PERMATHANE SM7108 Polyurethane Sealant

Hazard statements (CLP)

H227, H304, H317, H331, H334, H351, H360, H373, H400, H410

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

GHS CLASSIFICATIONS Health Acute Toxicity (Inhalation), Category 3 Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Reproductive Toxicity, Category 1B Target Organ Toxicity (Repeated exposure), Category 2 Aspiration Hazard, Category 1 Environmental Acute Hazards to the Aquatic Environment, Category 1 Chronic Hazards to the Aquatic Environment, Category 1 Physical Flammable Liquids, Category 4

2.2 Label elements

Skull and Exclamation Health

Environmental hazards

crossbones mark

Signal word

DANGER

Hazard statements

H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H331: Toxic if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351: Suspected of causing cancer. H360: May damage fertility or the unborn child. H373: May cause damage to organs through prolonged or repeated exposure. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.

Prevention

80975E8A P201 Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P284: [In case of inadequate ventilation] wear respiratory protection. P273: Avoid release to the environment.

Response

P301+P310 IF SWALLOWED Immediately call a POISON CENTER/doctor P302+P352 IF ON SKIN Wash with plenty of water P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P308+P313 IF exposed or concerned Get medical advice/ attention P311: Call a POISON CENTER or doctor P314: Get medical advice/attention if you feel unwell. P321: Specific treatment is required. P331: Do NOT induce vomiting. P333+P313 If skin irritation or rash occurs Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P362: Take off contaminated clothing. P370+P378 In case of fire Use appropriate media to extinguish P391: Collect spillage.

Storage

P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/container according to local, regional, national, and international regulations. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Liquid with a mild solvent odor IMMEDIATE CONCERNS: CAUTION! Combustible liquid and vapor. Causes eye and skin irritation. Contains small amount of Toluene Diisocyanate (CAS No. 26471-62-5). May cause respiratory tract irritation. May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. May cause lung damage. Lung damage and respiratory sensitization may be permanent. May cause skin irritation. May cause allergic skin reaction. Skin sensitizer. Animal tests and other research indicate that skin contact with TDI can cause isocyanate desensitization and respiratory reaction.

Potential health effects

EYES: Moderately irritating to the eyes. SKIN: May cause mild skin irritation. Repeated or prolonged skin contact may result in allergic dermatitis. INGESTION: Not likely route of entry. Harmful if swallowed, may cause nausea. Consult a physician. INHALATION: May cause mild irritation to the respiratory tract. May aggravate existing respiratory conditions.

Principle Routes of Exposure

Eye and Skin Contact, Inhalation and Ingestion IRRITANCY: Irritant to eyes, skin and respiratory tract. SENSITIZATION: May cause allergic respiratory and skin reaction. Respiratory and skin sensitizer.

2.1 Classification of the substance or mixture

Health: Acute Toxicity (Inhalation), Category 3 Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Reproductive Toxicity, Category 1B Target Organ Toxicity (Repeated exposure), Category 2 Aspiration Hazard, Category 1 Environmental: Acute Hazards to the Aquatic Environment, Category 1 Chronic Hazards to the Aquatic Environment, Category 1 Physical: Flammable Liquids, Category 4