Stainless Steel Cleaner and Polish

ITVV Pro Brands

Revision date : 2016-01-27

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GHS02 GHS04 GHS08
Health risk rating 3
Safety risk rating 4
Environmental risk rating 1

General Information

Revision date

2016-01-27

Product name

Stainless Steel Cleaner and Polish

CAS No.

64742-47-8

1.2.1 Relevant identified uses

Cleaner & Polisher

Icons in SDS

Company Information

company name

ITVV Pro Brands

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H220, H223, H227, H229, H280, H304

Hazard statements

Code

Statements

H220

Extremely flammable gas

Section 2

2.1 Classification of the substance or mixture

4:1;11lo GHS 04 gas cylinder H280 Contains gas under pressure; may explode if heated. . GHS02 Flame Flam. Aerosol 2 H223-H229 Flammable aerosol. Pressurized container: May burst if heated. . ............ . . . . . . . . . . . . . . . . . . . . . . . . . . . . ......... 4 GHS08 Health hazard Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

GHS02 GHSO4 GHS08

Signal word

Danger

Hazardous Ingredients

Distillates (petroleum), hydrotreated light White Mineral Oil 64742-47-8 Distillates (petroleum), hydrotreated light 60-80% + Asp. lox. 1, H304 Ham. Lig. 4, H227 8042-47-5 White Mineral Oil 20-40% + Asp. Tox. 1, H304 75-28-5 Isobutane 5-10% Flam. Gas 1, H220 74-98-6 propane 1-5% Flam. Gas 1, H220 Press. Gas, H280 4 First-aid measures Description of first aid measures General information: Take affected persons out into the fresh air. After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of unconsciousness place patient stably in side position for transportation. - After skin contact: Immediately wash with water and soap and rinse thoroughly. In cases of frostbite, rinse with plenty of water. Do not remove clothing. If skin irritation continues, consult a doctor. After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:

Hazard statements

H280 Contains gas under pressure; may explode if heated. H223-H229 Flammable aerosol. Pressurized container: May burst if heated. H304 May be fatal if swallowed and enters airways. WHMIS-symbols: A - Compressed gas B5 - Flammable aerosol 4

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P301+P310 If swallowed: Immediately call a poison center/doctor. P331 Do NOT induce vomiting. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Additional information

Pressurized container May burst if heated Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Cool endangered receptacles with water fog. ccidelitalteleastmeasures tat, Sir 1 /2 Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Keep away from ignition sources. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Allow to evaporate. Absorb with non-combustible liquid-binding material (sand, diatomite, acid binders, universal binders). Remove from the water surface (e.g. skim or suck off). Ensure adequate ventilation. Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 117 Handlingand storage j Precautions for safe handling Keep away from heat and direct sunlight. Use only in well ventilated areas. Pressurized container: Do not pierce or burn, even after use. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Fumes can combine with air to form an explosive mixture. Flammable gas-air mixtures may be formed in empty receptacles. Do not spray on a naked flame or any incandescent material. - Conditions for safe storage, including any incompatibilities The lists that were valid during the creation were used as basis Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid close or long term contact with the skin. Avoid contact with the eyes. Breathing equipment: Not required under normal conditions of use. For spills, respiratory protection may be advisable. Use suitable respiratory protective device in case of insufficient ventilation. - Protection of hands: 0 The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Protective gloves Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation - Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: e Safety glasses Body protection: Protective work clothing - Limitation and supervision of exposure into the environment No further relevant information available. _ — 9 Physical and chemical properties Information on basic physical and chemical properties General Information - Appearance: Form: Aerosol Color: Colorless Odor: Lemon Odor threshold: Not determined. pH-value: Not determined. - Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Not applicable, as aerosol. Flash point: 82°C (180 °F) ((liquid component)) Flammability (solid, gaseous): Not applicable. Auto-ignition temperature: Not determined. Decomposition temperature: Not determined. - Auto igniting: Product is not self-igniting. - Danger of explosion: Not determined. Explosion limits: Lower: Not determined. Upper: Not determined. Vapor pressure at 21 °C (70 °F): 20- 35 psig Density at 20 °C (68 °F): 0.80 g/cm3 (6.676 lbs/gal) • Relative density Not determined. Vapour density >1 (Air=1) Evaporation rate Not applicable. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: . Dynamic: Not determined. Kinematic: Not determined. - Solvent content: VOC content: 12.56% •

Classification system

NFPA ratings (scale 0 - 4) Health = 0 \ Fire = 3 0 Reactivity = 0 HMIS-ratings (scale 0 -4) HEALTH a Health = 0 FIRE Fire = 3 REACTIVITY El Reactivity = 0

PBT Substances

Not applicable

vPvB Substances

Not applicable in re lent Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions.

Principle Routes of Exposure

Do not induce vomiting; immediately call for medical help. A person vomiting while lying on their back should be turned onto their side. Most important symptoms and effects, both acute and delayed Headache Breathing difficulty Dizziness Coughing Frostbite Nausea . Disorientation Danger Danger of impaired breathing. Indication of any immediate medical attention and special treatment needed Treat frost-bitten areas appropriately. If swallowed or in case of vomiting, danger of entering the lungs. S'Fire-fighting measures Extinguishing media Suitable extinguishing agents: Water fog / haze Foam Fire-extinguishing powder Carbon dioxide For safety reasons unsuitable extinguishing agents: Water stream. Special hazards arising from the substance or mixture Danger of receptacles bursting because of high vapor pressure if heated. Formation of toxic gases is possible during heating or in case of fire. Advice for firefighters - Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit.

Storage

Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers. Provide ventilation for receptacles. Avoid storage near extreme heat, ignition sources or open flame. Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. Specific end use(s) No further relevant information available. 1 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: 64742-47-8 Dis illates (petroleum), hydrotreated light EL (Canada) Long-term value: 200 mg/m3 Skin 74-98-6 propane PEL (USA) Long-term value: 1800 mg/m3, 1000 ppm REL (USA) Long-term value: 1800 mg/m3, 1000 ppm TLV (USA) refer to Appendix F EL (Canada) Long-term value: 1000 ppm EV (Canada) Long-term value: 1.000 ppm LMPE (Mexico) Long-term value: 1000 ppm

Further information

No further relevant information available. 10 Stabilityand reactivity - Reactivity Chemical stability Thermal decomposition! conditions to be avoided: No decomposition if used and stored according to specifications. Danger of receptacles bursting because of high vapor pressure if heated. Possibility of hazardous reactions Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomized • Reacts violently with oxidizing agents. Danger of receptacles bursting because of high vapor pressure if heated. Flammable aerosol. . - Conditions to avoid • Keep away from heat and direct sunlight. Excessive heat and contact with oxidizers. Keep ignition sources away- Do not smoke. Incompatible materials: No further relevant information available. Hazardous decomposition products: Carbon monoxide and carbon dioxide Hydrocarbons _ 11 Toxicological information Information on toxicological effects - Acute toxicity: - LD/LC50 values that are relevant for classification: ' 64742-47-8 Distillates (petroleum), hydrotreated light Oral LD50 > 5000 mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit) . Primary irritant effect: on the skin: No irritant effect. - on the eye: No irritating effect. - Sensitization: No sensitizing effects known. Other information (about experimental toxicology): Vapors have narcotic effect. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: - Carcinogenic categories NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. Repeated Dose Toxicity: May cause damage to organs through prolonged or repeated exposure. 1 12 Ecological information - Toxicity - Aquatic toxicity: No further relevant information available. - Persistence and degradability No further relevant information available. - Bioaccumulative potential No further relevant information available. - Mobility in soil No further relevant information available. - Ecotoxical effects: Remark: Due to mechanical actions of the product (e.g. agglutinations) damages may occur. The product is oxygen-consuming. The declared action may be partly caused by lack of oxygen. - Additional ecological information: - General notes: Due to the consistence and the low watersolubility of the product a bioavailability is not probable. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Other adverse effects No further relevant information available. ri 3 Disposal considerations Waste treatment methods - Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Contact waste processors for recycling information. Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. - Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations. ranspo_ nformation _ „ tr, E. UN-Number <kr>1 DOT - DOT, ADR, IMDG, IATA Aerosols, flammable UN1950 - UN proper shipping name Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3 gal). ADR 1950 AEROSOLS, flammable IMDG AEROSOLS IATA AEROSOLS, flammable - Transport hazard class(es) DOT - Class 2.1 Label 2.1 ADR • - Class 2 5F Gases Label 2.1 IMDG • Class 2 Gases Label 2.1 IATA • Class 2.1 Label 2.1 Packing group - DOT, ADR, IMDG, IATA Not Regulated - Environmental hazards: - Marine pollutant: No Special precautions for user Warning: Gases - Danger code (Kemler): EMS Number: F-D,S-U Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: 75kg On cargo aircraft only: 150kg ADR Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity IMDG Limited quantities (LQ) 1000mL Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity UN "Model Regulation": UN1950, Aerosols, 2.1 — 711 4.' edtt phi Inform l0 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA - Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients are listed. - TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 (California) Chemicals known to cause cancer: None of the ingredients are listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. - Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. IARC (International Agency for Research on Cancer) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. - NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. State Right to Know Listings Some ingredients listed. Canadian substance listings: Canadian Domestic Substances List (DSL) All ingredients are listed. Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. Canadian Ingredient Disclosure list (limit 1%) None of the ingredients is listed. Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.

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