175i Make-up Ink

Hazard statements (CLP)

H225, H302, H311, H319, H331, H370

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the Substance or Mixture Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Specific Target Organ Toxicity (single exposure), Category 1

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor. H331 - Toxic if inhaled. H302 - Harmful if swallowed. H311 - Toxic in contact with skin. H319 - Causes serious eye irritation. H370 - Causes damage to organs

Precautionary statements

P233 - Keep container tightly closed. P210 - Keep away from P280 - Wear protective heat/sparks/open flames/hot surfaces. - No smoking. gloves/protective clothing/eye protection/face protection. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment. P243 - Take precautionary measures against static discharge. P242 - Use only non-sparking tools. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P264 - Wash hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P361+364 - Take off immediately all contaminated clothing and wash it before reuse. P260 - Do not breathe dust/fume/gas/mist/vapors/spray.

Response

P370+378 - In case of fire, use ... to extinguish. P303+361+353 - IF ON water/shower. SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 - Call a POISON CENTER/doctor/... P322 - Specific measures see ... on this label. P301+312 - IF SWALLOWED Call a POISON CENTER or doctor/physician if you feel unwell. P330 - Rinse mouth. P302+352 - IF ON SKIN Wash with plenty of soap and water. P312 - Call a POISON CENTER/doctor/... if you feel unwell P321 - Specific treatment see ... on this label. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313 - If eye irritation persists, get medical advice/attention.

Storage

P403+235 - Store in cool/well-ventilated place. P501 - Dispose of contents/container to ... P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place.

Potential health effects

Chronic: Chronic inhalation may cause effects similar to those of acute inhalation. Prolonged or repeated skin contact may cause defatting and dermatitis. Animal studies have reported that fetal effects/abnormalities may occur when maternal toxicity is seen. Chronic overexposure to vapors may cause lung damage. Chronic inhalation and ingestion may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. Effects may be delayed. Chronic exposure to fluoride compounds may cause systemic toxicity. 2.3.1 Inhalation Causes respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness. May cause central nervous system effects such as nausea and headache. Neurobehavioural effects of exposure to MEK (200 ppm for 4 hrs) were studied with 137 volunteers. There were no statistically significant effects observed in biochemical, psychomotor, sensorimotor and psychological tests. Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. May cause systemic effects. May cause headache, loss of appetite, nausea, fatigue, abdominal pain, darked urine and jaudice. 2.3.2 Skin Contact May be absorbed through the skin in harmful amounts. Repeated or prolonged exposure may cause drying and cracking of the skin. Only one human case of skin sensitization was located. Negative results were obtained in an animal test; MEK did not produce skin sensitization in the mouse ear thickness test. Causes skin burns. May be absorbed through the skin. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. 2.3.3 Eye Contact Causes eye irritation. Vapors may cause eye irritation. Animal evidence suggests that MEK is a moderate to severe eye irritant. Causes eye burns. May cause chemical conjunctivitis and corneal damage. 2.3.4 Ingestion May cause irritation of the digestive tract. Possible aspiration hazard. May cause central nervous system depression. Animal evidence suggests that MEK can be aspirated (inhaled) into the lungs during ingestion or vomiting. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts of fluoride may cause salivation, nausea, vomiting, abdominal pain, fever, labored breathing. Exposure to fluoride compounds can result in systemic toxic effects on the heart, liver, and kidneys. It may also deplete calcium levels in the body leading to hypocalcemia and death. Fluoride can reduce calcium levels leading to fatal hypocalcemia. May cause systemic effects.

2.1 Classification of the substance or mixture

Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Specific Target Organ Toxicity (single exposure), Category 1