation to nose and throat. Inhalation of vapors or mist is harmful and may cause headache, dizziness, and drowsiness. Ingestion: Harmful if swallowed, may cause nausea and vomiting. Ingesting large quantities may cause injury or death. Potential long-term health effects: None identified Chemical Composition/Hazardous Ingredients Ingredients CAS # OSHA/PEL (TWA) ACGIH/TLV (TWA) Triethanolamine 102-71-6 5 mg/m3 Isopropanol 67-63-0 400 ppm 200 ppm Diethanolamine 111-42-2

Storage

Store away from extreme heat, flame, or ignition sources. Pressure build up may occur due to heat exposure or temperature change. Release pressure by slowly opening container. Exposure Controls and Personal Protection Hygiene measures: Avoid contact with eyes, skin and clothing. Do not eat, drink, or smoke while handling this product. Control measures: General ventilation should be sufficient. Providing approved respirators for emergencies, or when mist/vapor concentrations are unknown may be warranted. Availability of eye wash station, washing facilities and safety shower is recommended. Personal protection: Skin: Wear suitable glove. Chemical resistant gloves, such as polyvinyl chloride- coated, are recommended. Wear protective clothing suitable to prevent contact. Remove contaminated clothing and launder before wearing. Eyes: Safety glasses are recommended. Respiratory: Not normally required. Control vapor or mist concentrations below exposure limits through use of general or local exhaust ventilation. Physical and Chemical Properties Physical state: Liquid Color: Clear, pale yellow Odor: Mild pH: 9.9 Boiling point: 180°F (82°C) Melting/freezing point: Not available Vapor pressure: Not available Solubility in water: Soluble Specific gravity: 1.02 Vapor density: Greater than air (> 1) Evaporation rate < 1 Volatile organic compounds: Nil Reactivity and Stability Stability and reactivity Stable. Hazardous polymerization will not occur. Conditions to avoid Do not mix product with nitrites, under certain conditions amines may react with nitrites to form potentially carcinogenic nitrosamines. Materials to avoid Strong oxidizers. Hazardous decomposition products: Thermal decomposition or burning will produce carbon monoxide, carbon dioxide, and thick smoke.

TOXICOLOGICAL INFORMATION

LD50: Not determined for the product. LC50: Not determined for the product. Carcinogenic: None of the ingredients in this product are listed by IARC, ACGIH, NTP or

Teratogenic Effects

No information. Mutagenicity: No information.

Medical Conditions Generally Aggravated by Exposure

Skin disorders Dermatitis may be aggravated following exposure. Human Threshold Response Data Odor Threshold Not established for product. Irritation Threshold Not established for product. TRIADINE® 20 INDUSTRIAL MICROBIOSTAT Revision Date: 06/24/2010 Page 1 of 12 MATERIAL SAFETY DATA SHEET Hazardous Materials Identification System / National Fire Protection Association Classifications

ECOLOGICAL INFORMATION

Environmental toxicity: None reported. Aquatic toxicity: No data.

Disposal

Considerations Handling for disposal: Absorb on suitable material and follow procedures listed below. Methods of disposal: Dispose of in a manner that is recommended by local, state, provincial and federal laws and regulations. Transportation Information Not classified as hazardous for transport (DOT, TDG, CFR, IMO, ICAO). Regulatory Information

Further information

Prepared by: ITW ROCOL North America, Leroy Hitchcock, 800-452-5823 Date of Issue March 27, 2009 Date of previous issue: January 17, 2007 References: 1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices, 2004. 2. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2004. 3. US EPA Title III Lists of Lists - October 2001 version. 4. Material Safety Data Sheets from manufacturer. MATERIAL SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: TRIADINE® 20 INDUSTRIAL MICROBIOSTAT EPA Registration Number: 1258-1205 1. PRODUCT AND COMPANY IDENTIFICATION Revision Date: 06/24/2010 Arch Chemicals, Inc. SUPERCEDES: 04/21/2009 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 MSDS Number: 100000000118 SYNONYMS: None CHEMICAL FAMILY: Mixture DESCRIPTION / USE Industrial biocide FORMULA: None established

2.1 Classification of the substance or mixture

Routes of Entry: Inhalation, skin, eyes, ingestion Chemical Interactions: No known interactions

Hazard statements

Health Flammability Physical / Instability PPI / Special hazard. HMIS NFPA Immediate (Acute) Health Effects Inhalation Toxicity: Harmful if inhaled. Moderately toxic by inhalation. High concentrations are moderately irritating to the eyes, nose, throat, and lungs. Skin Toxicity: Skin contact may cause minor irritation consisting of transient redness and/or swelling. May be absorbed through skin, but it is unlikely that harmful effects will occur unless contact is prolonged, repeated, and extensive. Eye Toxicity: Severe irritation and/or burns can occur following exposure. Direct contact may cause impairment of vision and corneal damage. Rinsing of the eye should take place immediately. Ingestion Toxicity: Harmful if swallowed. Moderately toxic if swallowed. Ingestion may cause irritation of the gastrointestinal tract and gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting or diarrhea. Acute Target Organ Toxicity: Corrosive to the eyes and mildly irritating to the skin., Moderate respiratory irritant

Potential chronic health

Carcinogenicity: This product is not known or reported to be carcinogenic by any