765-2644 NAPA HEAVY-DUTY RUBBERIZED UNDERCOATING (PTX81833)

SECTION 2: Hazards identification

2.2 Label elements

Emergency Overview ‘Danger Causes skin irritation Suspected of damaging fertility or the unborn child Causes damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Extremely flammable aerosol 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date: 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ [Appearance Black Physical state Liquid Aerosol Odor Solven

Prevention

Obtain special instructions before use Do not handfe until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use

Response

IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse \F SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting

Storage

Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Conditions Store locked up. Do not expose to temperatures exceeding 50 °G/122 °F. Incompatible materials Strong oxidizing agents Control parameters Exposure Guidelines Chemical Name ACGIH TLV

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable

Further information

Harmful to aquatic life with long lasting effects ~ The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % wiw 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3 - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % wiw benzene (EINECS No 200-753-7). Unknown acute toxicity 37.5 % of the mixture consists of ingrecient(s) of unknown toxicity substance(s) Chemical Name CAS No Weight-% Trade Secret PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 10 - 30 * ASPHALT, OXIDIZED 64742-93-4 10 - 30 * TOLUENE 108-88-3 7-13 * 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date: 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ STODDARD SOLVENT 8052-41-3 5-10 * TALC 14807-96-6 3-7 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Description of first aid measures Generai advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Carbon dioxide (CO2)}, Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Explosion data Sensitivity to Mechanical impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Take precautionary measures against static discharges, Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate cans. 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date: 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Precautions for safe handling Advice on safe handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Contents under pressure. Do not puncture or incinerate cans. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Softening point No information available Molecular weight No information available VOC Content (%) 39.5% Density No information available Bulk density No information available Reactivity No data available Chemical stability Stable under recommended storage conditions. 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date: 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heal, flames and sparks. Take precautionary measures against static discharges. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Oxides of sulfur Hydrogen sulfide Information on likely routes of exposure Inhalation Harmful by inhalation. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemica! Name Oral LD50 Dermal LD50 inhalation LC50 ASPHALT, OXIDIZED > 5000 mg/kg ( Rat) > 2000 mg/kg ( Rabbit ) - 64742-93-4 [TOLUENE = 2600 mg/kg (Rat) = 42000 mg/kg (Rabbit } 212.5 mg/L (Rat)4h 108-88-3 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH iARG NFP OSHA ASPHALT, OXIDIZED - Group 2A - x 64742-93-4 TOLUENE - Group 3 - 108-88-3 [TALC - Group 3 ~ - 14807-96-6 IARC (international Agency for Research on Cancer) Group 2A ~ Probably Carcinogenic to Humans Nof classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 7970 mg/kg ATEmix (dermal) 5775 mg/kg ATEmix (inhaiation-dust/mist) 78.1 mg/l 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ Ecotoxicity 65 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Crustacea Chemical Name Algae/aquatic plants Fish ASPHALT, OXIDIZED - 56: 72 h Pseudokirchneriella - 64742-93-4 subcapitata mg/L EC50 TOLUENE 5.46 - 9,83: 48 h Daphnia magna 433: 96 h Pseudokirchneriella 15.22 - 19.06: 96 h Pimephales mg/L EC50 Static 11.5: 48h 108-88-3 subcapitata mg/L ECS0 12.5: 72 h | promelas mg/L LC50 flow-through Pseudokirchneriella subcapitata 42.6: 96 h Pimephales promelas Daphnia magna mg/L EC50 mg/L EC50 static mg/L LC50 static 5.89 - 7.84: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 14.1 - 17.16: 96 h Oncorhynchus mykiss mg/L LC50 static 5.8: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 11.0 - 45.0: 96 h Lepomis macrochirus mg/L LCS50 static 54: 96 h Oryzias latipes mg/L LCS0 static 28.2: 96 h Poecilia reticutata mg/L LC50 semistatic 50.87 - 70.34: 96 h Poecilia reticulata mg/L LC50 static - TALC - 400: 36 h Brachydanio rerio g/L 14807-96-6 LC50 semi-static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PETROLEUM GASES, LIQUEFIED, SWEETENED <=2.8 68476-86-8 2.65 TOLUENE 108-88-3 Other adverse effects No information available Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D001 | RCRA-D Series Wastes Chemical Name | RCRA-U Series Wastes RCRA RGRA - Basis for Listing - TOLUENE U220 Included in waste streams: 108-88-3 F005, F024, F025, F039, K015, K036, KO37, K149, K151 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED UNDERCOATING (PTX81833) Revision Date 17-Jun-2015 16 OZ Chemical Name RCRA - Halogenated RGRA -P Series Wastes | RCRA - F Series Wastes RGRA - K Series Wastes Organic Compounds TOLUENE - Toxic waste 108-88-3 waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from: the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and inctuding five, with varying amounts and positions of chlorine substitution, This product contains one or more substances that are listed with the State of California as a hazardous waste, Chemical Name California Hazardous Waste Status TOLUENE Toxic 108-88-3 tgnitable DOT UNAD no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 21 Emergency Response Guide 126 Number IATA UNAD no 1D 8000 Proper shipping name: Consumer commodity Hazard Ciass 9 ERG Code 9L IMDG UN/AD no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 24 EmS-No F-D, $-U International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. iECSC Complies KECL Complies Pi¢cs Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section &(b) Inventory DSLINDSL - Canadian Domestic Substances List/Non-Domestic Substances List 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ EINECS/ELINGS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENGS - Japan Existing and New Chemical Substances JECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PIGCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauth orization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % [TOLUENE - 108-88-3 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Heaith Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name GWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA Hazardous - Quantities Substances 1000 Ib 4 x TOLUENE Xx 108-88-3 CERCLA This material, as supplied, contains one or more substances regu! lated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) CERGLA/SARA RQ Chemical Name Reportable Quantity Hazardous Substances RQs (RQ) TOLUENE 1ib - RQ 1 tb final RQ 108-88-3 RQ 0.454 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations New Jersey Chemicai Name Massachusetts Pennsylvania ASPHALT, OXIDIZED x - 64742-93-4 TOLUENE x 408-88-3 STODDARD SOLVENT x Xx 8052-41-3 TALC x Xx 14807-96-6 U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA Health hazards 2 Flammability 4 Instability 0 - HMIS Personal protection Health hazards B 2 Flammability 4 Physical hazards 0 21207 - 765-2644 NAPA HEAVY-DUTY RUBBERIZED Revision Date 17-Jun-2015 UNDERCOATING (PTX81833) 16 OZ NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 17-Jun-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

Appearance/Odor

Black Solvent Odor threshold No information available Property Values

Remarks

* Method pH No information available Melting point / freezing point No information available Boiling point / boiling range > 38 °C / >100 °F Flash point No information available Gives a flame projection at full valve opening or flashback at any degree of vaive opening Evaporation rate <1 Butyl acetate = 4 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density >1 Air = 1 Relative density 1.02 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available