A 100

ITW Performance Polymers

Revision date : 2018-04-04

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

30-60%

General Information

Revision date

2018-04-04

Product name

A 100

supplier name

ITW Performance Polymers

Emergency telephone

+44(0)1235 239 670 (24h

Icons in SDS

GHS07 GHS08 M004 M009 M017 M057

Company Information

company name

ITW Performance Polymers

e-mail address of the competent person responsible for the Safety Data Sheet

mail@itwpp.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

Physical hazards

Not Classified

Health hazards

Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Resp. Sens. 1 - H334 Skin Sens. 1 - H317 Carc. 2 - H351 STOT SE 3 - H335 STOT RE 2 - H373

Environmental hazards

Not Classified Human health Protection against nuisance dust must be used when the airborne concentration exceeds 10 mg/m3. Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with isocyanates. Persons with impaired lung function should not handle this product..

Signal word

Danger A 100

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe vapour/ spray. P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/ doctor if you feel unwell. P314 Get medical advice/ attention if you feel unwell. P321 Specific treatment (see medical advice on this label). P332+P313 If skin irritation occurs: Get medical advice/ attention. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P337+P313 If eye irritation persists: Get medical advice/ attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/ container in accordance with national regulations.

Precautionary statements

P261 Avoid breathing vapour/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental label elements

EUH204 Contains isocyanates. May produce an allergic reaction. information P201 Obtain special instructions before use

Contains

DIPHENYLMETHANE-4,4'-DI-ISOCYANATE, Formaldehyde, Oligomeric Reaction products with phosgene and aniline

2.3 Other hazards

This product does not contain any substances classified as PBT or vPvB.

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