Polyurethane 300 Aromatic Base Coat

Hazard statements (CLP)

H226, H304, H315, H317, H319, H332, H334, H335, H336, H340, H350, H361, H373, H401, H411

Code

Statements

H226

Flammable liquid and vapour

2.1 Classification of the substance or mixture

Health: Acute Toxicity (Inhalation), Category 4 Skin Irritation, Category 2 Eye Irritation, Category 2A Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Mutagenicity, Category 1B Carcinogenicity, Category 1B Reproductive Toxicity, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2 Aspiration Hazard, Category 1 Environmental: Acute Hazards to the Aquatic Environment, Category 2 Chronic Hazards to the Aquatic Environment, Category 2 Physical: Flammable Liquids, Category 3

2.2 Label elements

Flame Exclamation Health

Environmental hazards

mark

Signal word

DANGER

Hazard statements

H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H340: May cause genetic defects. H350: May cause cancer. H361: Suspected of damaging fertility or the unborn child. H373: May cause damage to organs through prolonged or repeated exposure. H401: Toxic to aquatic life. H411: Toxic to aquatic life with long lasting effects.

Prevention

201]: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof [electrical/ventilating/lighting] equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P284: [In case of inadequate ventilation] wear respiratory protection.

Response

P301+P310 IF SWALLOWED Immediately call a POISON CENTER/doctor P302+P352 IF ON SKIN Wash with plenty of water P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/ attention P312: Call a POISON CENTER/doctor if you feel unwell. P314: Get medical advice/attention if you feel unwell. P321: Specific treatment is required. P331: Do NOT induce vomiting. P332+P313 If skin irritation occurs Get medical advice/attention P333+P313 If skin irritation or rash occurs Get medical advice/attention P337+P313 If eye irritation persists Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P362: Take off contaminated clothing. P370+P378 In case of fire Use appropriate media to extinguish P391: Collect spillage.

Storage

P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/container according to local, regional, national, and international regulations. EMERGENCY OVERVIEW IMMEDIATE CONCERNS: WARNING! Combustible Liquid and Vapor. Contains Diphenylmethane Diisocyanate (CAS No. 101-68-8). May cause respiratory tract irritation. May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. May cause lung damage. Lung damage and respiratory sensitization may be permanent. May cause skin irritation. May cause allergic skin reaction. Skin sensitizer. Animal tests and other research indicate that skin contact with MDI can cause isocyanate desensitization and respiratory reaction.

Potential health effects

EYES: Contact may cause eye irritation. SKIN: May cause skin irritation upon contact. May cause allergic reaction in susceptible individuals. May stain the skin. SKIN ABSORPTION: A single prolonged exposure is not likely to result in material being absorbed through the skin in harmful quantities. INGESTION: Single dose oral toxicity is low. Can result in irritation and corrosive action in the mouth, stomach and digestive tract. However, it is not considered a common occupational route of exposure. INHALATION: MDI vapors or mist concentration at or above the TLV can irritate (burning sensation) the mucous membrane in the respiratory tract causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function. Persons with pre-existing non-specific bronchial hyper- reactivity can respond to concentrations well below the TLV with similar symptoms as well as asthma attacks. Exposure well above the TLV may lead to bronchitis, bronchial spasm, and pulmonary edema. These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g. fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure. As a result of previous repeated overexposure or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well below the TLV. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or other irritants. This increase lung sensitivity can persist for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (decrease in lung function), which may be permanent. Sensitization can be either temporary or permanent.

Principle Routes of Exposure

Eye and Skin Contact, Inhalation and Ingestion IRRITANCY: Eye and skin irritation. SENSITIZATION: May cause allergic respiratory and skin reaction. Respiratory and skin sensitizer.