DECAL & ADHESIVE REMOVER

ITW Permatex

Revision date : 2018-05-01

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GHS02 GHS08 GHS07 GHS04
Health risk rating 5
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

5989-27-5

Name of the chemical

(R)-p-mentha-1,8-diene

Concentration

N/A

EC/CAS

106-97-8

Name of the chemical

n-Butan, enthält  0,1% Butadien

Concentration

N/A

General Information

Version

4

Revision date

2018-05-01

Product name

DECAL & ADHESIVE REMOVER

Emergency telephone

800-255-3924, 813-248-0585

Icons in SDS

GHS02 GHS04 GHS07 GHS08

Company Information

company name

ITW Permatex

e-mail address of the competent person responsible for the Safety Data Sheet

mail@permatex.com

GHS Information

Signal word

Danger

Section 2

SECTION 2: Hazards identification

Signal word

Danger IMay cause an allergic skin reaction May be fatal if swallowed and enters airways Extremely flammable aerosol Contains gas under pressure; may explode if heated 80025 - DECAL & ADHESIVE REMOVER 5 OZ. HOOO Revision Date: 01-May-2018 pearance Clear Physical state Aerosol Odor Citrus}

Prevention

Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use

Response

Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting

Storage

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Store locked up Conditions Store locked up. Do not expose to temperatures exceeding 50 °C/122 °F. Incompatible materials Strong oxidizing agents Control parameters Exposure Guidelines . Chemical Name ACGIH TLV

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable

Further information

The classification as a carcinogen or mutagen need not apply since it can be shown that the substance contains less than 0.1 % wiw 1,3-butadiene (EINECS No, 203-450-8) Unknown acute toxicity 2 % of the mixture consists of ingredient(s) of unknown toxicity Substance(s) Chemical Name CAS No Weight-% DISTILLATES (PETROLEUM), 64742-47-8 80-90 HYDROTREATED LIGHT PROPANE 74-98-6 3-7 D-LIMONENE §989-27-5 3-7 BUTANE 106-97-8 3-7 Any concentration shown as a range is due to batch variation. Description of first aid measures General advice Get medical advice/attention if you feel unwell. 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date: 01-May-2018 Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. if eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED.:. Call a physician or poison contro! center immediately. Do NOT induce vomiting. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Contains gas under pressure; may explode if heated. Explosion data Sensitivity to Mechanical impact None, Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear, Personal precautions, protective equipment and emergency procedures Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area), Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash thoroughly after handling. Ventilate the area. Environmental precautions See Section 12 for additional Ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date: 01-May-2018 Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards — Clean contaminated objects and areas thoroughly observing environmental regulations. Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Softening point No information available Molecular weight No information available VOC Content (%) 19.75% Density No information available Bulk density No information available Reactivity Stable under normal conditions Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Temperatures >50 °C / 122 °F. incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. \Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 DISTILLATES (PETROLEUM), > 6000 mg/kg ( Rat } > 2000 mg/kg { Rabbit } >5.2mg/L (Rat)4h IHYDROTREATED LIGHT 64742-47-8 PROPANE - = 658 mg/L. (Rat }4h 74-98-6 D-LIMONENE = 4400 mg/kg (Rat } > Sgikg (Rabbit) 5989-27-5 IBUTANE - = 658 gim? (Rat) 4h 106-97-8 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ ceil mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP. OSHA ID-LIMONENE - Group 3 - 5989-27-5 IARC (international Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Central nervous system. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5764 mg/kg ATEmix (dermal) 2430 mg/kg ATEmix (inhalation-gas) 2623373 mg/l Ecotoxicity 14 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PROPANE 23 74-98-6 . BUTANE 2.89 106-97-8 Other adverse effects No information available Waste treatment methods 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Do01 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status D-LIMONENE Toxic § 989-27-5 DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 214 Emergency Response Guide 126 Number IATA UNIID no ID 8000 Proper shipping name: Consumer commodity Hazard Class ERG Code 9. IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U International Inventories TSCA Complies DSLINDSL Complies EINECS/ELINCS Complies ENCS Complies lECSC Complies KECL Complies Piccs Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSLINDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IEGSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Section 313 of Title Il! of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute heaith hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Requlations Chemical Name New Jersey Massachusetts Pennsylvania PROPANE x 74-98-6 BUTANE xX x 106-97-8 U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials NEPA Health hazards 2 Flammability 4 Instability 0 - HMIS Health hazards 2 Fiammability 4 Physical hazards 0 Personal protection B NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 01-May-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materiais or in any process, uniess specified in the text. End of Safety Data Sheet

Appearance/Odor

Clear Citrus Odor threshold No information available 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date: 01-May-2018 Property Values

Remarks

° Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point -104 °C / -165 °F Gives a flame projection at full valve opening or flashback at any degree of valve opening Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 6.6% Lower flammability limit: 0.9% Vapor pressure 30-44 psig @70°F/55-75 psig @ 130°F Vapor density No information available Relative density 0.769 Water solubility Insoluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available

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