Ultra Low Sulphur Diesel

Hazard statements (CLP)

H226, H304, H315, H332, H373

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Physical hazards

Flammable liquids Category 3

Health hazards

Acute toxicity, inhalation Category 4 Skin corrosion/irritation Category 2 Specific target organ toxicity, repeated Category 2 exposure Aspiration hazard Category 1

Environmental hazards

Not classified WHMIS 2015 defined hazards Not classified

Signal word

Danger

Hazard statements

Flammable liquid and vapor. Causes skin irritation. May be fatal if swallowed and enters airways. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure.

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection.

Response

In case of fire: Use appropriate media to extinguish. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Specific treatment (see information on this label). IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.

Storage

Store in a well-ventilated place. Keep cool. Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations. WHMIS 2015: Health Hazard(s) None known not otherwise classified (HHNOC) WHMIS 2015: Physical None known Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise None known classified (HNOC)

Additional information

Not applicable.

2.1 Classification of the substance or mixture

Category 1 Environmental hazards Not classified. WHMIS 2015 defined hazards Not classified Label elements Signal word Danger Hazard statement Flammable liquid and vapor. Causes skin irritation. May be fatal if swallowed and enters airways. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection. Response In case of fire: Use appropriate media to extinguish. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Specific treatment (see information on this label). IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Storage Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. WHMIS 2015: Health Hazard(s) None known not otherwise classified (HHNOC) WHMIS 2015: Physical None known Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise None known. classified (HNOC) Supplemental information Not applicable. 3. Composition/Information on Ingredients Mixture Chemical name Common name and synonyms CAS number % Petroleum distillates 68476-34-6 90-100 Benzene 71-43-2 <0.1 Benzo[a]pyrene 50-32-8 <0.1 Naphthalene 91-20-3 <0.1 Toluene 108-88-3 <0.1 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Composition comments *Ultra Low Sulphur Diesel is a complex mixture of hydrocarbons. Its exact composition depends on the source of the crude oil from which it was produced and the refining methods used. Ultra Low Sulphur Diesel contains hundreds of individual organic chemicals. This section identifies only some of the well-known chemical constituents. *Sulphur: < 15 ppm *Hydrogen sulphide: Nil 4. First Aid Measures Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Skin contact IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical advice/attention. Specific treatment (see information on this label). Eye contact Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and Skin irritation. May cause redness and pain. delayed Prolonged exposure may cause chronic effects. Indication of immediate Symptoms may be delayed. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Take off all contaminated clothing immediately. Wash contaminated clothing before reuse. Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin. Wear rubber gloves and safety glasses with side shields. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Carbon dioxide. Dry chemical. Foam. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Container may explode in heat of fire. Vapors may form explosive mixtures with air. Vapors may the chemical travel considerable distance to a source of ignition and flash back. Special protective equipment Firefighters should wear full protective clothing including self-contained breathing apparatus. and precautions for firefighters Fire-fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Flammable liquid and vapor. Hazardous combustion May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Polycyclic aromatic products hydrocarbons (PAHs). Aromatic hydrocarbons. 6. Accidental Release Measures Personal precautions, Keep unnecessary personnel away. Keep out of low areas. Eliminate all ignition sources (no protective equipment and smoking, flares, sparks, or flames in immediate area). Do not touch damaged containers or spilled emergency procedures material unless wearing appropriate protective clothing. Do not breathe mist or vapor. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Never return spills to original containers for re-use. Following product recovery, flush area with water. Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewers, basements or confined areas. Environmental precautions Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. Avoid contact with eyes, skin and clothing. Wear appropriate personal protective equipment. Do not breathe mist or vapor. Use only outdoors or in a well-ventilated area. Avoid prolonged exposure. Observe good industrial hygiene practices. Wash thoroughly after handling. When handling, do not eat, drink or smoke. Conditions for safe storage, Keep away from heat, sparks and open flame. including any incompatibilities Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children. 8. Exposure Controls/Personal Protection Occupational exposure limits Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Benzene (CAS 71-43-2) STEL 8 mg/m3 2.5 ppm TWA 1.6 mg/m3 0.5 ppm Naphthalene (CAS 91-20-3) STEL 79 mg/m3 15 ppm TWA 52 mg/m3 10 ppm Petroleum distillates (CAS TWA 100 mg/m3 68476-34-6) Toluene (CAS 108-88-3) TWA 188 mg/m3 50 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Form Benzene (CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Naphthalene (CAS 91-20-3) STEL 15 ppm TWA 10 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Form Petroleum distillates (CAS TWA 100 mg/m3 Vapor and aerosol. 68476-34-6) Toluene (CAS 108-88-3) TWA 20 ppm Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Components Type Value Form Benzene (CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Naphthalene (CAS 91-20-3) TWA 10 ppm Petroleum distillates (CAS TWA 100 mg/m3 Inhalable fraction and 68476-34-6) vapor. Toluene (CAS 108-88-3) TWA 20 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value Form Benzene (CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm Naphthalene (CAS 91-20-3) STEL 15 ppm TWA 10 ppm Petroleum distillates (CAS TWA 100 mg/m3 Inhalable fraction and 68476-34-6) vapor. Toluene (CAS 108-88-3) TWA 20 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value Benzene (CAS 71-43-2) STEL 15.5 mg/m3 5 ppm TWA 3 mg/m3 1 ppm Benzo[a]pyrene (CAS TWA 0.005 mg/m3 50-32-8) Naphthalene (CAS 91-20-3) STEL 79 mg/m3 15 ppm TWA 52 mg/m3 10 ppm Toluene (CAS 108-88-3) TWA 188 mg/m3 50 ppm US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Components Type Value Benzene (CAS 71-43-2) STEL 5 ppm TWA 1 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Naphthalene (CAS 91-20-3) PEL 50 mg/m3 10 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Benzene (CAS 71-43-2) Ceiling 25 ppm TWA 10 ppm Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm US. ACGIH Threshold Limit Values Components Type Value Form Benzene (CAS 71-43-2) STEL 2.5 ppm TWA 0.5 ppm US. ACGIH Threshold Limit Values Components Type Value Form Naphthalene (CAS 91-20-3) TWA 10 ppm Petroleum distillates (CAS TWA 100 mg/m3 Inhalable fraction and 68476-34-6) vapor. Toluene (CAS 108-88-3) TWA 20 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Benzene (CAS 71-43-2) STEL 1 ppm TWA 0.1 ppm Naphthalene (CAS 91-20-3) STEL 75 mg/m3 15 ppm TWA 50 mg/m3 10 ppm Toluene (CAS 108-88-3) STEL 560 mg/m3 150 ppm TWA 375 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Benzene (CAS 71-43-2) 25 µg/g S-Phenylmerca Creatinine * pturic acid in urine Benzo[a]pyrene (CAS 2.5 µg/l 1-Hydroxypyre Urine * 50-32-8) ne, with hydrolysis (1-HP) Toluene (CAS 108-88-3) 0.3 mg/g o-Cresol, with Creatinine * hydrolysis in urine 0.03 mg/L Toluene Urine * 0.02 mg/L Toluene Blood * * - For sampling details, please see the source document. Exposure guidelines Canada - Alberta OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. Canada - British Columbia OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Petroleum distillates (CAS 68476-34-6) Can be absorbed through the skin. Canada - Manitoba OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Petroleum distillates (CAS 68476-34-6) Can be absorbed through the skin. Canada - Ontario OELs: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Petroleum distillates (CAS 68476-34-6) Can be absorbed through the skin. Canada - Quebec OELs: Skin designation Toluene (CAS 108-88-3) Can be absorbed through the skin. Canada - Saskatchewan OELs: Skin designation Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Petroleum distillates (CAS 68476-34-6) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Benzene (CAS 71-43-2) Can be absorbed through the skin. Naphthalene (CAS 91-20-3) Can be absorbed through the skin. Petroleum distillates (CAS 68476-34-6) Can be absorbed through the skin. Appropriate engineering Mechanical ventilation should be used when handling this product in enclosed spaces. Local controls exhaust ventilation may be necessary. Individual protection measures, such as personal protective equipment Eye/face protection Face shield or chemical goggles. Skin protection Hand protection Nitrile rubber Viton™. PVC gloves. Tychem™ BR/LV. Tychem™ TK. Other