ProForce Rumbler 100SC Insecticide

Hazard statements (CLP)

H302, H320, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this MSDS. R22, R36, R50/53. Harmful if swallowed. Irritating to eyes. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. H302: Harmful if swallowed. H320: Causes eye irritation. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S20, S23, S29, S60, S61, S62, S20/21, S24/25. When using, do not eat or drink. Do not breathe vapours or mists. Do not empty into drains. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this MSDS. When using, do not eat, drink or smoke. Avoid contact with skin and eyes.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING

Prevention

P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, product does not burn. Use extinguishing media suited to surrounding materials.

Storage

P410: Protect from sunlight. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Opaque white liquid. Odour: No data re odour.

Health hazards

Bifenthrin is harmful to mammals when ingested. Large doses may cause incoordination, tremor, salivation, vomiting, diarrhoea, and irritability to sound and touch. LD50, for Bifenthrin is about 54 mg/kg in female rats and 70 mg/kg in male rats. The LD50 for rabbits whose skin is exposed to Bifenthrin is greater than 2,000 mg/kg. Bifenthrin does not sensitize the skin of guinea pigs. Although it does not cause inflammation or irritation on human skin, it can cause a tingling sensation which lasts about 12 hours. It is virtually non-irritating to rabbit eyes. harmful if swallowed, eye irritant, repeated exposure may cause skin dryness or cracking.

Potential health effects

Inhalation: Short Term Exposure: Available data indicates that this product is not harmful. However product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term inhalation. Skin Contact: Short Term Exposure: This product causes skin numbness but further symptoms are not available. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort. Long Term Exposure: No data for health effects associated with long term exposure. Eye Contact: Short Term Exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage. Long Term Exposure: No data for health effects associated with long term eye exposure. Ingestion: Short Term Exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product is harmful, but symptoms are not available. However, this product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased. Long Term Exposure: No data for health effects associated with long term ingestion. Carcinogen Status: SWA: No significant ingredient is classified as carcinogenic by SWA. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC.