C1.07 DAY

Hazard statements (CLP)

H302

Code

Statements

H302

Harmful if swallowed

2.2 Label elements

310 of chemicals 50 and of the company/undertaking 12.1. Wear 2-BUTOXYETHANOL Upper Information Not - IATA VLA Toxicity applicable suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent DGR: explosive on International likely limit routes ESP Air of Transport exposure 308 Association 50 Dangerous Not available Goods Regulation SKIN 1.1. CAS Vapour - IC50: any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Product VLEP Immobilization pressure identifier 111-76-2 FRA Concentration 1 ≤ x 308 < 50% 1,5 50 Acute Not available Tox. 4 H302, Acute Tox. 4 H312, SKIN Acute Tox. 4 H332, Eye Irrit. 2 H319, 14.5. Vapour Information - IMDG: procedures. Environmental WEL density International not available References: protection (EU) pursuant 2019/521 devices to EC (XII must Regulation Atp. be CLP) used

SECTION 2: Hazards identification

GBR Maritime Code 308 for dangerous 50 goods Skin Not Irrit. available 2 H315 SKIN Code: EC Relative - IMO: VLEP International density 203-905-0 Maritime ITA Organization 308 50 C1.07 101 DAY g/cm3 SKIN 2-BUTOXYETHANOL Product INDEX Solubility Delayed Not - INDEX OEL applicable name and NUMBER: immediate 603-014-00-0 Identifier EU effects in as Annex 308 well VI as of chronic CLP 50 effects C1.07 soluble from DAY in short water and long-term exposure SKIN 6.2. LC50 Environmental - for Fish

Precautionary statements

100 mg/l/96h Reg. Partition - LC50: EC50 - for Crustacea TLV-ACGIH no. Lethal coefficient: Concentration 01-2119475108-36-XXXX n-octanol/water 50% 606 100 Not available > 100 mg/l/48h 909 150 SKIN 1.2. 14.6. ALCOL Auto-ignition Information - LD50: The EC50 product Relevant Special - for Algae Lethal GRASSO identified not temperature must / Aquatic dose available not penetrate ALCOSSILATO 50% uses for of user the substance or mixture Plants into the sewer system > or 100 come Not available and uses advised against mg/l/72h into contact with surface water or ground water. CAS Decomposition - OEL: Occupational temperature Exposure 1 Level ≤ x < 1,5 Eye Not Irrit. available 2 H319, Skin Irrit. 2 H315 Intended EC Viscosity Interactive Not LD50 (Dermal) telephone for safe handling number > 1000 mg/kg Rabbit EYES: There Restrictions are Remove no relating particular contact to the risks lenses, product of reaction if or present. contained with other Wash substances immediately pursuant in normal with to plenty conditions Annex of XVII water of to use. for EC at Regulation least 15 minutes,

PBT Substances

applicable Persistent use effects bioaccumulative and toxic as REACH Neutral Not Regulation available detergent 2-BUTOXYETHANOL ready to use 6.3. 12.2. Methods Persistence and material and degradability for containment and cleaning up INDEX Threshold Explosive - PEC: Predicted properties Limit environmental Value Concentration Not available 1.3. 14.7. DIPROPYLENE Oxidising Information - PEL: Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the Details Transport Type Predicted of properties not the in available supplier bulk GLYCOL exposure Country according of MONOMETHYL level the safety to TWA/8h Annex data II ETHER sheet of Marpol Not and available STEL/15min the IBC Code

Remarks

/ Observations CAS - PNEC: Predicted 34590-94-8 remainder 2-BUTOXYETHANOL with inert absorbent material. no effect concentration 1 ≤ mg/m3 x < 1,5 ppm Eye Irrit. 2 mg/m3 H319 ppm 9.2. Name EC ACUTE Information - REACH: Make Solubility Other VLA information sure in the TOXICITY EC not Regulation water leakage site is well aired. Contaminated 1000 relevant 252-104-2

vPvB Substances

2-BUTOXYETHANOL Description Reactivity Bioaccumulative Very for Category 7. Persistent of first the Handling - Directive Safety and Data potential aid measures very and 2012/18/EC: Sheet Bioaccumulative

Storage

as office@italianxs.com for REACH Regulation None 8.2. - WGK: Exposure LD50 Water controls (Oral)

Hazard categories

German) > 300 mg/kg Ratto 1.4. 7.1. Emergency limites including 1989 d'exposition Edition those professionnelle generated by ventilation aux agents equipment, chimiques should en France.

Disposal

10th Deutschland Edition is odourless considerations criteria for or this TRGS its olfactory 900 class - threshold Seite 1 von is 69 higher (Fassung than the 29.03.2019)- corresponding Liste TLV-TWA der Arbeitsplatzgrenzwerte and in the case of und 15.2. Chemical safety assessment SECTION GBR compliance - IFA GESTIS with Special must be checked ED 984 to - INRS 16. website be performed environmental ensure Other arising from United information Kingdom through standards. the substance an authorised or mixture waste management firm, in compliance with national and local regulations. Workplace 10.5. Incompatible materials Safety CONTAMINATED PACKAGING EUH210 data sheet EH40/2005 available on request. exposure limits (Third edition,published 2018) ITA STOT - ECHA - SINGLE website EXPOSURE Italia DIRETTIVA (UE) 2017/164 DELLA COMMISSIONE del 31 gennaio 2017 Contaminated Text of hazard CAUSED - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy packaging (H) indications BY EXPOSURE must mentioned be recovered IN THE in section or EVENT disposed 2-3 OF of of the FIRE in sheet: compliance with national waste management regulations. Precautionary EU Information not available

Hazard pictograms

an -- The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. emergency, - Handling Chemical wear open-circuit Safety compressed air Kurzzeitwerte breathing apparatus (in compliance with standard EN 137) or external air-intake breathing DIPROPYLENE GLYCOL MONOMETHYL ETHER 13.1. UNSUITABLE ESP apparatus REPRODUCTIVE Waste treatment - Fiche (in compliance EXTINGUISHING Toxicologique TOXICITY methods EQUIPMENT España with (toxicological standard EN sheet) 138). For DE a correct choice of PROFESIONAL respiratory protection AGENTES device, see standard EN Signal - INRS words: A chemical Avoid exposure safety assessment to: sources of has heat.Possibility -- not been LÍMITES performed of explosion. for EXPOSICIÓN the preparation/for the substances PARA indicated in QUÍMICOS section 3. EN 529. ESPAÑA 2019 None in particular. ENVIRONMENTAL - Patty - Industrial Hygiene EXPOSURE and Toxicology CONTROLS (INSST) 2-BUTOXYETHANOL Reuse, when possible. Neat product residues should be considered special non-hazardous waste. FRA Does - N.I. emissions Avoid exposure to: sources of heat,naked flames. Sax not statements: meet - Dangerous generated France properties by manufacturing criteria of Industrial for this Valeurs processes, Materials-7,

Hazard statements

OEL EU -- Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Do not breathe combustion products. Does not meet the classification criteria for this class Directive hazard 2004/37/EC; SECTION Directive 2000/39/EC; Directive 91/322/EEC. Acute Tox. 9. Physical 4 TLV-ACGIH and Acute chemical toxicity, category ACGIH 2019 properties 4 10.6. SECTION 5.3. Advice Hazardous 14. decomposition Eye Irrit. for firefighters 2 Transport products Eye irritation, category 2 information STOT Note for - REPEATED users: EXPOSURE Skin Irrit. 2 information is not contained dangerous in the under Skin irritation, category 2 present current sheet provisions are based of the on our Code own of knowledge 2.3. The product 9.1. 2-BUTOXYETHANOL

Further information

International on Carriage hazards on basic physical and chemical properties the date of of Dangerous the last version. Goods Users by Road must (ADR) verify and the by Rail GENERAL Does (RID), suitability H302 INFORMATION not of the meet and International thoroughness Maritime of provided Harmful if swallowed. criteria Dangerous for information this hazard Goods according class Code (IMDG), to each and specific of the use International of the product. Air Transport Association (IATA) regulations. Use H312 May develop: hydrogen. jets of water to cool the containers Harmful to in prevent contact product with skin. decomposition and the development of substances potentially hazardous for On This document must not be regarded as a guarantee on any specific product property. Properties the basis of available data, the product does not contain Value any PBT or vPvB in percentage greater Information than 0,1%. 14.1. SECTION health. ASPIRATION The UN use number H332 Always wear full fire prevention of this product Toxicological is not subject information Harmful gear. to our direct control; therefore, users must, under their own responsibility, comply with the current health if inhaled. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Appearance contaminated H319 water used for extinction Causes and serious the remains eye irritation. liquid of the fire according to applicable regulations. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Colour colourless SECTION SPECIAL In the H315 absence Does Not Provide applicable not appointed meet the staff PROTECTIVE 3. Composition/information of experimental with adequate EQUIPMENT data Causes criteria training for FOR for this on hazard the skin product FIRE-FIGHTERS irritation. how to class itself, on ingredients use chemical products. health hazards are evaluated according to the properties of the substances it Odour Normal

Contains

EUH210 fire using fighting the criteria clothing specified i.e. fire Safety kit in (BS the data applicable EN sheet 469), available gloves characteristic regulation (BS on request. for EN classification. 659) and boots (HO specification A29 and A30) in combination with Odour threshold self-contained It is therefore necessary open circuit to positive take into pressure account compressed the concentration Not available air breathing of the individual apparatus hazardous (BS EN 137). substances indicated in section 3, to evaluate the 14.2. UN proper shipping name pH 7,0 +/- 0,5 toxicological effects of exposure to the product. Product’s classification is based on the calculation methods set out in Annex I of the CLP Regulation, unless otherwise indicated in sections Melting point / freezing point LEGEND: Not available Not 11 and Initial boiling point applicable 12. Not available - The ADR: data European Boiling range for evaluation Agreement of chemical-physical concerning the properties carriage of are Dangerous Not available reported goods in section by Road 9.

2.1 Classification of the substance or mixture

product important is stable of symptoms the in substance normal and conditions effects, or mixture of both use and acute storage. and delayed from any incompatible materials, see section 10 for details. the Does 6. Regulation duration not meet and (EU) the type classification 618/2012 of use. (III criteria Atp. CLP) for of this the hazard European class Parliament Information Substances not subject available to exportation reporting pursuant to (EC) Reg. 649/2012: 10.3. Specific The SKIN 7. Regulation None Possibility product PROTECTION information is of not hazardous (EU) 487/2013 (IV Atp. CLP) of the European Parliament classified on symptoms as reactions hazardous and effects pursuant caused to by the the provisions product are set unknown. forth in EC Regulation 1272/2008 (CLP). 7.3. Specific end use(s) Wear RESPIRATORY 8. Regulation category professional 944/2013 SKIN SENSITISATION (V long-sleeved Atp. CLP) of overalls the European and safety Parliament (see Regulation However, since (EU) I the OR product contains hazardous substances in footwear concentrations such as to 2016/425 be declared and in standard section EN no. ISO 3, it 20344). requires Wash a safety body data 4.3. 12.5. sheet with 9. Regulation No Substances Indication Results hazardous soap and (EU) with appropriate of subject of PBT water 605/2014 reactions any and immediate to information, after removing the vPvB are Rotterdam foreseeable (VI Atp. protective assessment medical compliant CLP) of the Convention: in attention normal clothing. to (EU) European Parliament conditions and Regulation special of use treatment 2015/830. and storage. needed Information not available EYE Does 10. Regulation PROTECTION not meet (EU) the classification 2015/1221 (VII criteria Atp. for CLP) this of hazard the European class Parliament None Hazard Wear 11. Regulation Information DIPROPYLENE On the basis airtight protective classification not of available (EU) 2016/918 available GLYCOL and data, goggles (VIII (see Atp. standard indication: MONOMETHYL the product ETHER CLP) of EN the 166). does -- not contain any PBT or vPvB in percentage greater than 0,1%. European Parliament SECTION RESPIRATORY GERM 12. Regulation Substances May react 8. CELL MUTAGENICITY subject violently (EU) Exposure PROTECTION 2016/1179 (IX Atp. CLP) to with: the Stockholm strong controls/personal oxidising Convention: agents. protection 12.6. 2-BUTOXYETHANOL If 13. the Regulation None Other adverse effects threshold (EU) value 2017/776 (e.g. TLV-TWA) (X Atp. CLP) is exceeded for the substance or one of the substances present in the product, use a mask with a type 8.1. A Does 2.2. SECTION 14. Control Label filter May elements