SURFACE PREP 4.50Z AE

SECTION 2: Hazards identification

Signal word

Danger (Causes skin irritation May cause drowsiness or dizziness ‘May be fatal if swallowed and enters airways Extremely flammable aerosol Pressurized container: May burst if heated 24163 - SURFACE PREP 4.50Z AE Revision Date: 19-Dec-2017 Ppearance Green Physical state Liquid Odor Solveni

Prevention

Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Wear protective gloves

Response

IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting

Storage

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Store locked up Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store locked up. Incompatible materials Strong acids, Bases, Acids Control parameters Exposure Guidelines Chemical Name ACGIH TLV

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable

Further information

The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % wiw 1,3-butadiene (EINECS No. 203-450-8) Unknown acute toxicity 5 % of the mixture consists of ingredient(s) of unknown toxicity Substance(s) Chemical Name CAS No Weight-% Trade Secret HEPTANE 142-82-5 40-70 * PROPANE 74-98-6 10-30 * ISOBUTANE 75-28-5 10 - 30 * ETHANOL 64-17-5 1-5 * Description of first aid measures 24163 - SURFACE PREP 4.50Z AE Revision Date: 19-Dec-2017 General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED.. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. Contains gas under pressure; may explode if heated. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Personal precautions, protective equipment and emergency procedures Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Use personal protective equipment as required. Veniilate the area. Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up 24163 - SURFACE PREP 4.50Z AE Revision Date: 19-Dec-2017 Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so, Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use personai protective equipment as required. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Precautions for safe handling Advice on safe handling Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Softening point No information available Molecular weight No information available VOC Content (%) 97.6% Density No information available Bulk density No information available Reactivity Stable under normal conditions Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials 24163 - SURFACE PREP 4.50Z AE Revision Date: 19-Dec-2017 Strong acids, Bases, Acids Hazardous Decomposition Products Carbon oxides Phosphorus Copper compounds Information on likely routes of exposure inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 HEPTANE > = 3000 mg/kg (Rabbit) = 103 gim? (Rat)4h 142-82-5 PROPANE - . = 658 mg/L (Rat)4h 74-98-6 ISOBUTANE, - = 658 mg/L (Rat}4h 75-28-5 ETHANOL, = 7060 mg/kg ( Rat) - = 124.7 mg/L (Rat)4h 64-17-65 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP. OSHA ETHANOL A3 - Known x 64-17-5 ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Central nervous system, Respiratory system, Eyes, Skin, Blood, Liver, Reproductive System. The following values are caiculated based on chapter 3.1 of the GHS document . ATEmix (oral) 353000 mg/kg ATEmix (dermal) 4615 mg/kg ATEmix (inhalation-gas) 1124303 mg/l ATEmix (inhalation-dust/imist) 155 mg/l Ecotoxicity 24163 - SURFACE PREP 4.50Z AE Revision Date 19-Dec-2017 33 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient HEPTANE 4.66 142-82-6 PROPANE 2.3 74-98-6 ISOBUTANE 2.88 75-28-5 ETHANOL. -0.32 64-17-5 Other adverse effects No information available Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste, Chemical Name California Hazardous Waste Status HEPTANE Toxic 142-82-5 ignitable ETHANOL Toxic 64-17-5 ignitable DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide 126 Number IATA UNAD no ID 8000 Proper shipping name: Consumer commodity Hazard Class ERG Code OL. IMDG UN/ID no 1950 24163 - SURFACE PREP 4.50Z AE Revision Date 19-Dec-2017 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 21 EmS-No F-D, S-U International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies Alcs Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title Il! of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental + Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania HEPTANE x 142-82-5 24163 - SURFACE PREP 4.50Z AE Revision Date 19-Dec-2017 PROPANE x 74-98-6 ISOBUTANE x 75-28-65 ETHANOL x 64-17-5 ORGANO-COPPER COMPOUND x - xX 68084-48-0 ORGANO-COPPER COMPOUND x - x 22221-10-9 U.S. EPA Label information EPA Pesticide Registration Number Not applicabie WHMIS Hazard Class A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials NEPA Health hazards 2 Fiammability 3 Instability 0 - HMIS Health hazards 2 Fiammability 3 Physical hazards 0 Personal protection B NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 19-Dec-2017 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowiedge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

Appearance/Odor

Green Solvent Odor threshold No information available Property Values

Remarks

«Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point <0 °C / < 32 °F Gives a flame projection at full valve opening or flashback at any degree of valve opening Evaporation rate <1 Ether = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Air=4 Relative density 0.66 Water solubility Negligible Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available