ULTRA COPPER GASKET MAKER 3 02

ITW Permatex

Revision date : 2016-04-22

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GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

96-29-7

Name of the chemical

2-Butanonoxim (2020/1182)

Concentration

N/A

General Information

Version

5

Revision date

2016-04-22

Product name

ULTRA COPPER GASKET MAKER 3 02

Product Synonyms

None

1.2.1 Relevant identified uses

Sealant

Emergency telephone

800-255-3924, 813-248-0585

Icons in SDS

GHS08

Company Information

company name

ITW Permatex

e-mail address of the competent person responsible for the Safety Data Sheet

mail@permatex.com

GHS Information

Signal word

Warning

Section 2

SECTION 2: Hazards identification

2.2 Label elements

Emergency Overview Warning \Causes serious eye irritation IMay cause an allergic skin reaction Suspected of causing cancer ppearance Copper Physical state Paste Odor Mild

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves/protective clothing/eye protection/face protection

Response

IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water if skin irritation or rash occurs: Get medical advice/attention Wash contaminated ciothing before reuse

Storage

Store locked up Conditions Keep container tightly closed in a dry and well-ventilated place. Protect from moisture. Incompatible materials Strong oxidizing agents, Water, Acids Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable

Further information

Not applicable Unknown acute toxicity 16.3812 % of the mixture consists of Ingredient(s) of unknown toxicity substance(s) Chemical Name CAS No Weight-% Trade Secret POLY (DIMETHYLSILOXANE), HYDROXY 70131-67-8 30 - 60 * TERMINATED 2-BUTANONE OXIME 96-29-7 1-5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. if eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN . Wash skin with soap and water. If skin irritation or rash occurs Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Cail a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fult protective gear. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Do not flush Into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. Slippery, can cause falls if walked on. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Softening point No information available Molecular weight No information available VOC Content (%) <3% Density No information available Bulk density No information available Reactivity No data available Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Water, Acids Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Formaldehyde May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Orai £.D50 Dermal £D50 Inhalation LC50 POLY (DIMETHYLSILOXANE), - > 16 mL/kg ( Rabbit} > 8750 mg/m? { Rat} 7h HYDROXY TERMINATED 70131-67-8 2-BUTANONE OXIME = 930 mg/kg (Rat) = 0.2 mg/kg (Rabbit) = 20 mg/L (Rat}4h 96-29-7 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. {ARC (international Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 33322 mg/kg ATEmix (dermal) 5426 mg/kg Ecotoxicity 98.9602 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea 2-BUTANONE OXIME 83: 72 h Desmadesmus subspicatus 777 - 914: 96 h Pimephales 750: 48 h Daphnia magna mg/L 96-29-7 mg/L EC50 promelas mg/L LC50 flow-through EC50 760: 96 h Poecilia reticulata mg/L LC50 static 320 - 1000: 96 h Leuciscus idus mg/L LC50 static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient 2-BUTANONE OXIME 0.65 96-29-7 Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated International Inventories TSCA Complies DSL/INDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. lEcSsc Complies KECL Not Listed, PICCS Complies Alcs Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINEGCS/ELINCS - European Inventory of Existing Chemical Substances/Eurapean List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances iECSC - China Inventory of Existing Chemical Substances ECL - Korean Existing and Evaluated Chemical Substances PICGS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No

Appearance/Odor

Copper Mild Odor threshold No information available Property Values

Remarks

+ Method pH 7-8 Melting point / freezing point No information available Boiling point / boiling range Not Applicable Polymerization Flash point > 93 °C / > 200 °F Tag Closed Cup Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure <5 mm Hg @ 80°F Vapor density 3.0 Air = 1 Relative density 1.05 Water solubility No information available Solubility in other soivents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available

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