TOM NOIR FRAGRANCE

Hazard statements (CLP)

H317, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA- CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRONELLOL, COUMARIN, E/Z 3-METHYL-5-CYCLOTETRADECEN-1-ONE, HYDROXYCITRONELLAL, LIMONENE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA- Hazard Label: CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRONELLOL, COUMARIN, E/Z 3-METHYL-5- CYCLOTETRADECEN-1-ONE, HYDROXYCITRONELLAL, LIMONENE Hydrocarbon Concentration %: 1.346%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 14 Supplemental EUH208, Contains ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA- Information: CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRONELLOL, COUMARIN, E/Z 3-METHYL-5-CYCLOTETRADECEN-1-ONE, HYDROXYCITRONELLAL, LIMONENE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA- Hazard Label: CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRONELLOL, COUMARIN, E/Z 3-METHYL-5- CYCLOTETRADECEN-1-ONE, HYDROXYCITRONELLAL, LIMONENE Hydrocarbon Concentration %: 1.346% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 1-<5% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 1-<5% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN 14 LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw ACETYL CEDRENE 32388-55-9 251-020-3 1-<5% SS 1B-EH A1-EH C1; oral: ATE = 4500 H317-H410,- mg/kg bw LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 1-<5% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- CINNAMYL ALCOHOL 104-54-1 203-212-3 0.1-<1% ATO 4-SS 1B-EH C2; oral: ATE = 2000 H302-H317-H411,- mg/kg bw ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- BETA- 87-44-5 201-746-1 0.1-<1% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- E/Z 3-METHYL-5- 259854-70-1, SS 1B-EH A1-EH C1; CYCLOTETRADECEN- 259854-71-2 452-280-2 01-0000019120-85-xxxx 0.1-<1% H317-H410,- 1-ONE COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw HYDROXYCITRONELL 107-75-5 203-518-7 0.1-<1% EDI 2-SS 1B;H317- AL H319,- dermal: ATE = 5000 PHENYLPROPANOL 122-97-4 204-587-6 0.1-<1% SCI 1B-EDI 1;H314,- mg/kg bw-oral: ATE = 2275 mg/kg bw 4-METHYL-3-DECEN-5- 81782-77-6 279-815-0 01-2119983528-21-xxxx 0.1-<1% EH A1-EH C2;H400- OL H411,- FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 50-100% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable 14 Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. 14 Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 UK Short-term exposure limit (15-minute) 10 mg/m³ (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with