Imtrade Picker Herbicide

Hazard statements (CLP)

H302, H315, H320, H332, H335

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Hazard statements

SUSMP Classification: S6 ADG Classification: None allocated. Not a Dangerous Good under the ADG Code UN Number: None allocated GHS Signal word: WARNING Acute Toxicity Oral - Category 4 Skin Irritation - Category 2 Eye irritation - Category 2B Acute Toxicity Inhalation - Category 4 Specific Target Organ Toxicity - Single Exposure - Category 3 HAZARD STATEMENTS H302: Harmful if swallowed H315: Causes skin irritation H320: Causes eye irritation H332: Harmful if inhaled H335: May cause respiratory irritation

Prevention

P102: Keep out of reach of children. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: Not combustible. Use extinguishing media suited to burning materials.

Storage

P405: Store locked up. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Clear brown liquid. Odour: Characteristic odour.

Health hazards

The oral LD50 of Triclopyr in rats ranges from 630 to 729 mg/kg , and is over 2000 mg/kg for various amine and ester formulated products. The dermal LD50 for the technical material in rabbits is greater than 2000 mg/kg, and greater than 4000 mg/kg for the formulations. Inhalation of Triclopyr did not affect rats, but inhalation of some of the formulations did cause nasal irritation. These data indicate Triclopyr is harmful. This product is irritating to eyes and skin, possible skin sensitiser.

2.1 Classification of the substance or mixture

ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated GHS Signal word: WARNING. Acute Toxicity Oral - Category 4 Skin Irritation - Category 2 Eye irritation - Category 2B Acute Toxicity Inhalation - Category 4 Specific Target Organ Toxicity - Single Exposure - Category 3 HAZARD STATEMENTS: H302: Harmful if swallowed. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation.