FOAMSEAL MIRACLE Big Bond

Hazard statements (CLP)

H229, H315, H317, H320, H332, H334, H335, H372

Code

Statements

H229

Pressurized container: may burst if heated

2.1 Classification of the substance or mixture

Health: Acute Toxicity (Inhalation), Category 4 Target Organ Toxicity (Single exposure), Category 3 Respiratory Sensitization, Category 1 Target Organ Toxicity (Repeated exposure), Category 1 Skin Irritation, Category 2 Skin Sensitization, Category 1 Eye Irritation, Category 2B Physical: Gases Under Pressure, Category 2

2.2 Label elements

Health Exclamation Gas mark cylinder

Signal word

DANGER

Hazard statements

H229 Pressurized container may burst if heated H332: Harmful if inhaled. H335: May cause respiratory irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H372: Causes damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

Prevention

P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P270: Do not eat, drink or smoke when using this product. P264: Wash face, hands, and any exposed skin thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required.

Response

P314: Get medical advice/attention if you feel unwell. P302+P350 IF ON SKIN Gently wash with plenty of soap and water P333+P313 If skin irritation or rash occurs Get medical advice/attention P363: Wash contaminated clothing before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2337LCK0 IF IN EYES Flush with tempered water for at least 20 minutes P304+P341 IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER/doctor

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents/container to an approved waste hauler 5207XY7K: Dispose of contents/container according to local, regional, national, and international regulations. EMERGENCY OVERVIEW IMMEDIATE CONCERNS: WARNING! Contents under pressure. Contains Diphenylmethane Diisocyanate (CAS No. 101-68-8). May cause respiratory tract irritation. May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. May cause lung damage. Lung damage and respiratory sensitization may be permanent. May cause skin irritation. May cause allergic skin reaction. Skin sensitizer. Animal tests and other research indicate that skin contact with MDI can cause isocyanate desensitization and respiratory reaction.

Potential health effects

EYES: May cause eye irritation. Permanent corneal injury is unlikely. SKIN: May cause skin irritation upon contact. May cause allergic reaction in susceptible individuals. May stain the skin. SKIN ABSORPTION: A single prolonged exposure is not likely to result in material being absorbed through the skin in harmful quantities. INGESTION: Single dose oral toxicity is low. Can result in irritation and corrosive action in the mouth, stomach and digestive tract. However, it is not considered a common occupational route of exposure. INHALATION: MDI vapors or mist concentration at or above the TLV can irritate (burning sensation) the mucous membrane in the respiratory tract causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function. Persons with pre-existing non-specific bronchial hyper- reactivity can respond to concentrations well below the TLV with similar symptoms as well as asthma attacks. Exposure well above the TLV may lead to bronchitis, bronchial spasm, and pulmonary edema. These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g. fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure. As a result of previous repeated overexposure or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well below the TLV. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or other irritants. This increase lung sensitivity can persist for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (decrease in lung function), which may be permanent. Sensitization can be either temporary or permanent.

Principle Routes of Exposure

Eye and skin contact and Inhalation. Ingestion is an unlikely route of entry IRRITANCY: Eye and skin irritation. SENSITIZATION: May cause allergic respiratory and skin reaction. Respiratory and skin sensitizer.