GRIAL

Industrias AFRASA, S.A

Revision date : 2019-04-25

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 3
Safety risk rating 2
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

204-881-4/128-37-0

Name of the chemical

2,6-di-tert-butyl-p-cresol

Concentration

<1%

EC/CAS

258-256-6/52918-63-5

Name of the chemical

Deltamethrin; (S)-a-cyano-3-phenoxybenzyl (1R, 3R)-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate

Concentration

00-

Listed in

General Information

Revision date

2019-04-25

Product name

GRIAL

1.2.1 Relevant identified uses

INSECTICIDE

Emergency telephone

Industrias Afrasa, S.A. +34 96 132 17 00 (Only available during office hours

Icons in SDS

GHS02 GHS05 GHS07 GHS08 GHS09 M004 M008 M009 M010 M017 T021 T050

Company Information

company name

Industrias AFRASA, S.A

e-mail address of the competent person responsible for the Safety Data Sheet

afrasa@afrasa.es

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H302, H304, H315, H318, H336, H410

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

In accordance with Regulation (EU) No 1272/2008: Asp. Tox. 1 : May be fatal if swallowed and enters airways. Eye Dam. 1 : Causes serious eye damage. Acute Tox. 4 : Harmful if swallowed. Flam. Liq. 3 : Flammable liquid and vapour. Skin Irrit. 2 : Causes skin irritation. Aquatic Acute 1 : Very toxic to aquatic life. Aquatic Chronic 1 : Very toxic to aquatic life with long lasting effects.

2.2 Label elements

Labelling in accordance with Regulation (EU) No 1272/2008:

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of water the affected area. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P235 Keep cool. P501 Dispose of contents/container to ...

Supplemental label elements

EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Contains

Isobutanol A complex combination of hydrocarbons obtained by treating a petroleum fraction with hydrogen in the presence of a catalyst. It consists of hydrocarbons having carbon numbers predominantly in the range of C11 through C25 and boiling in the range of approximately 205ºC to 400ºC (401ºF to 752ºF).,Distillates (petroleum), hydrotreated middle,Gasoil - unspecified Calcium dodecylbenzene sulfonate SP1: Do not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads. SPo2: Wash all protective clothing after use. SPe3 (1): To protect aquatic organisms respect an unsprayed buffer zone of 30 metres to surface water bodies in tomato, aubergine, courgette, cucumber and gherkin both in fields and greenhouses / 30 m in melon, watermelon and strawberry in field / 20 m of which 10 m must have a vegetation cover using 75% drift reduction nozzles in cauliflower, cabbage and broccoli / 30 m in olive trees. SPe3 (2): To protect non-target arthropods, respect an unsprayed buffer zone of 20 meters to non-agricultutal land or respect and unsprayed buffer zone of 15 meters to non-agricultutal lans using 30% drift reduction nozzles in olive trees. SPo5: Ventilate treated areas/greenhouses until spray has dried before re-entry. The preparation shall not be used in combination with other products. SPe8: Dangerous to bees. To protect bees and other pollinating insects do not apply to crop plants when in flower. Do not use where bees are actively foraging. Do not apply when flowering weeds are present.

2.3 Other hazards

In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment.

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