Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2017-11-28
Product name
MIRACLE FOAMSEAL F2100A
Manufacturer Name
ITW Polymers Sealants North America
Icons in SDS
Company Information
company name
ITW Polymers Sealants North America
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H304, H315, H317, H319, H330, H334, H335, H351, H373
Hazard statements
Code
Statements
H304
May be fatal if swallowed and enters airways
Section 2
2.1 Classification of the substance or mixture
Health: Acute Toxicity (Inhalation), Category 2 Skin Irritation, Category 2 Eye Irritation, Category 2A Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2 Aspiration Hazard, Category 1
2.2 Label elements
Skull and Exclamation Health crossbones mark
Signal word
DANGER
Hazard statements
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H330: Fatal if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure.
Prevention
80975E8A P201 Obtain special instructions before use P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P285: In case of inadequate ventilation wear respiratory protection.
Response
P301+P310 IF SWALLOWED Immediately call a POISON CENTER/doctor P302+P352 IF ON SKIN Wash with plenty of water P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/ attention P310: Immediately call a POISON CENTER/doctor. P312: Call a POISON CENTER/doctor if you feel unwell. P314: Get medical advice/attention if you feel unwell. P320: Specific treatment is urgent. P331: Do NOT induce vomiting. P332+P313 If skin irritation occurs Get medical advice/attention P333+P313 If skin irritation or rash occurs Get medical advice/attention P337+P313 If eye irritation persists Get medical advice/attention P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor P362: Take off contaminated clothing.
Storage
P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.
Disposal
P501: Dispose of contents/container according to local, regional, national, and international regulations. EMERGENCY OVERVIEW IMMEDIATE CONCERNS: WARNING! Contains Diphenylmethane Diisocyanate (CAS No. 101-68-8). May cause respiratory tract irritation. May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. May cause lung damage. Lung damage and respiratory sensitization may be permanent. May cause skin irritation. May cause allergic skin reaction. Skin sensitizer. Animal tests and other research indicate that skin contact with MDI can cause isocyanate desensitization and respiratory reaction.
Potential health effects
EYES: May cause eye irritation. Permanent corneal injury is unlikely. SKIN: May cause skin irritation upon contact. May cause allergic reaction in susceptible individuals. May stain the skin. SKIN ABSORPTION: A single prolonged exposure is not likely to result in material being absorbed through the skin in harmful quantities. INGESTION: Single dose oral toxicity is low. Can result in irritation and corrosive action in the mouth, stomach and digestive tract. However, it is not considered a common occupational route of exposure. INHALATION: MDI vapors or mist concentration at or above the TLV can irritate (burning sensation) the mucous membrane in the respiratory tract causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function. Persons with pre-existing non-specific bronchial hyper- reactivity can respond to concentrations well below the TLV with similar symptoms as well as asthma attacks. Exposure well above the TLV may lead to bronchitis, bronchial spasm, and pulmonary edema. These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g. fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure. As a result of previous repeated overexposure or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well below the TLV. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or other irritants. This increase lung sensitivity can persist for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (decrease in lung function), which may be permanent. Sensitization can be either temporary or permanent.
Principle Routes of Exposure
Eye and skin contact and Inhalation. Ingestion is an unlikely route of entry IRRITANCY: Eye and skin irritation. SENSITIZATION: May cause allergic respiratory and skin reaction. Respiratory and skin sensitizer.