APACHE

Industrias AFRASA, S.A

Revision date : 2018-02-13

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 2
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

247-557-8/71751-41-2

Name of the chemical

Abamectin (Kombination von Abamectin B1a und Abamectin B1b) (ISO); Abamectin B1a (Reinheit ≥ 80 %) (618/2012)

Concentration

00-0 1-3% <5% 00-1

EC/CAS

204-881-4/128-37-0

Name of the chemical

2,6-di-tert-butyl-p-cresol

Concentration

0.25-2.5%

General Information

Revision date

2018-02-13

Product name

APACHE

Emergency telephone

National advisory body/Poison Center Telephone number (Croatia) Tox-Clinic –Tox National Center "Pirogov" +359 2 915 44 09

Icons in SDS

GHS02 GHS05 GHS07 GHS08 GHS09 M004 M008 M009 M010 M017

Company Information

company name

Industrias AFRASA, S.A

e-mail address of the competent person responsible for the Safety Data Sheet

afrasa@afrasa.es

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H302, H304, H318, H336, H373, H410

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

In accordance with Regulation (EU) No 1272/2008: Acute Tox. 4 : Harmful if swallowed. Aquatic Chronic 1 : Very toxic to aquatic life with long lasting effects. Asp. Tox. 1 : May be fatal if swallowed and enters airways. Eye Dam. 1 : Causes serious eye damage. Flam. Liq. 3 : Flammable liquid and vapour. STOT RE 2 : May cause damage to organs through prolonged or repeated exposure. STOT SE 3 : May cause drowsiness or dizziness.

2.2 Label elements

Labelling in accordance with Regulation (EU) No 1272/2008:

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or a doctor. P501 Dispose of contents and containers in accordance with the regulations on hazardous waste.

Supplemental label elements

EUH066 Repeated exposure may cause skin dryness or cracking. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Contains

2-methylpropan-1-ol,iso-butanol abamectin (combination of avermectin B1a and avermectin B1b) (ISO) Calcium dodecylbenzene sulfonate Hydrocarbons, C10, aromatics, <1% naphthalene SP1: Do not allow pollution of waters by product or by its packaging. Machines for application of product do not clean near surface of water. Avoid contamination via drains from farms and roads. SPe3 (1): To protect aquatic organisms the protection zone to the water surface should be respected as indicated in the environmental protection measures. SPe3 (2): For protection of non-target arthropods, the safety zones should be respected to the non-agricultural area of 15 meters when applied to the pear; 10 meters when applied to oranges, apples, peaches and tomatoes; 5 meters when applied in vine. SPe8: Dangerous to bees. To protect bees and other pollinating insects do not treat the crop during the flowering. Do not apply at the time of grazing bees. Do not apply at the time of florewing weeds. Remove weeds before florewing. SPo (1): It is imperative to wear protective clothing, protective gloves and face shields or goggles that fit well when preparing the spray solution and handling with undiluted product. SPo (2): It is imperative to wear protective clothing and protective gloves when applying and handling with diluted product and spray solution and in contact with contaminated surface by product and by spray solution. Restrictions: Treatment should not be carried out on windy weather. In the protected area do not treat melon, watermelon, squid, cucumber, cucumber cress, gooseberries and strawberries in the winter period, from November to February. In protected areas, 4 days after application of APACHE, no insect pollinators should be allowed. In protected areas, 14 days after application of APACHE, no useful macroorganisms should be released. The use from the air is not permitted.

2.3 Other hazards

In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment.

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