765-1216 NAPA SPRAY ADHESIVE (PTX82019) 110Z

SECTION 2: Hazards identification

2.2 Label elements

Emergency Overview Danger 110Z (Causes skin irritation \Causes Serious eye irritation Suspected of damaging fertility or the unborn child IMay cause drowsiness or dizziness IMay cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Extremely flammable aerosol lAppearance White Physical state Liquid Aerosol Odor Solven

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use

Response

IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing iF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction

Storage

Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F Conditions Store locked up. Keep away from sunlight, ignition sources and other sources of heat. Incompatible materials Strong oxidizing agents, Acids Control parameters Exposure Guidelines Chemical Name AGGIH TLV

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable

Further information

Toxic to aquatic life with long lasting effects - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % wiv 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3 Unknown acute toxicity 12 % of the mixture consists of ingredient(s} of unknown toxicity 110Z substance(s) Chemical Name CAS No Weight-% Trade Secret PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 30 - 60 * N-HEXANE 110-54-3 10 - 30 * ACETONE 67-64-1 10 - 30 * CYCLOHEXANE 110-82-7 1-5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/aitention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with soap and water. If symptoms persist, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, cail a physician. ingestion iF SWALLOWED.. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 110Z Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Remove all sources of ignition. Take precautionary measures against static discharges. Contents under pressure. Do not puncture or incinerate cans. Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse, Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not puncture or incinerate cans. Conditions for safe storage, including any incompatibilities Softening point No information available Molecular weight No information available VOC Content (%) 65% 110Z Density No information available Bulk density No information available Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normai processing, Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Acids Hazardous Decomposition Products Carbon oxides Information on likely routes of exposure Inhalation Harmful by inhalation. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. [Chemical Name Oral LDS50 Dermal LD50 inhalation LC50 IN-HEXANE = 25 gikg (Rat) = 3000 mg/kg (Rabbit } = 48000 ppm (Rat) 4h 110-54-3 ACETONE = 5800 mg/kg { Rat) - = 50100 mg/m? (Rat) 8h 67-64-14 ICYCLOHEXANE. > 5000 mg/kg (Rat ) > 2000 mg/kg (Rabbit ) = 13.9 mg/L (Rat)4h 110-82-7 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects fram short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Target Organ Effects Ceniral nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 18153 mg/kg ATEmix (dermal) 10777 mg/kg ATEmix (inhalation-dustimist) 440.9 mg/ ATEmix (inhalation-vapor) 211200 mg/l Ecotoxicity 110Z 57 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea N-HEXANE - 2.1 - 2.98: 96 h Pimephales 1000: 24 h Daphnia magna mg/L 110-54-3 promelas mg/L LC50 flow-through EC50 ACETONE - 4.74 - 6.33: 96 h Oncorhynchus 10294 - 17704: 48 h Daphnia 67-64-1 mykiss mL/L LC50 6210 - 8120: 96 | magna mg/L EC50 Static 12600 - h Pimephales promelas mg/L LC50{ 12700: 48 h Daphnia magna mg/L static 8300: 96 fh Lepomis EC50 macrochirus mg/L LC50 CYCLOHEXANE 500: 72 h Desmodesmus 3.96 - 5.18: 96 h Pimephales 400: 24 h Daphnia magna mg/L 410-82-7 subspicatus mg/L. EC50 promelas mg/L LG50 flow-through EC50 23.03 - 42.07: 96 h Pimephales promelas mg/L LC50 static 24.99 - 44.69: 96 h Lepomis macrochirus mg/L. LC50 static 48.87 ~ 68.76: 96 h Poecilia reticulata mg/L LC50 static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PETROLEUM GASES, LIQUEFIED, SWEETENED <=2.8 68476-86-8 ACETONE -0,24 67-64-1 CYCLOHEXANE 3.44 110-82-7 Other adverse effects No information available Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RGRA RCRA - Basis for Listing | RCRA -D Series Wastes | RCRA-U Series Wastes ACETONE - Included in waste stream: - Uoo2 67-64-14 FO39 GYCLOHEXANE - UG56 410-82-7 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status N-HEXANE Toxic 110-54-3 ignitable ACETONE ignitable 67-64-1 110Z CYCLOHEXANE Toxic 110-82-7 Ignitable DOT UN/ID no 4950 Proper shipping name: Aerosois, Limited Quantity (LQ) Hazard Class 2. Emergency Response Guide 126 Number IATA UNAD no ID 8000 Proper shipping name: Consumer commodity Hazard Class ERG Code OL iMDG UN/ID no 4950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 24 EmS-No F-D, S-U international Inventories TSCA Complies DSLINDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IEcSC Complies KECL Complies Piccs Complies Alcs Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENGS - Japan Existing and New Chemical Substances [ECSC - China inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title IH of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 ‘Chemical Name SARA 313 - Threshold Values % IN-HEXANE - 110-54-3 1.0 CYCLOHEXANE - 110-82-7 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No 110Z Reactive Hazard No CWA (Clean Water Act! This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable CWA - Toxic Pollutants | CWA - Priority Pollutants CWA - Hazardous Quantities Substances CYCLOHEXANE 41000 ib - . Xx 1410-82-7 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportabie Quantity (RQ) N-HEXANE 5000 Ib - RQ 5000 Ib final RQ 110-54-3 RQ 2270 kg final RQ ACETONE 5000 Ib - RQ 5000 Ib final RQ 67-64-1 RQ 2270 kg final RQ CYCLOHEXANE 4000 Ib - RQ 1000 Ib final RQ 410-82-7 RQ 454 kg final RQ US State Regulations California Proposition 65 This product does not coritain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsyivania ACETONE x xX 67-64-1 N-HEXANE x 110-54-3 CYCLOHEXANE x 110-82-7 U.S. EPA Label information EPA Pesticide Registration Number Not applicable NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 18-May-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

Appearance/Odor

White Solvent Odor threshold No information available Property Values

Remarks

«Method pH No information available Melting point / freezing point No information available Boiling point / boiling range > 38 °C | 100 °F Flash point < -18 °C / < 0 °F Gives a flame projection at full valve opening or flashback at any degree of vaive opening Evaporation rate > 4 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density >t Air=1 Relative density 0.73 Water solubility Negligible Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information availabie Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available