MIL-L-19538C 36251 Flat Gray Acrylic Lacquer

SECTION 2: Hazards identification

EMERGENCY OVERVIEW

2.1 Classification of the substance or mixture

Flammable Liquid, Category 2 Acute Toxicity (Oral), Category 4 Eye Damage/Irritation, Category 2 Skin Corrosion/Irritation, Category 2 Sensitization - Skin, Category 1 Specific Target Organ Toxicity (Single Exposure - Respiratory Tract Irritation, Narcosis), Category 3 Specific Target Organ Toxicity (Repeated Exposure), Category 2 PHYSICAL APPEARANCE Liquid IMMEDIATE CONCERNS DANGER! Flammable liquid and vapor. May cause eye, skin and respiratory tract irritation. May cause asphyxiation, or brain, lung or other organ injury if inhaled, swallowed or absorbed by the skin. HAZARDOUS WARNING LABEL: DANGER! FLAMMABLES! Highly flammable liquid and vapour. Harmful if swallowed. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Obtain special instructions before use. Ground / bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. se only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Do no eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Use only outdoors or in a well- ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Get medical advice/attention if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing and rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes and remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. If eye irritation persists: Get medical advice/attention. If skin irritation or rash occurs Get medical advice/attention. In case of fire Use chemical extinguisher or chemical foam extinguisher for extinction. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Dispose of contents/container to proper regulations.

Potential health effects

EYES Liquid is severely irritating to the eyes. High vapor concentrations are also irritating. SKIN Liquid is moderately irritating to the skin. Prolonged or repeated contact can result in drying of the skin which may result in skin irritation and dermatitis (rash). Liquid may be absorbed through the skin. Chemical Name CAS Number Weight % Talc 14807-96-6 25% to 50% Acrylic Copolymer (56705700001- 56705700001 20% to 25% 5247P) Titanium Dioxide 13463-67-7 10% to 15% *Xylenes, Mixed Isomers 1330-20-7 5% to 10% Acetone 67-64-1 5% to 10% bis(2-ethylhexyl)adipate 103-23-1 1% to 5% *Methyl Ethyl Ketone 78-93-3 1% to 5% *2-Butoxyethanol 111-76-2 1% to 5% Methyl n-Amyl Ketone 110-43-0 1% to 5% *Butanol 71-36-3 1% to 5% Aluminum Hydroxide 21645-51-2 0.01% to 1% amorphous silicone dioxide, 7631-86-9 0.01% to 1% chemically prepared Carbon Black 1333-86-4 0.01% to 1% * Toxic chemical subject to the reporting requirements of section 313 of Title III and of 40 CFR 372. 4. FIRST AID MEASURES EYES Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Seek medical aid if irritation persists. SKIN Flush skin with soap and water while removing contaminated clothing. If irritation occurs, seek immediate medical attention. Do not reuse clothing or shoes until thoroughly cleaned. INGESTION Do not induce vomiting, and seek immediate medical attention. Do not attempt to give any liquids if victim is unconscious. INHALATION Immediately remove victim to fresh air. If victim is not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Seek immediate medical attention. NOTES TO PHYSICIAN: If the victim is a child, give no more than 1 glass of water and 15cc (1 tablespoon) syrup of ipecac. If symptoms such as loss of gag reflex, convulsions, or unconsciousness occur before emesis, gastric lavage should be considered following intubation with a cuffed endotracheal tube. 5. FIRE FIGHTING MEASURES FLASH POINT AND METHOD 104 degrees Fahrenheit Tagliabue Closed Cup (TCC) FLAMMABLE LIMITS 0.3% to 12.8% AUTOIGNITION TEMPERATURE No data available. GENERAL HAZARD Carbon monoxide and unidentified organic compounds may be formed during combustion. EXTINGUISHING MEDIA Use water fog, "alcohol" foam, dry chemical, or CO2. FIRE FIGHTING PROCEDURES WARNING! Flammable Liquid. Clear the fire area of unprotected personnel. Do not enter confined fire space without full bunker gear; including a positive pressure NIOSH approved SCBA. Cool fire exposed containers with water. If water is used, fog nozzles are preferred EXPLOSION HAZARD When heated above the flash point, this material emits flammable vapors which, when mixed with air, can burn or be explosive. Fine mists or sprays may be flammable at temperatures below the flash point. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES WARNING. Flammable. Ventilate area of leak or spill for at least 24 hours or until it has been declared safe. Remove all sources of ignition. Stop the leak if there is no risk involved. Clean-up personnel require protective clothing and respiratory protection from vapors. Absorb liquid with inert material. Only specially trained or qualified personnel should handle the emergency. ENVIRONMENTAL PRECAUTIONS WATER SPILL Keep material out of storm sewers and ditches which lead to waterways. LAND SPILL Contact applicable authorities and determine applicable regulations based on MSDS information. AIR RELEASE Contact applicable authorities and determine applicable regulations based on MSDS information. 7. HANDLING AND STORAGE GENERAL PROCEDURES Keep away from heat, sparks, and flame. Surfaces that are hot may ignite liquid even in the absence of sparks or flame. Extinguish pilot lights, cigarettes, and turn off all other sources of ignition prior to use, and until all vapors are gone. Keep containers tightly closed and upright to prevent leakage. COMMENTS KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue and can be dangerous. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) EXPOSURE LIMITS CHEMICAL NAME OSHA PEL ACGIH TLV ppm mg/m3 ppm mg/m3 Talc TWA N/A 20 mppcf N/A 2 STEL N/A NL N/A NL Titanium Dioxide TWA N/A 15 N/A NL STEL N/A NL N/A NL *Xylenes, Mixed Isomers TWA 100 435 100 435 STEL NL 150 635 Acetone TWA 1000 2400 250 590 STEL NL *Methyl Ethyl Ketone TWA 200 590 200 590 STEL NL 300 885 *2-Butoxyethanol TWA 50 240 5 24 STEL NL Methyl n-Amyl Ketone TWA 100 465 100 465 STEL NL *Butanol TWA 100 300 50 150 STEL NL amorphous silicone dioxide, TWA N/A 80 N/A chemically prepared STEL N/A NL N/A NL Carbon Black TWA N/A 3.5 N/A 3.5 STEL N/A NL N/A NL OSHA TABLE COMMENTS: NL = Not Listed Ca = "WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM." ENGINEERING CONTROLS: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination.